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无机含氧酸的酸性与分子拓扑指数的关系 总被引:5,自引:0,他引:5
本文提出一种新的分子拓扑指数Y=δR(m+k0.5m)n-0.5。Y对25种无机含氧酸呈现唯一性表征,并与其pK1显示高度相关性。用最小二乘法拟合pK1与Y的线性回归方程为:pK1=12.23-1.22Y,r=-0.979,并在0.01显著水平下通过F检验 相似文献
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本文基于W(Ⅵ)-5′-硝基水杨基荧光酮(5′-N-SAF)-Tween-80体系的荧光熄灭效应,提出一种测定微量钨的新荧光方法。在0.2~1.0mol/L的硫酸介质中,在Tween-80存在下,5′-N-SAF存在两个激发峰,其激发波分别为λex1=475nm,λex2=505nm,发射波长为λem=525nm。W(Ⅵ)与5′-N-SAF形成1∶3的配合物。钨浓度在每25mL0.25~2.5μg范围内呈线性关系,检测限为每25mL0.25μg。本法灵敏度高,选择性好,不经分离可直接测定合金钢中的钨,结果满意。 相似文献
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催化动力学光度法测定痕量铁的研究 总被引:9,自引:0,他引:9
本文研究了在稀硫酸介质中铁催化过氧化氢氧化胭脂红的褪色反应及其动力学条件,测定了反应级数和表现活化能,建立了测定痕量铁的新方法。该方法的检出限为0.25ng/mLFe,线性范围为0~0.4μg/25mLFe,方法简便、快速、灵敏度高。应用于水及食品中痕量铁的测定,结果满意。 相似文献
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二甲苯蓝FF分光光度法测定微量亚硝酸根 总被引:12,自引:0,他引:12
研究了在稀盐酸介质中微量亚硝酸根与二甲苯蓝FF发生的亚硝化反应,建立了测定微亚硝酸极的新方法,方法的线性范围为0.2×10^-6~15×10^-6g/25mlNO^-2其Sandell灵敏度为9.15×10^-10g/cm^2,方法已用于水微量亚硝酸根的测定,并对反应机理进行了初步探讨。 相似文献
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分光光度法同时测定中草药中的钼和铜 总被引:2,自引:2,他引:2
本文建立了在混合显色剂(PF+PAN)的胶束体系中,利用分光光度法同时测定中草药中的钼和铜。实验表明:在混合体系中,钼量在0~10μg/25mL,铜量在0~50μg/25mL的范围内符合比尔定律,ε′Mo=9.2×104L·mol-1·cm-1;ε′Cn=1.5×104L·mol-1·cm-1。该法用于中草药样品的分析,结果满意,回收率可达92~111%。 相似文献
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5′—硝基水杨基荧光酮荧光熄灭法测定微量钨 总被引:3,自引:1,他引:3
本文基于W(Ⅵ)-5′-硝基水杨基荧光酮(5′-N-SAF)-Tween-80体系的荧光熄来效应,提出一种测定微量钨的荧光方法,在0.2~1.0mol/L的硫酸介质中,在Tween-80存在下,5′-N-SAF存在两个激发峰,其激发波分别为λex1=475nm,λex2=505nm发射波长为λem=525nm。W(Ⅵ)与5′-N-SAF形成1:3的配合物,钨浓度在每25mL0.25~2.5μg范围 相似文献
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混合表面活性剂存在下二溴羟基苯基荧光酮光度法测定痕量铜 总被引:7,自引:0,他引:7
研究了在氯化十六烷基吡啶(CPC)和吐温-40存在下,铜与二溴羟基苯基荧光酮(DBH-PF)显色反应,结果表明,在pH6.0-7.1的六次甲基四胺-盐酸缓冲溶液中,铜与DBH-PF形成1:1配合物,其最大吸收峰全于570nm摩尔吸光系数1.2×10^5L.mol^-1.cm^-1,铜含量在0~6μg/25mL范围内符合比尔定律,方法用于测定环境水标样及牛肝粉标样中的痕量铜。 相似文献
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Ti(Ⅳ)—F^——邻硝基苯基荧光酮—氯化十六烷基吡啶四元体系显色反应… 总被引:3,自引:0,他引:3
本较详细研究了在H2SO4介质中,Ti(Ⅳ)-F^--o-NPF-CPC体系水相光度法测定痕量钛的新方法。四元体系的最大吸收峰在565nm处,表观摩尔吸光系数为2.1×10^5L.mol^-^1.cm^-^1,Sandell灵敏度为2.28×10^-^4μgTi/cm^2。钛含量在0-4μg/25mL范围内遵宁比尔定律。方法用于土壤,粮食,牧草,蔬菜和中草药中钛的测定,结果满意。 相似文献
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高效毛细管电泳—电化学法检测烟酰胺腺嘌呤二核苷酸 总被引:2,自引:0,他引:2
报道了一种测定烟酰胺腺嘌呤二核苷酸的毛细管电泳电化学检测方法。采用30cm×25μm的石英毛细管分离NADH与脲酸,以微型碳糊电极测定经分离后的NADH的含量。在pH7.5的磷酸盐缓冲溶液中,标准工作曲线的范围为1.0-100μmol/L;最代检测浓度为0.60μmol/L。 相似文献
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本文报道了以二溴羟基苯基荧光酮(DBH-PF)为指示剂,在阳离子表活性剂CPC存在下荧光猝灭间接测定Br^-的新方法。在0.6mol/LH2SO4介质中,Br^-和BrO3^-反应生成Br2,Br2与DBH-PF(λem=520nm)生成红色化合物,使体荧光猝灭。Br^-含量在0.25-6.25μg/25mL范围内有良好的线性关系,检测限为0.25μg/25mL。该法灵敏度高,选择性好,用于合成海 相似文献
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Reactions in droplets in microfluidic channels 总被引:5,自引:0,他引:5
Fundamental and applied research in chemistry and biology benefits from opportunities provided by droplet-based microfluidic systems. These systems enable the miniaturization of reactions by compartmentalizing reactions in droplets of femoliter to microliter volumes. Compartmentalization in droplets provides rapid mixing of reagents, control of the timing of reactions on timescales from milliseconds to months, control of interfacial properties, and the ability to synthesize and transport solid reagents and products. Droplet-based microfluidics can help to enhance and accelerate chemical and biochemical screening, protein crystallization, enzymatic kinetics, and assays. Moreover, the control provided by droplets in microfluidic devices can lead to new scientific methods and insights. 相似文献
