共查询到20条相似文献,搜索用时 180 毫秒
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
采用毛细管气相色谱内标法代替标准工作曲线法测定偏二甲肼纯度(UDMH),内标法的使用避免了微量进样不准确的缺陷.结果显示,该方法线性范围宽,偏二甲肼的标准曲线相关系数为0.9959,样品加标回收率98.39%,样品的测定标准偏差为0.0015,方法的准确度高、重现性好. 相似文献
12.
研究了Ni/Fe催化剂对废水中偏二甲肼臭氧化分解的催化作用,考察了组分含量、体系的pH值和偏二甲肼初始浓度对催化反应的影响.结果表明,Ni/Fe催化剂对水中偏二甲肼的臭氧化具有良好的催化活性.催化剂组分含量、体系的pH值和初始浓度对反应的影响程度不大.对催化剂的XRD表征结果表明,催化剂主要由尖晶石结构的铁酸盐和FeNi3合金相组成,催化剂的良好催化性能与催化剂中尖晶石结构的铁酸盐和FeNi3合金相的形成有关. 相似文献
13.
STUDY ON PREPARATION OF INORGANIC COMPOSITE MEMBRANE AND ITS PROPERTIES FOR HYDROGEN PERMEATION 下载免费PDF全文
IntroductionDevclopmcntoftcchniqucsforthcscparationofgascousmixturesisofgrcatimportancetochemicalindustries.Rccentadvanccsinceramicmaterialprocessinghavcstimulatedtheeffortstodcvclopccramicormctallicmcmbrancsforgasseparation.Suchmembraneswouldbesuitableforthescparationsathightemperatureatx`hichthcx`ellcstablishedorganicpol}mermcmbranescannotfunctionButmostcommercialceramicmembranesxvhichcanbcobtainedinmarkctaremicroporous(porediamcterfromO.ItoloPm)whereseparationmcchanismisgovcrncdbyKnudscnd… 相似文献
14.
Alexander D. Smolenkov Pavel P. Krechetov Andrey V. Pirogov Tatiana V. Koroleva Alexander A. Bendryshev Oleg A. Shpigun 《International journal of environmental analytical chemistry》2013,93(14):1089-1100
A new procedure for the determination of 1,1-dimethylhydrazine (UDMH) in soil samples was developed. This involves the distillation of UDMH from an alkaline suspension of soil and ion chromatographic analysis of the distillate. The separation was performed on a silica cation-exchanger column with ammonium acetate buffer solution as mobile phase and amperometric detection at +1.2?V. Hydrazine (Hy) and methylhydrazine (MH), which are decomposition products of UDMH, can be determined simultaneously. The limits of detection in aqueous solutions were 0.2, 0.5 and 1?µg?L?1 for Hy, MH and UDMH, respectively. The developed technique was used for investigating the behaviour of UDMH in spills of rocket fuels on soils. It was found that the addition of 4?kg?m?2 UDMH resulted in a 0.02% residue one year after the soil treatment. The vertical migration of UDMH in soil was less than 50?cm. 相似文献
15.
16.
Dense tubular Ba0.5Sr0.5Co0.8Fe0.2O3−δ (BSCFO) membranes were successfully prepared by the plastic extrusion method. The oxygen permeation flux was determined at different oxygen partial pressures in the shell side and different temperatures between 700 and 900 °C. The oxygen vacancy diffusion coefficients (Dv) at different temperatures were calculated from the dependence of oxygen permeation flux on the oxygen partial pressure term based on the surface current exchange model. No unsteady-state of oxygen permeation flux was observed at the initial stage in our experiments. The reason is the equilibrium time is too short (less than 10 min) to observe the unsteady-state in time. The increase of the helium flow rate can increase the oxygen permeation flux, which is due to the decrease of the oxygen partial pressure in the tube side with increasing of the helium flow rate. The oxygen permeation flux can also be affected by the air flow rate in the shell side when the air flow rate is lower than 150 ml/min. But the oxygen permeation flux is insensitive to the air flow rate when the air flow is higher than 150 ml/min. The membrane tube was operated steadily for 150 h with oxygen permeation flux of 1.12 ml/(cm2 min) at 875 °C. X-ray diffraction (XRD) and energy dispersive spectroscopy (EDS) analysis showed that both the surface exposed to air and the surface exposed to helium of the BSCFO membrane tube after permeation for 150 h are similar to the fresh membrane tube in composition and structure. These results indicated that the membrane tube exhibits high structure stability. 相似文献
17.
18.
澄清溶液中NaA型分子筛膜的合成及气体渗透性能 总被引:1,自引:0,他引:1
The use of zeolite membranes in separation or combined reaction and separation processes is very attractive. Advantages of using such a type of membranes include their ability to discriminate molecules based on the molecular size and their stability[1]. In the past ten years, most efforts were involved in the synthesis and permeation studies of MFI zeolite membrane[2, 3]. Recently, NaA zeolite membrane has attracted much attention because of its high potential in the dehydration of organic liquids[4]. However, few gas permeation results were reported[5]. Furthermore, most of the NaA zeolite membrane was synthesized from gel[4]. In this letter, the synthesis of NaA zeolite membrane from clear solution and its gas permeation properties are reported. 相似文献
19.
T. V. Belysheva E. A. Kazachkov L. P. Bogovtseva V. N. Kubyshkin V. M. Vokhontsev 《Journal of Analytical Chemistry》2006,61(7):683-686
Some n-type semiconductor metal oxide sensors based on WO3 and In2O3 were studied in detecting unsymmetrical dimethylhydrazine (UDMH) vapors. The sensors are highly sensitive to the presence of UDMH vapors in air at concentrations equal to or lower than the MPC. They have short response and relaxation times in detecting UDMH vapors in air. It was found that, when ammonia was present in air in concentrations comparable to those of UDMH, it did not affect the electrophysical properties of the semiconductor sensors. 相似文献
20.
Screening of transformation products in soils contaminated with unsymmetrical dimethylhydrazine using headspace SPME and GC-MS 总被引:1,自引:0,他引:1
The paper describes a novel SPME-based approach for sampling and analysis of transformation products of highly reactive and toxic unsymmetrical dimethylhydrazine (UDMH) which is used as a fuel in many Russian, European, Indian, and Chinese heavy cargo carrier rockets. The effects of several parameters were studied to optimize analyte recovery. It was found that the 85 μm Carboxen/polydimethylsiloxane fiber coating provides the highest selectivity for selected UDMH transformation products. Optimal sampling/sample preparation parameters were determined to be 1-h soil headspace sampling time at 40 °C. The GC inlet temperature was optimized to 170 °C held for 0.1 min, then 1 °C s−1 ramp to 250 °C where it was held for 40 min. Temperature programing resulted in a fast desorption along with minimal chemical transformation in the GC inlet. SPME was very effective extracting UDMH transformation products from soil samples contaminated with rocket fuel. The use of SPME resulted in high sensitivity, speed, small labor consumption due to an automation and simplicity of use. It was shown that water addition to soil leads to a significant decrease of recovery of almost all target transformation products of UDMH. The use of SPME for sampling and sample preparation resulted in detection of the total of 21 new compounds that are relevant to the UDMH transformation in soils. In addition, the number of confirmed transformation products of UDMH increased from 15 to 27. This sampling/sample preparation approach can be recommended for environmental assessment of soil samples from areas affected by space rocket activity. 相似文献