共查询到20条相似文献,搜索用时 171 毫秒
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很久以来人们就尝试着结合有机材料和无机材料的性质于一种复合材料。在还没有复合材料这一概念时,有机/无机复合结构已被广泛用于聚合物工业中——无机添加剂(矿物、粘土、滑石等)被加入聚合物中以改善其性能。过去十年中,关于有机/无机纳米复合材料的研究工作已成为材料学科的一个重要领域。不同于传统的复合材料,有机无机纳米复合材料其相微区通常为纳米尺度,有时甚至减小到分子水平的复合。复合材料的性质不但与各组分的性质有关,而且各组分相的形态和其间界面性质密切相关,后两者对决定材料的整体性质起着至关重要的作用[1,2]. 相似文献
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有机染料-层状硅酸盐光活性纳米复合材料* 总被引:2,自引:0,他引:2
有机-无机纳米复合材料,尤其是有机客体插层入无机层状固体自组装形成的纳米复合材料,因其独特的微观结构与性能,在超分子构筑纳米材料领域中具有特殊地位。本文主要介绍了光致变色与光致发光光功能性有机染料插层层状硅酸盐纳米复合材料的研究进展,着重讨论了螺吡喃、偶氮、二芳基乙烯、芘、香豆素等染料在二维纳米片层间独特的光学行为、有序排列形态、构筑的多层功能性薄膜及其在光功能性材料开发方面的应用前景。 相似文献
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《化学通报》2005,68(11):878-880
[w123]具有纳米结构的有机发光材料研究进展**Progress in Research on Organic Nanomaterials for Luminescence赵雷黄维*(复旦大学先进材料研究院上海200433)对有机纳米发光材料制备方法以及材料的性能作了较为全面的综述。有机纳米发光材料由于存在分子间作用力(范德华力)或氢键以及具有小的Frenkel激子半径,与无机半导体纳米微粒以及纳米金属有着很大的区别,具有自己独特的光电性能,同时又兼具了有机发光材料响应速度快、可进行分子设计和纳米材料的尺寸效应等优点,在新型光电器件方面具有潜在应用前景。综合研究现状,本文也提出了该… 相似文献
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近年来,溶胶-凝胶技术在制备无机-有机复合材料中的应用越来越广泛犤1~6犦。该方法既可以制得具有很好机械性能和光学均匀性的块体材料,也可以制得薄膜和粉体材料。有机光学活性物质在无机基质中的存在状态及其化学环境,有机分子之间及有机分子与无机基质之间的相互作用对材料的热稳定性、光学特性以及实际应用影响极大犤7~10犦。研究无机基质的微环境与有机光学活性分子之间的相互作用,对于复合材料的组成、性能、制备工艺的优化设计和实际应用至关重要。但是,目前有关这方面的系统研究报道很少。本文在硅溶胶中分别掺入了一… 相似文献
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通过两步电化学阳极氧化技术制备了孔径为40nm的多孔纳米阳极氧化铝材料(AAO),在AAO薄膜上分别填充了几种有机荧光分子使其形成高度有序的有机-无机复合体发光阵列,测定了此复合体的发射光谱.结果表明,AAO薄膜对有机分子具有较强的结合能力,其结合能力来源于物理和化学的协同作用.在AAO纳米薄膜上的有机荧光分子的最大发射波长均产生了明显的蓝移现象,初步探讨了此现象的机理.有机分子填充进入高度有序的AAO纳米孔阵列之中时,有机分子的聚集形式会发生改变并且也是高度有序的,同时由于极化作用使有机分子沿着纳米孔的轴向具有相对优势的分子取向,使有机分子在AAO纳米薄膜上形成了接近单分子层的高度有序的排列方式,增强了发光效率. 相似文献
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Organic/inorganic hybrid materials prepared by the sol–gel approach have rapidly become a fascinating new field of research
in materials science. The explosion of activity in this area in the past decade has made tremendous progress in both the fundamental
understanding of the sol–gel process and the development and applications of new organic/inorganic hybrid materials. Polymer-inorganic
nanocomposite present an interesting approach to improve the separation properties of polymer material because they possess
properties of both organic and inorganic such as good permeability, selectivity, mechanical strength, and thermal and chemical
stability. Composite material derived by combining the sol–gel approach and organic polymers synthesis of hybrid material
were the focus area of review It has also been demonstrated in this review that a more complete understanding of their structure–property
behavior can be gained by employing many of the standard tools that are utilized for developing similar structure–property
relationships of organic polymers. This review article is introductory in nature and gives introduction to composite materials/nanocomposite,
their applications and the methods commonly employed for their synthesis and characterization. A brief literature survey on
the polysaccharide templated and polysaccharide/protein dual templated synthesis of silica composite materials is also presented
in this review article. 相似文献
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《Journal of separation science》2018,41(1):195-208
The efficiency of the extraction and removal of pollutants from food and the environment has been an important issue in analytical science. By incorporating inorganic species into an organic matrix, a new material known as an organic–inorganic hybrid material is formed. As it possesses high selectivity, permeability, and mechanical and chemical stabilities, organic–inorganic hybrid materials constitute an emerging research field and have become popular to serve as sorbents in various separaton science methods. Here, we review recent significant advances in analytical solid‐phase extraction employing organic–inorganic composite/nanocomposite sorbents for the extraction of organic and inorganic pollutants from various types of food and environmental matrices. The physicochemical characteristics, extraction properties, and analytical performances of sorbents are discussed; including morphology and surface characteristics, types of functional groups, interaction mechanism, selectivity and sensitivity, accuracy, and regeneration abilities. Organic–inorganic hybrid sorbents combined with extraction techniques are highly promising for sample preparation of various food and environmental matrixes with analytes at trace levels. 相似文献
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Ali Abou‐Hassan Dr. Olivier Sandre Dr. Valérie Cabuil Prof. 《Angewandte Chemie (International ed. in English)》2010,49(36):6268-6286
The application of microfluidics in chemistry has gained significant importance in the recent years. Miniaturized chemistry platforms provide controlled fluid transport, rapid chemical reactions, and cost‐saving advantages over conventional reactors. The advantages of microfluidics have been clearly established in the field of analytical and bioanalytical sciences and in the field of organic synthesis. It is less true in the field of inorganic chemistry and materials science; however in inorganic chemistry it has mostly been used for the separation and selective extraction of metal ions. Microfluidics has been used in materials science mainly for the improvement of nanoparticle synthesis, namely metal, metal oxide, and semiconductor nanoparticles. Microfluidic devices can also be used for the formulation of more advanced and sophisticated inorganic materials or hybrids. 相似文献
