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Eu(MBA)2NO3Phen配合物的发光光谱 总被引:6,自引:0,他引:6
在77K测定了Eu(o-MBA)_2NO_3Phen和Eu(m-MBA)_2NO_3Phen配合物的激发光谱,发光光谱和时间分辨光谱。光谱数据说明由于邻甲基的位阻影响,在Eu(o-MBA)_2NO_3Phen配合物里存在化学环境稍有不同的两种Eu ̄(3+)格位,它们的局部对称性分别为c_2v和c_1,c_2或c_s。在Eu(m-MBA)_2NO_3Phen配合物里,仅存在一种Eu ̄(3+)格位,它类似于前一个配合物的c_2v对称性的Eu ̄(3+)格位。 相似文献
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三元体系Y(ClO4)3·3H2O—B15C5—CH3OH(25℃)的半微量相平衡研究 总被引:1,自引:0,他引:1
采用半微量相平衡方法研究了三元体系Y(ClO4)3.3H2O-B15C5-CH3OH在25℃的溶解度,测定了各饱和溶液的折光率。该体系在25℃生成三种化学计量的配合物,其组成分别为:4Y(ClO4)3.3B15C5.12H2O.12Ch3OH(I),Y(ClO4)3.2B12C5.3H2O.Ch3OH(Ⅲ),其中配合物(I)和(Ⅱ)是溶解不一致化合物。在甲醇溶剂中,分离制备了配合物(Ⅲ),在69- 相似文献
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合成了3种以4,4'-联吡啶为桥联配体的三核环状Cu(Ⅱ)配合物[Cu_3(4,4'-bpy)_3·(phen)_3](ClO_4)_6·2H_2O(1)、[Cu_3(4,4'-bpy)_3](bpy)_3](ClO_4)_6·H_2O(2)和[Cu_3(4,4'-bpy)_3·(NO_2-phen)_3](ClO_4)_6·6H_2O(3)。经元素分析、电导、IR、电子光谱、ESR、磁化率等方法进行了表征,推定该配合物具有以4,4'-联吡啶为扩展桥的结构。利用Heisenberg模型求得交换参数J值为-0.23cm-1(1)和-0.90cm-1(3),表明配合物中金属离子间仅有很弱的反铁磁交换作用. 相似文献
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采用半微量相平衡方法研究了三元体系Y(ClO4)3·3H2O-B15C5—CH3OH在25℃的溶解度,测定了各饱和溶液的折光率.该体系在25℃生成三种化学计量的配合物,其组成分别为:4Y(ClO4)3·3B15C5·12H2O·12CH3OH(Ⅰ)、Y(ClO4)3·B15C5·3H2O·1.5CH3OH(Ⅱ)与Y(ClO4)3·2B15C5·3H2O·CH3OH(Ⅲ),其中配合物(Ⅰ)和(Ⅱ)是溶解不一致化合物.在甲醇溶剂中,分离制备了配合物(Ⅲ),在69—72℃下干燥得到配合物Y(ClO4)3·2B15C5·3H2O.利用IR光谱、电导测量及X-射线衍射分析对配合物进行了表征. 相似文献
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用溶胶-凝胶法以磷钼酸(MPA)的镍盐溶液水解钛酸四丁酯制备了NiPMo/TiO2催化剂.使用ICP、 XRD、 TG-DTA、 IR、 TPD-MS和微反应技术研究了催化剂的化学组成、热稳定性、化学吸附性质和催化反应性能.杂多钼酸盐与TiO2通过O2-在TiO2表面发生了键合.在623 K下,杂多阴离子仍保持原有的Keggin结构.CO2在Lewis酸位Ni(Ⅱ)和Lewis碱位Ni-O-Mo的桥氧协同作用下生成CO2卧式吸附态Ni(Ⅱ)←O-(CO)←(O--Ni).丙烯有多种吸附态在催化剂上吸附.在563 K、 1 MPa和空速1500 h-1的反应条件下,丙烯的摩尔转化率为3.2%,产物MAA选择性为95%. 相似文献
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Different approaches for the synthesis of 1-benzyloxypyrazin-2(1H)-one derivatives from simple amino acids have been investigated. A library of 33 precursors for the preparation of N-hydroxy pyrazinones was obtained in moderate to good yields. 相似文献
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A general synthesis of previously unknown semicarbazone-based α-amidoalkylating reagents, 4-(tosylmethyl)semicarbazones, has been developed. The synthesis involved three-component condensation of semicarbazones of aliphatic or aromatic aldehydes with the same or other aldehydes and p-toluenesulfinic acid. The scope and limitations of this reaction were investigated. The compounds obtained were demonstrated to be an efficient α-(4-semicarbazono)alkylating agents. They were reacted with H- (sodium borohydride), O- (sodium methylate), S- (sodium phenylthiolate), N- (pyrrolidine, sodium succinimide), P- (trialkyl phosphites), and C-nucleophiles (sodium diethyl malonate) to give the corresponding products of the tosyl group substitution, 4-substituted semicarbazones, including analogues of nitrofurazone. Among the prepared compounds tested in vitro for antibacterial and antifungal activity, three nitrofuryl-containing semicarbazones exhibited high biological activities with minimum inhibitory concentration (MIC) values of 8–32 μg/mL. 相似文献
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A small library of new chiral bidentate hydroxyalkyl-imidazolium salts 1 is conveniently synthesized on multi-gram scale from inexpensive and commercially available chiral pool amino acids. The corresponding carbenes, generated by deprotonation of imidazolium salts 1, in combination with palladium(II) chloride were tested in the Mizoroki–Heck coupling reaction. The most significant results in terms of yields and reactivities were achieved with low catalyst loading. The catalytic activities of these imidazolium salts were also investigated in the asymmetric addition of diethylzinc to benzaldehyde. The use of MgO nanoparticles as an additive in conjunction with these ligands played a crucial role in increasing the efficiency of these reactions. 相似文献
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Uroš Grošelj Mojca Žorž Amalija Golobič Branko Stanovnik Jurij Svete 《Tetrahedron》2013,69(52):11092-11108
