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为了测定钽酸锂铁电晶体异常声子的方向色散,我们找到一种较为满意的直角散射几何配置,制备了十个不同取向的样品,并为消除内反射光引起的附加散射,在样品表面上镀了增透膜,获得了波夫与光轴成不同夹角时的一系列寻常声子和异常声子的喇曼光谱.对这些喇曼光谱进行了识别,认定了四个A_1光学声子和九个E光学声子,确定了十三个异常声子方向色散支.由于全部异常声子的散射峰能始终一起出现在同一喇曼光谱中,使得异常声子方向色散的确定一目了然.最后用单轴晶体异常声子方向色散公式计算了异常声子的方向色散曲线,实验与理论计算相当符合. 相似文献
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本文建立了极性倍频晶体中极化声子相干喇曼混频的耦合波方程,其中考虑了超喇曼极化率β_R.该方程在小信号、声子近似以及喇曼驱动的参量近似下求解.结果表明:在高强度泵浦光受激喇曼散射的相干驱动下,极性倍频晶体可以在泵浦光倍频附近产生极化声子的相干喇曼光束.这种光束可以通过不同的相干喇曼混频过程,由倍频光直接转换,或由基波光直接转换,还可以由倍频光与基波光共同转换而成.这三种转换过程具有各自不同的相位失配因子.在一定条件下,后两种过程可以同时进行.在LiIO_3晶体中证实了上述的结论.实验中泵浦光强度约3.0×10~9W/cm~2. 相似文献
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本文用衰减全反射(ATR)和光声(PA)方法研究表而等离子激元(surface plasmons)的衰减,分别对Ag-空气界面和CaF_2-Ag-空气界面进行衰减全反射谱和光声光谱测定.测量结果确定两种衰减方式,辐射和无辐射定量结果,并且发现表面粗糙度对衰减方式有影响. 相似文献
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利用325nm紫外光激发,对不同组分的InxGa1-xN薄膜的喇曼散射谱进行了研究.在光子能量大于带隙的情况下,观察到显著增强的二阶A1(LO)声子散射峰.二阶LO声子峰都从一阶LO声子的二倍处向高能方向移动,移动量随样品In组分的增加而增大,认为是带内Frhlich相互作用决定的多共振效应引起的.分析了一阶LO声子散射频率和峰型与In组分的关系.在喇曼谱中观察到样品存在相分离现象,并与X射线衍射的实验结果进行
关键词:
xGa1-xN合金')" href="#">InxGa1-xN合金
紫外共振喇曼散射
二阶声子
相分离 相似文献
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《光子学报》2017,(10)
设计了一种表面镀有Ag涂层且具有内凹弧度的圆锥形钨(W)针尖,运用时域有限差分法建立了针尖-球形样品结构的针尖增强喇曼散射模型,研究了针尖增强效应及参数优化配置.采用波长632.8nm光源斜入射激励方式,对模型的针尖增强喇曼散射效应进行电磁场仿真计算,获得了模型在不同光源入射角度、样品粒径、针尖-样品间距下的增强电场强度和针尖增强喇曼散射增强因子.研究结果表明:当光源入射角为72°、样品粒径约为140nm、针尖-样品间距达到2nm时可产生最大的增强因子,达到104量级.该结果为制备高增强效率的探针针尖,及其在高空间分辨率和高检测灵敏度喇曼光谱仪中的实用化提供了参考依据. 相似文献
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利用U(5)群链描述三原子分子振转谱的对称性质,并用群论方法计算了CO_2分子喇曼散射的跃迁矩阵元,给出了它的振动与转动喇曼散射截面.结果与实验较好地符合. 相似文献
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We report here the development of a Coherent Anti-Stokes Raman Scattering (CARS) configuration which takes advantage of the phasematching criterion to produce simultaneous spatially-separated signals from different constituents within a gas. In particular, we have show that separate CARS beams from nitrogen monoxide may be simultaneously observed from a single sample volume. 相似文献
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本文从理论和实验两方面探讨了具有微结构的金属纳米线系统中表面等离激元传播规律和分光特性. 我们由麦克斯韦方程组出发, 利用严格耦合波近似和有限元差分等方法首先从理论上给出了金属纳米线系统中等离激元的色散关系和能带特征, 然后基于微结构的银纳米线及其等离激元能带结构, 设计并制备出等离激元分光原型器件, 实验展示其将不同频率的光在微小空间分离的特性. 该研究结果是我们前期相关工作的延续和补充, 可应用于构造多功能集成的光子芯片和新型亚波长光电材料和器件. 相似文献
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J.C. Tsang Ph. Avouris J.R. Kirtley 《Journal of Electron Spectroscopy and Related Phenomena》1983,29(1):343-348
We demonstrate that multichannel optical detectors provide the capability of observing Raman Scattering from molecular monolayers in solid-air and solid-solid interfaces in the absence of the conditions considered essential for surface enhanced Raman scattering. We present spectra of adsorbates on smooth Ag films, air-oxidized smooth Al films and Al gratings. Finally, we demonstrate a new configuration for surface enhanced Raman scattering which need not involve noble metals. Raman scattering from a doped Al/AlOx/Sn tunnel junction provides a specific example of such a configuration. 相似文献
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The results of a study on the influence of the nonparabolicity of the free carriers dispersion law on the propagation of surface polaritons (SPs) located near the interface between an n-type semiconductor and a metal arc reported. The semiconductor plasma is assumed to be warm and nonisothermal. The nonparabolicity of the electron dispersion law has two effects. The first one is associated with nonlinear self-interaction of the SPs. The nonlinear dispersion equation and the nonlinear Schrodinger equation for the amplitude of the SP envelope are obtained. The nonlinear evolution of the SP is studied on the base of the above mentioned equations. The second effect results in third harmonics generation. Analysis shows that these third harmonics may appear as a pure surface polariton, a pseudosurface polariton, or a superposition of a volume wave and a SP depending on the wave frequency, electron density and lattice dielectric constant. 相似文献
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Spencer J. Petersen Soumyadipta Basu Mathieu Francoeur 《Photonics and Nanostructures》2013,11(3):167-181