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The technological need for new and better soft materials as well as the drive for new knowledge and fundamental understanding
has led to significant advances in the field of nanocomposite gels. A variety of complex gel structures with unique chemical,
physical, and biological properties have been engineered or discovered at the nanoscale. The possibility to form self-assembled
and supramolecular morphologies makes organic polymers and inorganic nanoparticles desirable building blocks for the design
of water based gels. In this review, we highlight the most recent (2004–2008) accomplishments and trends in the field of nanocomposite
polymer hydrogels with a focus on creative approaches to generating structures, properties, and function within mostly biotechnological
applications. We examine the impact of published work and conclude with an outline on future directions and challenges that
come with the design and engineering of new nanocomposite gels. 相似文献
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与无机热电材料相比, 有机热电材料具有资源丰富、 成本低、 质量轻、 柔韧性好及热导率低等优点, 成为热电研究领域关注的热点. 理论和实验结果表明, 低维化和小尺度化是热电材料研究和开发的发展方向. 本文对低维有机热电材料的合成、 器件组装及热电性质的影响因素等进行简要评述, 并对低维有机热电材料的研究方向进行了讨论. 相似文献
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Studies on Hybrid Organic/Inorganic Nanocomposite Gels Using Photoluminescence Techniques 总被引:1,自引:0,他引:1
Vlasoula Bekiari Elias Stathatos Panagiotis Lianos Urska L. Stangar Boris Orel Patrick Judeinstein 《Monatshefte für Chemie / Chemical Monthly》2001,132(1):97-102
Summary. Transparent nanocomposite gels made of hybrid organic/inorganic polymers, synthesized through the sol-gel method, composed
of poly-(ethylene oxide) or poly-(propylene oxide) chains, and grafted on silica through urea bridges, have been studied by
steady-state and time-resolved photoluminescence techniques. These nanocomposite materials consist of two distinguished subphases,
an organic and an inorganic one. The volume fraction of the organic (polyether) subphase is larger than that of the inorganic
(silica) subphase, and it increases with increasing polyether chain size. The condensation of the silica subphase provides
luminescent entities emitting light by electron-hole recombination on delocalized states associated with the active chemical
species of the urea bridges. Materials with smaller polyether chains are more luminescent than such with longer polyether
chains. Divalent or trivalent cations introduced into these materials enhance the luminescence intensity by solubilization
close to the silica cluster surface and thus by decreasing surface defects and the ensuing quenching mechanism.
Received June 23, 2000. Accepted (revised) July 18, 2000 相似文献
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Alain Walcarius 《Electroanalysis》2015,27(6):1303-1340
A review (350 references) is given to the interest of mesoporous materials for designing electrochemical sensors. After a brief summary of the implication of template‐based ordered mesoporous materials in electrochemical science, the various types of inorganic and organic‐inorganic hybrid mesostructures used to date in electroanalysis and the corresponding electrode configurations are described. The various sensor applications are then discussed on the basis of comprehensive tables and some representative illustrations. The main detection schemes developed in the field are (volt)amperometric sensing subsequent to preconcentration and electrocatalytic detection. 相似文献
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The family of fullerene molecules is composed of a large variety of compounds that have been synthesized following the discovery of C60 in 1985. The chemistry of fullerenes, developed in these last years, has allowed designing the properties of this family of molecules for specific applications in materials science. One of the main tasks to build up solid state devices based on fullerenes is the synthesis of materials doped with a highly dispersed and homogeneous distribution of fullerenes. Many of the peculiar photophysical properties, such as the reverse saturable absorption used to obtain a solid state optical limiter, are in fact lost in the aggregates of fullerenes. Sol-gel processing allows preparing inorganic oxides and hybrid organic-inorganic materials at low temperatures and presents an interesting alternative to organic polymers to entrap molecules of the fullerene family in a solid matrix. Porous inorganic solids and aerogels are also important classes of materials that can be synthesized via sol-gel and can act as hosts of fullerenes. In the present article we have reviewed the main achievements of sol-gel processing of fullerene based nanocomposite materials. 相似文献