一种受激紫外光谱的产生办法

以原子物理学理论为基础,详细地给出了在红外光谱之外原子材料紫外光谱的产生方法,列出了计算数据,给出了实验的结果。     

光学光谱仪器光谱响应的校正原理及其在光学光谱分析仪上的应用

本文阐述了光学光谱仪器的不平坦光谱响应的校正原理，给出了光学光谱分析仪（ＯＳＡ）系统测试灯光谱的方法．作为例子测试了氙灯光谱，井打印出氙灯光谱图，获得满意的结果．     

锗等离子体远紫外光谱研究

测量了线聚焦激光加热锗等离子体发射的远紫外光谱，对ＧｅＸＸ－ＧｅＸＸＶＩ谱线进行了辨认和分类。给出了谱线波长和相对强度；计算了辐射跃迁概率和吸收振子强度；并；与其他实验室有关结果进行了比较。 关键词：     

农药草甘膦的拉曼光谱计算及分析

草甘膦(glyphosate)是一种高效、低毒、非选择性的芽后除草剂。本文首先给出了草甘膦分子的空间结构图,并用近似方法(Hartree-Fock,HF)对其进行了空间结构优化;然后分别用HF和密度泛函理论(Density Functional Theory,DFT)两种方法基于基组6-31G计算了该分子的振动特性,给出了拉曼光谱和红外光谱强度图,并对比了两种算法的拉曼光谱图和其实验光谱图,结果显示很好的一致性;本文还给出了草甘膦分子的各个键长、键角等空间结构参数,并对草甘膦分子在800cm-1～1600cm-1区间的振动谱做了指认。这些工作将促进针对草甘膦分子的农药残留检测领域的研究。     

光谱分辨率可调的新型干涉成像光谱技术研究

针对色散型和静态干涉型成像光谱仪光谱分辨率固定、系统效能得不到充分发挥等问题,提出了一种光谱分辨率可调的静态双折射干涉成像光谱技术.该技术的创新点之一在于,仪器的光谱分辨能力可调,且调节范围较宽.对于不同的探测目标,利用这一技术,只获取有用的光谱数据,既能满足多目标、多任务光谱图像探测的需要,又可大幅减少对存储空间和通信带宽的占用,有效缩短数据处理时间,提高系统信噪比,从而使仪器总体性能达到最优.本文给出了新技术的具体实现方案及理论模型,对核心元件—横向剪切量可调的新型双Wollaston平行平板分束器进行了光线追迹,给出了其横向剪切量的精确理论计算公式,深入分析了其分光及横向剪切量调节原理.在此基础上,研究了新技术的光谱分辨率调节特性,给出了其光谱调节范围,并对其光谱调节原理进行了实验验证.     

金刚石薄膜质量的红外光谱判断技术

给出了利用红外透射光谱计算金刚石薄膜中ＳＰ＾２／ＳＰ＾３键价比，从而判断金刚石薄质量的判断技术。这种方法给出了薄膜质量的定量判断，甚至当由于灵敏度限制拉曼光谱无法给出判断结果时这种方法仍可使用。     

