包钴型r-Fe2O3磁粉各向异性研究

包钴型γ-Fe₂O₃磁粉的矫顽力可比原γ-Fe₂O₃磁粉提高8000—32000A/m。木文研究探讨了两种包钴型γ-Fe₂O₃磁粉(包钴γ-Fe₂O₃和包钴包亚铁γ-Fe₂O₃)的单轴各向异性的起源和矫顽力增大的机制。包钴γ-Fe₂O₃磁粉矫顽力 关键词：     

包钴铁氧体型γ-Fe2O3磁粉穆斯堡尔效应的研究

包钴铁氧体型,γ-Fe₂O₃磁粉(简记为CoFe-γ-Fe₂O₃)是针状γ-Fe₂O₃磁粉与Co⁺⁺和Fe⁺⁺溶液起反应,在每个针状颗粒上包覆了一层钴铁氧体固溶体。经此种方法处理后的γ-Fe₂O₃磁粉的矫顽力及其它磁特性有较大的提高。如矫顽力由原来415Oe增加到715Oe;剩磁和矫顽力随时间及温度变化小等。我们利用穆斯堡尔效应并配合其它研究手段进行了研究,认为:CoFe-γ-Fe₂O₃磁粉矫顽力的提高,主要是由于γ-Fe₂O₃磁粉表面包覆了一层钴铁氧体固溶体,γ-Fe₂O₃与钴铁氧体固溶体之间发生磁耦合作用之故。 关键词：     

包钴对α-Fe2O3粉末Morin相变的影响

用穆斯堡尔谱,磁性测量,中子衍射和X射线光电子能谱(XPS)等方法对纯的和包钴α-Fe₂O₃粉末Morin相变的影响以及有关性质进行了研究,发现包钴会使α-Fe₂O₃的Morin温度降低,相变温度的区域扩大,矫顽力明显增大,3d能带变化,假设包钴可使α-Fe₂O₃的单离子各向异性常数K_FS下降来解释上述实验结果。 关键词：     

溅射氧化铁薄膜的Hall效应

在磁场垂直于薄膜表面,磁感应强度B由0—1.4T变化的条件下,测量了溅射氧化铁薄膜的Hall效应。从实验数据得到了Fe₃O₄薄膜和γ-Fe₂O₃薄膜的寻常Hall系数R₀和非常Hall系数R_s,计算出这两种薄膜的Hall迁移率μ_H分别是2.35和1.56(cm)²/V·s。这个结果适合于大极化子导电机制的条件(ν≥1(cm)^关键词：     

超细颗粒γ-Fe2O3微粉包钴前后的各向异性

本工作利用穆斯堡尔谱并配合其它研究手段,测量了超细γ-Fe₂O₃微粉在包钴和不包钴两种情况下的各向异性常数K;观察到前者比后者的各向异性常数K增加30％左右。对普通针状包钴型γ-Fe₂O₃磁粉矫顽力增大的原因提供了进一步的说明。 关键词：     

α-Fe2O3单离子磁晶各向异性的计算及Morin转变的解释

本文根据晶场理论计算了α-Fe₂O₃的单离子磁晶各向异性。采用点电荷模型,计及近邻及次近邻对晶场的贡献,并考虑到近邻O^2-离子对次近邻Fe³⁺离子的电屏蔽效应,在六级微扰近似下,得到单离子各向异性场H_si=102.3×10²Oe。这一结果结合Artman等人对磁偶极各向异性的计算,导出了α-Fe₂O₃的Morin转变温度T _关键词：     

Ce1.66Mg1.34Co3和α″-Fe16N2多层梯度膜磁反转性质的微磁学模拟

为了改善永磁薄膜的磁性能,基于微磁学理论,使用编程软件OOMMF针对Ce_1.66Mg_1.34Co₃和α″-Fe₁₆N₂交换耦合多层梯度膜的磁化过程进行模拟,系统研究磁晶各向异性梯度对多层膜性能的影响,分析体系的剩余磁化强度、矫顽力、磁滞回线和磁化反转过程中的能量变化。研究表明：减小磁晶各向异性梯度或增加界面处磁晶各向异性的差值,可以有效提高薄膜的矫顽力和剩余磁化强度,从而改善磁性能。通过计算磁矩分布发现一种磁涡旋态,这种磁涡旋态的产生过程伴随系统能量的增加。     