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The toxicity of inorganic trivalent arsenic for living organisms is reduced by in vivo methylation of the element. In man, this biotransformation leads to the synthesis of monomethylarsonic (MMA) and dimethylarsinic (DMA) acids, which are efficiently eliminated in urine along with the unchanged form (Asi). In order to document the methylation process in humans, the kinetics of Asi, MMA and DMA elimination were studied in volunteers given a single dose of one of these three arsenicals or repeated doses of Asi. The arsenic methylation efficiency was also assessed in subjects acutely intoxicated with arsenic trioxide (As2O3) and in patients with liver diseases. Several observations in humans can be explained by the properties of the enzymic systems involved in the methylation process which we have characterized in vitro and in vivo in rats as follows: (1) production of Asi metabolites is catalyzed by an enzymic system whose activity is highest in liver cytosol; (2) different enzymic activities, using the same methyl group donor (S-adenosylmethionine), lead to the production of mono- and di-methylated derivatives which are excreted in urine as MMA and DMA; (3) dimethylating activity is highly sensitive to inhibition by excess of inorganic arsenic; (4) reduced glutathione concentration in liver moderates the arsenic methylation process through several mechanisms, e.g. stimulation of the first methylation reaction leading to MMA, facilitation of Asi uptake by hepatocytes, stimulation of the biliary excretion of the element, reduction of pentavalent forms before methylation, and protection of a reducing environment in the cells necessary to maintain the activity of the enzymic systems. 相似文献
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Electrochemistry is one of the most advanced techniques for monitoring neurochemical activities in the living brain because electrochemical approaches bear the advantageous features of high spatial and temporal resolutions, which facilitate its tremendous potential in investigating the highly spatially heterogeneous brain system and the fast dynamics of neurochemical activities. On the other hand, since brain is the most complicated organ in the sense of its numerous kinds of neurochemical species, high selectivity is always required for any analytical methods that approach the brain. In this review, we will discuss various electrochemical methodologies to achieve selective detection of neurochemicals in mammalian brain and the strategies developed mainly by our group towards selective monitoring of both electrochemically active and inactive neurochemicals. At the end, we will discuss possible solutions towards brain mapping of neurochemical species and combination of neurochemical detection strategy with electrophysiology as the direction of future development of electroanalysis in living brain. 相似文献
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G. den Boef 《Fresenius' Journal of Analytical Chemistry》1981,305(2):127-129
Summary At the session of the WPAC of Fechem on education in analytical chemistry it was concluded that it is now essential to include chemometrics and basic knowledge of computers in all courses on analytical chemistry.
Tendenzen in der analytisch-chemischen Ausbildung
Zusammenfassung Bei einer Tagung der WPAC über die Lehre auf dem Gebiet der analytischen Chemie wurde bei der Betrachtung neuer Aspekte festgestellt, daß vor allem Chemometrie und Grundkenntnisse in Computertechnik in die Ausbildung aufgenommen werden sollten.相似文献
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Michael F. Cunningham 《Comptes Rendus Chimie》2003,6(11-12):1351-1374
Recent developments in nitroxide-mediated polymerizations conducted in emulsion and miniemulsion have advanced the field across a range of both experimental and theoretical fronts. This article reviews progress in bicomponent initiating systems (including use of camphorsulfonic acid to enhance rate), unimolecular initiating systems, miniemulsions not requiring the use of volatile costabilizers, polymerization of acrylates, mathematical modeling and simulation, and theoretical understanding with regards to issues such as compartmentalization, preservation of polymer chain livingness, the role of aqueous phase kinetics and phase partitioning. These topics are discussed and analyzed to present an integrated portrait of the current status of nitroxide-mediated polymerizations in emulsion/miniemulsion and to identify the most pressing concerns, issues, and opportunities. To cite this article: M.F. Cunningham, C. R. Chimie 6 (2003). 相似文献