蛋白质分子Raman光谱的选择定则

利用作者给出的α螺旋蛋白质分子体系哈密顿有级结构，从理论上给出了该体系Ｒａｍａｎ谱的选择定则及合理的解释。     

类Be氩离子振子强度和跃迁光谱

研究了类Ｂｅ氩离子内壳层电子光电离的激发能级，寿命和辐射速率，谱线波长和振子强度，并给出了位于“水窗”波段的谱线波长和谱线强度。     

光源变线宽度对测量滤光片光谱分布影响的研究

从理论上分析光源的光谱宽度对滤光片测量结果的影响，给出光源光谱曲线及滤光片透过率曲线为正态分布时测得的滤光片光谱分布曲线。     

皮肤组织容积脉搏波400~1000 nm光谱特性仿真研究

根据皮肤组织解剖结构特性建立了六层层状模型,并给出了皮肤组织各层的特性参数;考虑了氧合血红蛋白和还原血红蛋白的吸收特性,依据皮肤组织各层的水、血、脂肪、血氧饱和度含量以及血管大小给出了皮肤组织各层的光谱吸收系数;对不同波长散射系数做了适当简化,给出了皮肤组织各层的光谱散射系数。利用蒙特卡罗方法仿真血管组织在收缩与舒张两种状态下, 400~1 000 nm波长光在皮肤组织多层模型中的传输过程,并通过统计大量光子的分布特性,获得了皮肤组织光谱反射系数,并利用模拟所得的两种状态下的反射系数计算得到了光谱容积脉搏波幅度。仿真结果表明,当入射光强一定时,绿光的容积脉搏波幅度优于红光和蓝光。通过计算不同波长光沿皮肤组织深度方向光能流率衰减为1/e时对应的皮肤组织深度,获得了皮肤组织光谱穿透深度。结果显示,血管舒张状态下蓝光和绿光的穿透深度较小,蓝光大部分只能达到表皮层,绿光能到达微循环层,红光可直达真皮层。考虑到光在皮肤组织中传播包含了一个从收缩到舒张的动态过程,基于此,根据穿透深度定义了脉搏波信号产生深度,利用血管舒张与收缩两种不同状态下的穿透深度计算得到了光谱产生深度。结果表明,不同波长光产生深度大于其穿透深度,蓝光产生深度较浅,且其受到的血液吸收调制较小,因而其获得的脉搏信号易受噪声干扰;红光的容积脉搏波产生深度较大,但是相比于绿光其受血液吸收调制较小,且绿光产生深度足够达到真皮血管层,因而红光容积脉搏波的幅度小于绿光。上述仿真结果明确了皮肤组织部分光谱特性,为皮肤组织多光谱容积脉搏波的精确获取及其他相关研究提供了一定的理论基础。     

Light filaments in air for ultraviolet and infrared wavelengths

The propagation of femtosecond UV laser pulses in air is numerically shown to form intense light filaments over several tenths of Rayleigh lengths. We compare UV filamentation with IR filamentation and show that the balance of the physical processes supporting the filaments is identical in both cases. For IR and UV wavelengths, it is shown that the intensity in the filament and the density of the electron plasma created by ionization of air molecules reach similar values as high as 10(14) W/cm(2) and 10(17) cm(-3). Spectral data exhibit a large broadening in the IR filament and a limited one for UV, which justifies the white-light generation associated with IR filamentation only.     

Investigation on trap distribution and photoelectronic effect due to UV,IR and visible light excitation in self-activated zns crystals

Photoelectronic effects in IR sensitive ZnS crystals are found for IR, UV and visible light excitations. The transient rise characteristic of UV excited photoluminescence (UPL) saturates faster than UV produced photoconductivity (UPC). The UPC shows a typical S-shaped rise curve for any 365 run excitation irradiance and temperature. Simultaneously measured transient behaviors of IR induced photoconductivity (INP) and IR stimulated luminescence (STL) have a strong IR excitation intensity dependence for λ_IR = 2.5?4.6 microm. A unique phenomenon, quick rise followed by quick decay during the initial 20 msec, is found in INP before reaching final maximum but is not observed in STL. During UV steady irradiation, additional photoconductivity and luminescence are quickly induced by an abrupt IR excitation of 2.5 microm. Then, the photoconductivity reaches a new steady state level below UPC steady state. However, the luminescence sets the same UPL steady state level. This means that photoconductivity exhibits an IR optical quenching but not stimulation, while neither optical quenching nor stimulation is found in luminescence. It is also possible to quench the UPC response with visible light excitation at 570 nm. These observations support the previously reported discussion that IR absorbing impurity centers and shallow traps, including recombination (or luminescence) centers must be involved in IR stimulable ZnS crystals. They also indicate the presence of deep trap centers for E_T ≈ 2.18 eV, which have a strong role in slow UPC rise.     

