红外紫外双色光谱的产生

本文给出了在红外光谱多外利用热受激后的原子材料产生紫外光谱的方法。文中给出了计算数据和实验结果。     

高光谱遥感器的光谱定标

高光谱遥感器光谱性能参数的准确定标是高光谱遥感器数据定量应用的基本前提。本文基于单色准直光标定法对高光谱遥感器进行了光谱性能参数定标,通过数据采集软件及数据处理软件对高光谱遥感器光谱性能参数定标数据进行了分析。分析结果显示:定标测试的重复性在1 h内小于0.2 nm,在20 h内小于0.35 nm。光谱定标结果表明:高光谱遥感器的平均光谱分辨率为4.94 nm,且各高光谱遥感器空间维光谱分辨率均小于5 nm,典型谱段的平均带宽均在6 nm左右。     

基于光谱分类的端元提取算法研究

目前成熟的端元提取算法是基于单形体几何学的像元纯度指数(PPO)算法,N-FINDR,VCA等算法.这些算法从图像所有像元中提取纯光谱,具有提取速度慢、精度不高的缺点;部分算法需要进行光谱降维,不利于小目标信息的提取.该文提出先利用基于空间特征的光谱分类算法进行分类,将格个图像划分成空间相邻、光谱相似的若干类,每一类的...     

广义二维相关光谱技术及其应用

广义二维相关光谱技术目前逐渐成为光谱分析中广泛应用的研究方法,综述了其历史发展、基本原理、获取谱图方法、数学计算过程、谱图性质及其解释规则,并介绍了二维红外、近红外、拉曼和荧光光谱相关光谱技术在各个领域中的应用,展望了广义二维相关光谱技术的发展趋势.     

多孔硅的时间延迟光谱

利用时间延迟光谱技术测量了多孔硅的发光光谱. 实验结果表明,多孔硅的发光是复杂的动力学发光弛豫过程,时间延迟光谱测量技术在研究复杂动力学发光过程方面比稳态光谱测量方法更有效.     

TixY1-xBa2Cu3O7-δ超导体的红外、远红外光谱

本文报道了Ti_xY_1-xBa₂Cu₃O_7-δ(x=0.2和0.4)在4.2—300K的红外、远红外光谱。在50—360cm^-1波段内发现七个反射峰。它们分别与Ba,Cu,O离子团,Y,O离子团。Ti,O离子团,以及Cu—O键的振动有关,对于x=0.2的样品,存在两个反转结构。对于x=0.4的样品,则仅发现一个反转结构。在红外光谱中观察到六个反对峰和三个吸收峰,它们的强度大多随Ti含量的增加而增强。与Y₁Ba₂Cu₃O_7-δ的光谱结果比校,讨论了声子峰及反转结构的物理起因。 关键词：     

基于光谱靶标的光学遥感器退化特性在轨评估方法研究

多光谱遥感器在轨运行期间,受化学分子污染、发射振动、宇宙辐射等因素的影响,其光谱响应特性会发生变化,使目标物理量的测量值产生偏差,且不能用辐射定标进行校正,影响数据产品序列的一致性。提出了一种基于光谱靶标的光谱响应退化特性在轨评估方法,通过建立响应函数退化模型,并利用光谱靶标反射率在检测波段内呈非线性变化的特性来实现对光谱响应函数退化情况的定量化评估。模拟仿真与外场实验结果初步验证了本文方法的有效性,该方法在提高辐射定标精度和优化遥感器设计等方面有重要意义。     

共振光散射的时间量子理论

本文发展了Ｓｃｈｏｍｍｅｒｓ的时间观点，定义了时间，尤其是表征量子系统光散射的散射时间和共振散射时间。通过散射时间本征态的假定实现了散射时间的量子化，得到了量子化的共振散射时间。对原子的弹性光散射和Ｒａｍａｎ散射的成功应用推出了原子和原子的价电子逐级电离所形成的离子的所有原子能级的普适近似公式。     

Nonlinear spectroscopic effects in quantum gases induced by atom-atom interactions

We consider nonlinear spectroscopic effects—interaction-enhanced double resonance and spectrum instability—that appear in ultracold quantum gases owing to collisional frequency shift of atomic transitions and, consequently, due to the dependence of the frequencies on the population of various internal states of the particles. Special emphasis is put to two simplest cases, (a) the gas of two-level atoms and (b) double resonance in a gas of three-level bosons, in which the probe transition frequency remains constant.     

Three-Photon Resonant Nondegenerate Six-Wave Mixing in a Dressed Atomic System

We report a three-photon resonant nondegenerate six-wave mixing （NSWM） in a dressed cascade five-level system. It has advantages that phase match condition is not stringent and NSWM signal is enhanced tremendously due to the multiple resonance with the atomic transition frequencies. In the presence of a strong coupling field, the threephoton resonant NSWM spectrum exhibits＂ Autler-Townes splitting. This technique provides a spectroscopic tool for measuring not only the resonant frequency and dephasing rate but also the transition dipole moment between two highly excited atomic states.     

Force spectroscopy in noncontact mode

We have analyzed the possibility of using noncontact scanning force microscopy (NCAFM) to detect variations in surface composition, i.e., to detect a ‘spectroscopic image' of the sample. This ability stems from the fact that the long-range forces, acting between the AFM tip and sample, depend on the composition of the AFM tip and sample. The long-range force can be magnetic, electrostatic, or van der Waals forces. Detection of the first two forces is presently used in scanning force microscopy technique, but van der Waals forces have not been used. We demonstrate that the recovery of spectroscopic image has a unique solution. Furthermore, the spectroscopic resolution can be as good as lateral one.     