γ-Fe2O3中的氢含量

利用热中子透射法测定γ-Fe₂O₃的氢含量。利用差热分析、磁分析以及穆斯堡尔效应研究γ-Fe₂O₃的相变,实验结果表明在γ-Fe₂O₃结构中确实含有一定量的氢,当γ-Fe₂O₃结构中的阳离子空位被H¹⁺,Co²⁺,Si⁴⁺,P⁵⁺等离子占据时,将 关键词：     

过渡金属元素掺杂对磁铁矿磁矩及磁各向异性的调控

磁性Fe₃O₄纳米粒子在纳米医学领域展现出巨大的应用前景.饱和磁化强度和磁各向异性对于Fe₃O₄纳米粒子在药物输送和磁热疗中的应用至关重要.在此,通过密度泛函理论计算,仔细研究了3d和4d过渡金属元素的掺杂对Fe₃O₄磁矩及磁各向异性的影响.结果表明, Fe₃O₄中Zn和Cd的掺杂会增大总磁矩,而其他3d和4d过渡金属元素的掺杂会降低总磁矩.有趣的是, Cd的掺杂也会大大增大磁各向异性.本文结果表明,掺杂Cd是提高Fe₃O₄作为药物输送和磁热疗材料性能的可行方法.     

基于拉曼光谱成像技术的铁质文物锈蚀产物定量模型研究

铁质文物是我国文化遗产的重要组成部分。由于化学性质较为活泼,铁质文物易发生腐蚀劣化。锈蚀产物对铁质文物的稳定性有较大影响,因此判断铁质文物锈蚀产物的组成特征,对于铁质文物稳定性评估具有重要意义。以赤铁矿(α-Fe₂O₃),磁铁矿(Fe₃O₄),四方纤铁矿(β-FeOOH)三种铁质文物的锈蚀产物为研究对象,采用拉曼光谱成像结合主成分回归法(PCR)和偏最小二乘法(PLS),同时结合多种预处理方法,构建了两组二元混合锈蚀(α-Fe₂O₃+Fe₃O₄, α-Fe₂O₃+β-FeOOH)的定量模型。结果表明,对于α-Fe₂O₃+Fe₃O₄二元体系,PCR和PLS算法构建模型的定量效果基本一致,α-Fe₂O₃和Fe₃O_...     

Effects of calcium and zinc on the adsorption of cobalt on γ-Fe2O3

The effects of calcium and zinc on the room-temperature coercivity of γ-Fe₂O₃ particles having cobalt ions adsorbed in 3M NaOH solution at 373K have been studied. When the Ca²⁺ ions are adsorbed on the γ-Fe₂O₃ prior to Co²⁺ ions adsorption, the coercivity of Co-modified γ-Fe₂O₃ significantly increases compared with that of γ-Fe₂O₃ modified only with Co²⁺ ions. In the case of Zn²⁺ ions, the coercivity of Co-modified γ-Fe₂O₃ is the same as that of γ-Fe₂O₃ modified only with Co²⁺ ions. The emission Mössbauer spectrum of⁵⁷Co²⁺ adsorbed on the surfaces of γ-Fe₂O₃ after pretreating with Ca²⁺ ions consists of a typical sextet of Fe³⁺ ions with hyperfine magnetic field, whereas those of γ-Fe₂O₃ modified only with Co²⁺ ions and with both Zn²⁺ and Co²⁺ ions show nonmagnetic components in addition to magnetic one. The effects of Ca²⁺ and Zn²⁺ ions on the adsorption of cobalt on the surface of γ-Fe₂O₃ are discussed from the viewpoint of site preference energy of cations in ferrite and distribution ratio of each cation.     

