手性分子反-2,3-环氧丁烷的旋光拉曼光谱研究

本文从拉曼峰强出发,求得了反-2,3-环氧丁烷分子的拉曼键极化率,明确了拉曼激发下电荷的分布的信息.还从旋光拉曼(Raman optical activity,ROA)谱的峰强,求取了该分子的旋光拉曼键极化率.由分子手性中心的C-H产生的偶极矩与拉曼激发过程中,电荷流动产生的跃迁磁偶极矩的耦合,来理解旋光拉曼活性产生的机理.分析表明,旋光拉曼活性分子手性中心的C-H键两侧的旋光拉曼极化率符号相反,显示着手性分子局域的不对称性.还得到了对称和反对称坐标的键极化率和旋光拉曼极化率,并且从对称性的角度,即C2群的不可约表示,讨论了这些极化率的内涵.     

微米手性晶粒凝胶玻璃的制备及其消偏振效应

采用干法粉碎法将具有手性特征的块体水晶粉碎成粒径为70μm的手性晶粒，利用溶胶-凝胶法，将粒径为70μm的手性晶粒均匀地撒入凝胶基质中，制成厚度为4mm的含微米手性晶粒的凝胶玻璃，发现其表现出了消偏振效应.而将微米手性晶粒替换成同样尺寸粒径的玻璃粉体，以同样方法制成的相同厚度的含微米玻璃粉体的凝胶玻璃却表现出线偏振保持的性能.分析了此现象发生的原因. 关键词： 手性晶粒 溶胶-凝胶 消偏振     

基于折线形手征负折射介质结构的设计与仿真

分别设计和仿真了一种新型的工作在微波段和光波段的折线形手征介质结构.利用仿真得到的透射系数和反射系数反演计算了该结构的旋光角、椭偏度、相对介电常数、相对磁导率、手征参数以及折射率等参数.结果表明该结构在这两种波段下都显示出极大的旋光角和椭偏度,且因具有大的手征参数,而不再需要介电常数和磁导率同时为负就可实现左旋圆极化波(LCP)和右旋圆极化波(RCP)的负折射率. 关键词： 手征介质 旋光角 椭偏度 负折射率     

木榄醇手性光谱的密度泛函研究

手性光学理论研究有助于解释手性分子的旋光机理和设计新的手性药物.采用B3LYP方法,计算了木榄醇A—C的旋光度和圆二色谱.从分子结构、正则振动和电子结构方面,探索了分子手性微观起源,分析了旋光度和电子圆二色谱的溶剂效应.表明OH的引入可调节分子的手性,甲基和苯环加强了分子的手性.发生在手性骨架上的振动和电子跃迁,加强了分子的手性.溶剂效应减小旋光度、削弱电子圆二色谱. 关键词： 木榄醇 光学活性 密度泛函理论 圆二色谱     

雷达波吸收剂的包覆改性设计

从电磁场理论出发，建立了包覆改性吸收剂等效电磁参数模型，初步得到了磁性吸收剂经介电改性后外包覆层和内层材料相对体积分数对损耗性能和特性阻抗的影响规律；以此为基础，进行了包覆改性吸收剂的结构设计；采用溶胶-凝胶法制备了包覆改性吸收剂，实验测试了样品的电磁参数，同理论预测结果进行了比较，表明理论预测的电磁参数频谱特性同实际测试结果比较接近. 关键词： 包覆改性吸收剂 等效电磁参数     

SiO2薄膜中咔唑的发光特性

利用溶胶-凝胶工艺制备了含咔唑的SiO2薄膜,实验测量了薄膜样品的光致发光特性.结果发现：样品不仅能发射红光,并且当激发波长从610 nm连续减小到400 nm时,其发射谱峰位又能从760 nm连续蓝移到550 nm左右.薄膜样品的荧光特性随激发波长而改变的现象可归因于咔唑分子被紧缩在凝胶内部的微孔中受到挤压而导致共轭尺寸发生变化.     