A closed form expression for the local density of electromagnetic states (LDOS) due to a thermally emitting metamaterial bulk is derived from Maxwell's equations combined with fluctuational electrodynamics. The final form is the same as that for nonmagnetic materials, where the influence of the magnetic permeability is embedded in the Fresnel reflection coefficients. Spectral distributions of LDOS near metallic- and dielectric-based metamaterials are investigated. Results reveal that LDOS profiles are dominated by surface polaritons (SPs) in both TE and TM polarization states. A detailed discussion is provided on the necessary conditions for exciting TM- and TE-polarized SPs via a dispersion relation analysis that accounts for losses. Beyond the conventional conditions for excitation of SPs, the lossy dispersion relation analysis demonstrates mathematically that SPs exist when the imaginary parts of the permittivity or permeability, as well as n′n″, are close to zero, where n′ and n″ are the real and imaginary parts of the refractive index, respectively. An asymptotic expression for the extreme near field LDOS is derived, showing a Δ?3 power law relationship, as for nonmagnetic media, between LDOS and distance from the emitting bulk Δ. Results obtained from this study will assist in assessing material properties of arbitrarily electromagnetic materials in applications related to energy harvesting. 相似文献
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The dispersoon curves for surface plasma waves (SPW) in Ag have been determined from calculated reflectivity minima as exhibited by attenuated total reflection (ATR spectra) for the prism-metal-air (PMA) configuration and from the direct calculation of the dispersion relation for the same configuration. Comparison is made with published results. The dispersion curves for Au and Cu have been determined for the same configuration from calculated ATR spectra and verified experimentally. Comparison is made with the direct calculation of the dispersion relation. The direct calculation yields two types of modes; namely the surface or Brewster mode and the virtual mode. Both modes are discussed. The marked effect of small electronic damping as exhibited by Ag and moderate electronic damping as exhibited by Au and Cu upon the PMA dispersion curves from ATR spectra is examined. Finally the direct calculation of the dielectric shift (perturbing effect of the prism-metal surface upon the active metal-air surface dispersion curve) is presented for the three metals as a function of film thickness and photon energy. 相似文献
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基于非线性包络方程我们研究了平面非线性介质波导中的时空不稳定性,得到了有拉曼散射效应情形下不稳定性调制的增益谱的表达式.结果表明在正常和反常两种群速度色散情形下,拉曼散射效应都会导致出现新的不稳定性区域,并且使原有的每一个谱分量的增益上升从而使谱的范围扩大.并通过分析反常色散情况下四种不同函数分布的非线性色散介质系数对不稳定性增益谱的影响,得到呈双曲函数分布的非线性色散介质最为理想. 相似文献
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We report the first measurement of phonon surface polariton (s.p.) dispersion by a non-forward Raman scattering geometry. The Raman scattering from surface modes was excited by the evanescent electromagnetic wave produced by total reflection at the interface between two transparent media. This Raman Scattering excited in condition of Total Reflection, RSTR, has been applied to the NaClO3-sapphire interface for studying the surface polariton dispersion in the gap between the TO frequency at 966 cm-1 and the LO frequency at 983 cm-1 of sodium chlorate. Comparison is made between the experimental and theoretical dispersion curves. 相似文献
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In the present paper, we discuss the molecular information that can be derived from surface‐enhanced resonance Raman Scattering (SERRS) experiments performed with different excitation wavenumbers, which are close to resonance with an excited electronic state of the molecule [surface‐enhanced Raman dispersion spectroscopy (SERADIS)]. We specifically consider the situation, where a molecule is physisorbed to a site characterized by a local electric field with a direction independent of the direction of the external, exciting field. The molecular information available in this experimental situation is compared with the information available in a corresponding Raman dispersion spectroscopy (RADIS) experiment performed on a free molecule or a molecule physisorbed to a site, where the local field is isotropic. The consequences for resonance Raman scattering (RRS) and RADIS, when the molecule is adsorbed in the highly anisotropic hot spot (HS), are discussed; here it is shown that only the molecular information originating from the symmetric part of the scattering tensor can survive in SERRS and in SERADIS. Besides, it is shown that the depolarization ratio can no longer be used to discriminate between totally and non‐totally symmetric modes in the polarized surface‐enhanced Raman scattering (SERS) spectra. These results have implications for the resonance Raman spectra, but even more important for the application of the resonance Raman effect in the investigation of excited vibronic molecular states, in general, and in the investigation of electronic states in larger bio‐molecules, such as the various metallo‐porphyrins. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献