Effect of time delay in FitzHugh-Nagumo neural model with correlations between multiplicative and additive noises

We study the effect of time delay in the FitzHugh-Nagumo neural model with correlations between multiplicative and additive noise terms. Based on the corresponding Fokker-Planck equation, the explicit expressions of the stationary probability distribution function (SPDF), the mean first passage time (MFPT) and the signal-to-noise ratio (SNR) are obtained, respectively. Research results show that: (i) the system undergoes a succession of two phase transitions (i.e., the reentrance phenomenon) as the noise correlation parameter is increased and a (single) phase transition as the time delay is increased. (ii) The MFPT as a function of the multiplicative noise intensity exhibits a maximum. This maximum for MFPT identifies the noise enhanced stability (NES) effect, the noise correlation parameter intensifies the NES effect while the time delay, and the additive noise intensity weakens it. (iii) The existence of a maximum in the SNR as a function of the multiplicative noise intensity is the identifying characteristic of the stochastic resonance (SR) phenomenon, the noise correlation parameter enhances the SR while the time delay, and the additive noise intensity weaken it.     

Four Wave Mixing spectroscopy at the interface between the time and frequency domains

We demonstrate a new approach to Four Wave Mixing spectroscopy involving simultaneous measurements at time and frequency domains, where spectral selectivity is achieved by phase matching filtering, and the time resolution is obtained within a single ultra-short pulse. We analyze the Four Wave Mixing signal, and show that our method is capable for discrimination between different spectroscopic pathways of vibrational coherences modulating the scattered signal.     

镁Mg3s~(21)S_0-3s3d~1D_2单光子电四极矩跃迁的研究

用原子束技术—激光共振电离—飞行时间质谱探测离子信号的方法，观察到了原子束中镁Ｍｇ３ｓ２１Ｓ０－３ｓ３ｄ１Ｄ２单光子电四极矩共振跃迁，并对实验结果进行了判断和分析。     

Probe field spectroscopy in three-level Λ systems under arbitrary collisional relaxation of low-frequency coherence

We investigate theoretically the spectrum of weak probe field absorption by three-level atoms with the Λ configuration of levels in the field of a strong electromagnetic wave acting on an adjacent transition and colliding with buffer gas atoms. Analysis is carried out for the general case of arbitrary collisional relaxation of low-frequency coherence at a transition between two lower levels. It is shown that, in the absence of collisional relaxation of low-frequency coherence, the probe field spectrum always exhibits clearly manifested anisotropy with respect to mutual orientation of wavevectors of the strong and probe radiation (even under small Doppler broadening). It is found that the probe field spectrum may acquire under certain conditions supernarrow resonances with a width proportional to the diffusion coefficient for atoms interacting with radiation. This fact may form the basis for a spectroscopic method for measuring transport frequencies of collisions between absorbing and buffer particles. A large-amplitude supernarrow resonance (with an amplitude much larger than the amplitude of the resonance near the line center), which is observed in the far wing of the absorption line, exhibits collisional narrowing (a nonlinear spectroscopic analog of the Dicke effect) at collision frequencies several orders of magnitude lower that the Doppler linewidth. Simple working equations proposed for describing the probe field spectrum are convenient for experimental data processing.     

用于原子能级结构研究的激光共振电离光谱系统

激光共振电离光谱技术是一种利用一路或多路激光将待测原子选择性共振激发与电离,通过测量离子信号来研究原子能级结构的光谱技术。研建了一套激光共振电离光谱装置,用于原子高激发态能级结构参数的测量。分别从该装置的总体结构、关键技术和应用实例等方面进行了详细介绍。该套装置主要包括高调谐精度的染料激光器系统、高效的激光离子源系统和高分辨率的飞行时间质量分析器。染料激光器系统包括3台多纵模可调谐染料激光器和1台单纵模可调谐染料激光器,均为脉冲工作方式,重复频率为10 kHz,泵浦源均为532 nm的Nd∶YAG固体激光器。激光离子源系统包括原子化源、激光与原子相互作用区和离子光学透镜组三部分组成,样品在原子化源中被电加热实现原子化,喷射出的原子被激光选择性激发、电离,产生的离子被离子传输透镜整形成能量分散小、束窄的离子束。飞行时间质量分析器采用了反射式结构设计、脉冲垂直推斥技术和偏转板调节技术。利用此装置,实验测定了U原子的自电离态光谱,获得了U原子一条较佳的三色三光子共振电离路径,对应激光的波长分别为591.7,565.0和632.4 nm。此系统还可用于测量同位素位移和原子超精细结构等参数。另外,由于此系统中联用了质量分析器,因此可用于样品多元素分析、痕量元素分析、同位素丰度分析。     

Radiostability of Allantoin by Using Electron Spin Resonance Spectroscopy

The radiosterilization potential and dosimetric feature of allantoin were investigated through the molecular degradations produced after ultraviolet and gamma irradiation using electron spin resonance, infrared, and ultraviolet spectroscopies and thermal measurement techniques (differential thermal analysis and the glass transition temperature). Although ultraviolet-irradiated allantoin presents no electron spin resonance signal, gamma irradiation exhibited an electron spin resonance signal of triplet appearance. Room temperature and high-temperature line intensity and spectrum area data and their variations with applied microwave power, storage time, annealing time, annealing temperature, and applied radiation dose were analyzed by assuming the production of two different types of radicals having different spectroscopic and decay characteristics. Based on its relatively stable nature toward gamma and ultraviolet radiations, it was concluded that allantoin itself and the products containing it can be sterilized by gamma and/or ultraviolet radiations without creating a great loss in its beneficial effects in the allowed radiosterilization dose limits.