A new and simple synthesis of novel N-protected methyl 5-substituted-4-hydroxypyrrole-3-carboxylates, which exist in equilibrium with their 4-oxo tautomers, has been developed in two steps starting from N-protected α-amino acids. The key intermediates are enaminones, which can also be isolated, characterized, and used for the construction of other functionalized heterocycles, before they spontaneously decompose to pyrrole products. 4-Hydroxypyrroles are prone to partial aerial oxidation but can be efficiently alkylated or reduced to stable polysubstituted pyrrolidine derivatives. 相似文献
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The chemoselectivity in the intramolecular CH insertion of various diazosulfonamides has been experimentally studied. The results reveal that the aliphatic 1,4-, 1,5-, or 1,6-C(sp3)?H insertions of diazosulfonamides are not accessible, while the aromatic 1,5-C(sp2)?H insertion can be realized specifically by adjusting the diazo-adjacent group. In addition, the general chemoselectivities in the intramolecular CH insertions of diazosulfonyl compounds are summarized. Generally, diazosulfones undergo both aromatic 1,5-C(sp2)?H and aliphatic 1,5- and 1,6-C(sp3)?H insertions, while diazosulfonates undergo aliphatic 1,5- and 1,6-C(sp3)?H insertions. However, diazosulfonamides only undergo aromatic 1,5-C(sp2)?H insertion. 相似文献
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The Langevin paramagnetic theory can’t describe the relation between magnetization of ferrofluids and applied magnetic field. The structuralization of ferrofluids, which is considered the main influence factor of the magnetization, is regarded. The part of magnetization works is deposited when the structure is forming. This action influences the magnetization of ferrofluids directly or indirectly. On the base of the “compressing” model, the Langevin function that usually describes the magnetization of ferrofluid is modified, and a well-fitted curve is obtained. An equation of the relation between the equivalent volume fraction after being “compressed” and the intensity of magnetic field is discovered, which approximately describes the process of magnetization. The relation between the approximate initial susceptibility and the volume fraction can be obtained from modified formula. 相似文献
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Microwave-assisted copper-catalyzed ring expansions of three-membered heterocycles with α-diazo-β-dicarbonyl compounds were investigated. Thiiranes generated 3-acyl-5,6-dihydro-1,4-oxathiines in the presence of copper sulfate and trans-3-acyl-5,6-dihydro-1,4-oxathiines as stereospecific products for 1,2-disubstituted cis-thiiranes through an intramolecular SN2 process. Oxiranes gave rise to 2-acyl-5,6-dihydro-1,4-dioxines under the catalysis of copper hexafluoroacetylacetonate and cis-3-acyl-5,6-dihydro-1,4-dioxines as stereospecific products for 1,2-disubstituted cis-oxiranes via an intimate ion-pair mechanism. The current method provides a direct and simple strategy in efficient preparation of 3-acyl-5,6-dihydro-1,4-oxathiines and 2-acyl-5,6-dihydro-1,4-dioxines, important agents in medicinal and agricultural chemistry, from readily available thiiranes and oxiranes, respectively. 相似文献
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Rebecca J. Burton Mandy L. CrowtherNeal J. Fazakerley Shaun M. FilleryBarry M. Hayter Jason G. KettleCaroline A. McMillan Paula PerkinsPeter Robins Peter M. SmithEmma J. Williams Gail L. Wrigley 《Tetrahedron letters》2013
The highly regioselective Buchwald–Hartwig amination at C-2 of the cheap and readily accessible reagent, 2,4-dichloropyridine with a range of anilines and heterocyclic amines is described. This new methodology is robust and provides a facile access to 4-chloro-N-phenylpyridin-2-amines on 0.25 mol scale. These intermediates undergo a further Buchwald–Hartwig amination at higher temperature to enable rapid exploration of the chemical space at C-4 and to provide a library of 2,4-bisaminopyridines. 相似文献
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N-Heterocyclic carbene-palladacyclic complexes 3 were successfully achieved in a one-pot procedure under mild conditions. The structure of 3a was unambiguously confirmed by X-ray single crystal diffraction and it was an active catalyst in the Buchwald-Hartwig amination and α-arylation of ketones even at very low catalyst loadings (0.01?mol%). 相似文献