最新科技动态

手征性介观多孔硅的合成及特性手征性广泛地用来描述有机材料,特别是生物分子、蛋白质等.但无机材料中大尺度手征性则很少见.最近中外科学家合作报道了在表面活化板上合成手征性介观多孔硅的结果及电镜结构分析,他们制备的材料具有螺旋六角棒状形态,直径130nm～180nm,长1nm～6n     

基于透射光谱确定溶胶凝胶ZrO2薄膜的光学常数

基于溶胶凝胶ZrO2薄膜的紫外/可见/近红外透射实验光谱,采用Swanepoel方法结合Wemple-DiDomenico色散模型,方便地导出了ZrO2薄膜在200-1200 nm波长范围内的光学常数,包括折射率、色散常数、膜层厚度、吸收系数及能量带隙.研究发现,溶胶凝胶ZrO2薄膜具有高折射率(1.63-1.93,测试波长为632.8 nm)、低吸收和直接能量带隙(4.97-5.63 eV) 等光学特性,而且其光学常数对薄膜制备过程中的重要工艺参数--膜层后处理温度表现出强烈的依赖性.此外,在膜层的弱吸收和中等吸收光谱区域内,计算得到的折射率色散曲线与分光光度法的测试结果基本符合,说明本实验中所建立的计算方法在确定溶胶凝胶ZrO2薄膜光学常数方面的可靠性.     

手性分子2, 3-丁二醇的旋光拉曼光谱研究

本文从拉曼峰和旋光拉曼峰出发,通过键极化率和微分键极化率分析研究(2R, 3R)-2, 3-丁二醇. 通过分子C₁和C₂两种点群的优化结构,获得不依赖于这两种结构的结果 和有关这个手性系统物理图像的丰富信息.对分子拉曼键极化率分析,得出在拉曼弛豫过程中, 电荷主要从外围流向骨架结构.对分子微分键极化率的分析,显示在不对称C原子和与其相联系的H原子 两侧化学键, C-O和C-CH₃的微分键极化率的符号正好相反,意味着这个分子具有相当好的手性 不对称性质.对比对称和反对称的键极化率、微分键极化率,本文得到这样的结论: 对于(特别是键伸缩的)键极化率,(大体上是)对称的大于反对称的; 而对于微分键极化率则是反对称的大于对称的. 关键词： 旋光拉曼 键极化率 微分键极化率 2,3-丁二醇     

平板波导的溶胶-凝胶法制备与测试

利用溶胶-凝胶法制作了平板波导.实验中,在不同的条件下采用溶胶-凝胶法在玻璃衬底上制备出TiO2平板波导,分析了影响平板波导的因素,如溶胶-凝胶溶液的浓度、pH值,滴胶速度,热处理等.并对在不同工艺条件下的波导膜特性进行了测试,分析了影响波导膜质量的各个因素.实验表明,在控制实验条件的前提下溶胶-凝胶法在制作平板波导膜的工艺上制作方法简单,容易实现.     

Effective electromagnetic and chiral parameters of chiral composite material

The effective parameters of chiral composite are studied using a simple model, that is, randomly oriented non-interacting wire helices embedded in a nonchiral host medium. It is found that both the effective permittivity and permeability are independent on the handedness of the chiral objects while the effective chirality admittance is dependent. It is also found that when the ratio of the radius of the chiral helix to its pitch is about 0.23, maximum chirality admittance is achieved. The effective parameters of equichiral sample are also discussed.     

电磁波在旋波介质中的传播特性研究

介绍了旋波介质的结构特征，讨论了旋波材料的电磁性质和物质方程，结合麦克斯韦方程和边界条件。给出了电磁波入射介质的反射系数和透射系数。，     

A systematical study of the chiral magnetic effects at the RHIC and LHC energies

Considering the magnetic field response of the QGP medium,we perform a systematical study of the chiral magnetic effect(CME),and make a comparison with the experimental results for the background-subtracted correlator H at the energies of the RHIC Beam Energy Scan(BES)and the LHC energy.The CME signals from our computations show a centrality trend and beam energy dependence that are qualitatively consistent with the experimental measurements of the charge dependent correlations.The time evolution of the chiral electromagnetic current at the RHIC and LHC energies is systematically studied.The dependence of the time-integrated current signal on the beam energy√s with different centralities is investigated.Our phenomenological analysis shows that the time-integrated electromagnetic current is maximal near the collision energy√s≈39 GeV.The qualitative trend of the induced electromagnetic current is in agreement with the CME experimental results at the RHIC and LHC energies.     

W-geometry from chiral embeddings

Recent work by Y. Matsuo and the present author is summarized. It is shown that, classically, the conformal Toda equations associated with the simple lie algebras A_n sl (n + 1) follow from the embedding of particular 2D surfaces in CPⁿ. Since these Toda theories provide Noether realizations of W-symmetries, this gives the geometrical interpretation of the corresponding two-dimensional physics.     