蓖麻碱的提取及光谱研究

本文报导了蓖麻碱的提取方法,研究了它的紫外光谱和红外光谱。     

特丁基对苯二酚的光谱及密度泛函研究

特丁基对苯二酚是重要的食品抗氧化剂.理论上,基于密度泛函理论,采用B3LYP泛函及6-311G(d,p)基组在气相环境下优化分子的结构并进行频率计算.在此基础上,基于含时密度泛函理论,选用SMD(solvation model based on density)溶剂模型,利用B3LYP泛函并结合def2-TZVP基组计算分子在无水乙醇溶剂中的前50个激发态.再通过Multiwfn软件对红外光谱做振动分析并考察分子间相互作用对红外光谱的影响,对紫外光谱做分子轨道和电子空穴分析.实验上,通过KBr压片法,利用傅里叶红外变换光谱仪测定样品红外光谱.采用液相法,以乙醇为溶剂,利用紫外可见分光光度计测定样品紫外光谱.通过对比分析可知,理论光谱与实验光谱总体吻合较好.红外光谱各基团的特征吸收峰都较为明显且较好吻合,特丁基对苯二酚二聚体存在氢键作用,这使得O—H键的强度被削弱,导致吸收频率降低并在3670—3070 cm^-1处出现一个宽峰.紫外光谱主要由基态跃迁至第1,2,6,7激发态形成,最大吸收峰位于200 nm以下,为π→π^*和s→π^*跃迁形成,268.8 nm和221.4 nm处的吸收峰均为n→π^*和π→π^*跃迁形成.由电子空穴图可知,这4个主要激发均为电子局域激发.     

海空背景下红外-紫外双色探测技术研究

舰船采用紫外-红外多传感器探测低空飞行的导弹、飞机等目标，对各个传感器采集的目标图像数据进行融合处理，可提高对目标的探测识别概率。本文分析了红外传感器器和紫外传感器的各自的优越性、海空背景下导弹羽烟的紫外辐射传输特性，得出采用红外-紫外图像融合技术能使红外、紫外传感器的优势得到互补，融合级别适合在特征级上进行，并对红外-紫外双色探测技术进行了展望。     

温度限制串联相关网络用于有机环境污染物紫外光谱的识别

本文将温度限制串联相关网络用于有机环境污染物紫外光谱的识别。紫外光谱的库检索比红外光谱检索更困难 ,因为紫外光谱的重叠更为严重。此外 ,光谱测量的漂移和噪声也会影响紫外光谱库检索的正确率。因此 ,采用具有模糊性质的神经网络是一个很好的选择。温度限制串联相关网络 (TCCCN)是一种与通常所用BP网络不同结构的网络模型 ,它采用串联相关的神经元连续方式 ,且引入温度参数 ,因而可以减少网络的过度训练和加快训练速度。本工作采用TCCCN进行紫外光谱的库检索 ,对有关参数进行了优化 ,并对光谱测量噪声的影响做了研究。结果表明 ,采用TCCCN方法明显优于在谱库检索中常用的相关系数法。     

Strong UV absorption and visible luminescence in ytterbium-doped aluminosilicate glass under UV excitation

A broad visible luminescence band and characteristic IR luminescence of Yb(3+) ions are observed under UV excitation in ytterbium-doped aluminosilicate glass. Samples made under both oxidizing and reducing conditions are analyzed. A strong charge-transfer absorption band in the UV range is observed for glass samples containing ytterbium. Additional absorption bands are observed for the sample made under reducing conditions, which are associated with f-d transitions of divalent ytterbium. The visible luminescence band is attributed to 5d-4f emission from Yb(2+) ions, and the IR luminescence is concluded to originate from a relaxed charge-transfer transition. The findings are important to explain induced optical losses (photodarkening) in high-power fiber lasers.     

Performance improvements of ultraviolet/infrared dual-band detectors

Results are reported on dual-band detectors based on a GaN/AlGaN structure operating in both the ultraviolet–midinfrared (UV–MIR) and ultraviolet–farinfrared (UV–FIR) regions. The UV detection is due to an interband process, while the MIR/FIR detection is from free carrier absorption in the emitter/contact followed by internal photoemission over the barrier at the GaN/AlGaN interface. The UV detection, which was observed from 300 K to 4.2 K, has a threshold of 360 nm with a peak responsivity of 0.6 mA/W at 300 K. The detector shows a free carrier IR response in the 3–7 μm range up to 120 K, and an impurity response around 54 μm up to 30 K. A response in the range 7–13 μm, which is tentatively assigned to transitions from C impurities and N vacancies in the barrier region, was also observed. It should also be possible to develop a detector operating in the UV–visible–IR regions by choosing the appropriate material system. A dual-band detector design, which allows not only to measure the two components of the photocurrent generated by UV and IR radiation simultaneously but also to optimize the UV and IR responses independently, is proposed.     

脐橙香料、色素的提取及光谱研究

本文分别用水蒸气蒸馏法和溶剂浸出法从干脐橙皮中提取脐橙香料及脐橙色素与香料的混合物，测定了它们的紫外可见光吸收光谱、红外光谱。采用电感耦合等离子体原子发射光谱测定了该混合物中矿物质的含量。