| 偏二甲肼纯度分析方法的改进 |
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| 引用本文： | 杨宝军,陈建平,焦天恕,李志鲲,梁开伦,吕功煊.偏二甲肼纯度分析方法的改进[J].分析测试技术与仪器,2006,12(4):243-245. |
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| 作者姓名： | 杨宝军 陈建平 焦天恕 李志鲲 梁开伦 吕功煊 |
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| 作者单位： | 1. 中国科学院,兰州化学物理研究所,羰基合成与选择氧化国家重点实验室,甘肃,兰州,730000
2. 中国酒泉卫星发射中心,甘肃,酒泉,732750 |
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| 摘 要： | 采用毛细管气相色谱内标法代替标准工作曲线法测定偏二甲肼纯度(UDMH),内标法的使用避免了微量进样不准确的缺陷.结果显示,该方法线性范围宽,偏二甲肼的标准曲线相关系数为0.9959,样品加标回收率98.39%,样品的测定标准偏差为0.0015,方法的准确度高、重现性好.
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| 关 键 词： | 偏二甲肼 纯度 毛细管气相色谱 内标法 |
| 文章编号： | 1006-3757（2006）04-0243-03 |
| 收稿时间： | 2006-09-29 |
| 修稿时间： | 2006-10-23 |
Improved Analytical Method for Determining the Purity of Unsymmetrical Dimethylhydrazine |
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| YANG Bao-jun,CHEN Jian-ping,JIAO Tian-shu,LI Zhi-kun,LIANG Kai-lun and LU Gong-xuan.Improved Analytical Method for Determining the Purity of Unsymmetrical Dimethylhydrazine[J].Analysis and Testing Technology and Instruments,2006,12(4):243-245. |
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| Authors: | YANG Bao-jun CHEN Jian-ping JIAO Tian-shu LI Zhi-kun LIANG Kai-lun and LU Gong-xuan |
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| Institution: | 1. State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, CAS, Lanzhou 730000,China; 2. China Jiuquan Satellite Launch Center, Jiuquan 732750,China |
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| Abstract: | Capillary gas chromatographic internal standard method was used to determine the purity of unsymmetrical dimethylhydrine(UDMH) instead of the standard working curve method.Weakness of trace impouring imprecisely was avoided by using internal standard method.The results showed that the method has broad linear scope and the correlation coefficient for UDMH is 0.9959.The average recovery for the sample is 98.39% and standard deviation is 0.0015.In addition,this method had high accuracy and good repeatability. |
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| Keywords: | unsymmetrical dimethylhydrazine purity capillary gas chromatography internal standard method |
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