相对论重离子碰撞手征电荷分离效应的研究

相对论重离子碰撞的拓扑荷作用破坏作用平面两侧不同手征性的夸克数目的平衡,从而引起P和CP破坏特征。本工作主要分析RHIC和LHC能区的手征电荷分离作用,分析手征电荷分离随碰撞中心度、碰撞能量和核屏蔽等依赖关系。并未发现手征电荷分离效应与碰撞能量大小有非常紧密的依赖关系,但发现核屏蔽效应对手征电荷分离有重要的影响,与不考虑屏蔽效应相比,考虑屏蔽效应会使手征分离效应明显压低,由于屏蔽效应出现,使得a₊₊（a_--）的分布与a_+-（a_-+）分布并不对称。并且还发现手征分离效应主要发生在碰撞参量较大的周边碰撞,越接近中心碰撞,手征分离效应几乎可以忽略。The topological charge interactions in relativistic heavy ion collisions cause quark chirality imbalance, resulting in charge separation under the strong magnetic field and local P and CP violation. In this paper, the chiral charge separation at RHIC and LHC energies is systematically analyzed as functions of the collision centrality, the collision energy and the nuclear shielding factor. It is found that there is not a very close dependence of the chiral charge separation effect on the collision energies, but that has an important dependence on nuclear shielding factor. Compared with the non-shielding effect, the shielding effect can reduce the chiral separation effect obviously. Due to the shielding effect, the distribution of a₊₊(a_--) and the distribution of a_+-(a_-+) are asymmetric. One also finds that chiral separation effect, which is almost negligible when more close to the central collision, occurs mainly in the peripheral collision for larger impact parameter.     

水溶性镧系位移试剂对羟基脯氨酸的手性识别

用¹H NMR和¹³ C NMR研究了水溶性镧系位移试剂Sm-pdta对反式-4-羟基脯氨酸的手性识别. 反式-4-羟基脯氨酸与Sm-pdta形成络合物后,其¹H NMR和¹³C NMR图谱的化学位移有所变化,手性碳附近的某些原子所对应的吸收峰裂分为2组信号,分别对应反式-4-羟基脯氨酸的两种对映异构体. 结果显示,对于反式-4-羟基脯胺酸, Sm-pdta是一个既方便又有效的手性位移试剂.     

Mixing of scalar meson and baryon-baryon interaction

At quark level,we study the effect of ideal mixing of singlet σ 0 and octet σ 8 scalar mesons on baryon-baryon interaction in the chiral SU（3） quark model.We solve the resonating group method equation for scattering process and bound state.The results show that the binding energy of deuteron and nucleonnucleon and hyperon-nucleon scattering data can be reasonably described for ideal mixing.Taking the same parameters we used in the scattering calculation,we further investigate the possible dibaryons and find the binding energy of （ΩΩ） ST =00 and （Ξ ＊Ω） ST =0 1 2 can be reduced a lot for ideal mixing.     

Chiral effective Lagrangian for excited heavy-light mesons from QCD

We derive the chiral effective Lagrangian for excited heavy-light mesons from QCD under proper approximations. We focus on the chiral partners with j_l~P=3+/2 and j_l~P=3~-/2 which amounts to(1~+, 2~+) and(1~-, 2~-) states respectively. The low energy constants including the masses of the chiral partners are calculated. The calculated spectrum for the excited mesons are found roughly consistent with experimental data. In addition, our results indicate that quantum numbers of B_J(5970) can be identified with 1~-or 2~-.     

Chiral SU（3） Quark Model Study of Tetraquark States： cnn^-s^-/css^-s^-

The new members of the charm-strange family Dsj^＊（2317）, Dsj（2460）, and Ds（2632）, which have the surprising properties, are challenging the present models. Many theoretical interpretations have been devoted to this issue. Most authors suggest that they are not the conventional cs^- quark model states, but possibly are four-quark states, molecule states, or mixtures of a P-wave cs^- and a four-quark state. In this work, we follow the four-quark-state picture, and study the masses of cnn^-s^-/css^-s^- states （n is u or d quark） in the chiral SU（3） quark model. The numerical results show that the mass of the mixed four-quark state （cnn^-s^-/css^-s^-） with spin parity j^P ： 0^＋ might not be Ds （2632）. At the same time, we also conclude that Dsj^＊（2317） and Dsj（2460） cannot be explained as the pure four-quark state.