Influence of Si-N interlayer on the microstructure and magnetic properties of γ′-Fe4N films

The (γ′-Fe₄N/Si-N)_n (n: number of layers) multilayer films and γ′-Fe₄N single layer film synthesized on Si (1 0 0) substrates by direct current magnetron sputtering were annealed at different temperatures. The structures and magnetic properties of as-deposited films and films annealed at different temperatures were characterized using X-ray diffraction, scanning electron microscopy and vibrating sample magnetometer. The results showed that the insertion of Si-N layer had a significant influence on the structures and magnetic properties of γ′-Fe₄N film. Without the addition of Si-N lamination, the iron nitride γ′-Fe₄N tended to transform to α-Fe when annealed at the temperatures over 300 °C. However, the phase transition from γ′-Fe₄N to ?-Fe₃N occurred at annealing temperature of 300 °C for the multilayer films. Furthermore, with increasing annealing temperature up to 400 °C or above, ?-Fe₃N transformed back into γ′-Fe₄N. The magnetic investigations indicated that coercivity of magnetic phase γ′-Fe₄N for as-deposited films decreased from 152 Oe (for single layer) to 57.23 Oe with increasing n up to 30. For the annealed multilayer films, the coercivity values decreased with increasing annealing temperature, except that the film annealed at 300 °C due to the appearance of phase ?-Fe₃N.     

Magnetic properties of nanosized γ-Fe2O3 and α-(Fe2/3Cr1/3)2O3, prepared by thermal decomposition of heterometallic single-molecular precursor

Thermal decomposition of the trinuclear complex [Fe₂CrO(CH₃COO)₆(H₂O)₃]NO₃ at 300, 400 and 500 °C gave γ-Fe₂O₃ nanoparticles along with amorphous chromium oxide, while decomposition of the same starting compound at 600 and 700 °C led to the formation of α-(Fe_2/3Cr_1/3)₂O₃ nanoparticles. Size of γ-Fe₂O₃ nanoparticles, determined by X-ray diffraction, was in the range from 9 to 11 nm and increased with formation temperature growth. Average size of α-(Fe_2/3Cr_1/3)₂O₃ nanoparticles was about 40 nm and almost did not depend on the temperature of its formation. γ-Fe₂O₃ nanoparticles possessed superparamagnetic behavior with blocking temperature 180-250 K, saturation magnetization 29-35 emu/g at 5 K, 44-49 emu/g at 300 K and coercivity 400-600 Oe at 5 K. α-(Fe_2/3Cr_1/3)₂O₃ nanoparticles were characterized by low magnetization values (2.7 emu/g at 70 kOe). Such magnetic properties can be caused by non-compensated spins and defects present on the surface of these nanoparticles. The increase of α-(Fe_2/3Cr_1/3)₂O₃ formation temperature led to decrease of magnetization (being compared for the same fields), which may be caused by decrease of the quantity of defects or non-compensated spins (due to decrease of particles' surface).     

包钴型γ-Fe2O3磁粉矫顽力的研究

包钴型γ-Fe₂O₃磁粉分为包钴γ-Fe₂O₃(简记为Co-γ-Fe₂O₃)和包钴包亚铁γ-Fe₂O₃(简记为CoFe-γ-Fe₂O₃)两种,它们的矫顽力可比γ-Fe₂O₃磁粉的提高100至400Oe左右,本工作对这两种磁粉矫顽力增大的原因作了探讨,认为它们矫顽力增大的机制不同:CO-γ-Fe₂O₃矫顽力增大是由于表面包覆一层Co(OH)₂使表面各向异性增大,而CoFe-γ-Fe₂O₃则是由于表面包覆的是钴铁氧体,γ-Fe₂O₃与钴铁氧体之间发生耦合作用,使矫顽力增大。     

Implications of nanoparticle concentration and size distribution in the superparamagnetic behaviour of aging-improved maghemite xerogels

Evolution of static magnetic properties of a set of enhanced γ-Fe₂O₃/SiO₂ nanocomposites with different iron concentration has been studied on the basis of their corresponding hysteresis loops, zero-field/field-cooled (ZFC/FC) magnetization curves and transmission electron microscopy images. The lack of coercivity in all compositions, as well as the fulfillment of the H/T scaling law by the magnetization above the blocking temperature of each system under study, evidence a superparamagnetic behaviour in the iron oxide nanoparticles. In order to study the influence of iron content in the unblocking processes of nanoparticles, ZFC curves under different applied magnetic fields have been fitted to a model considering the systems under study as a distribution of energy barriers. Depart from the superparamagnetic model is discussed considering interparticle interactions.     

Mössbauer spectroscopic properties of tin-doped iron oxides

The ⁵⁷Fe Mössbauer spectra recorded in situ from tin-doped Fe₃O₄ at elevated temperature in vacuo shows the Curie temperature to decrease with increasing concentrations of the dopant. Thermal treatment under oxidising conditions results in the initial formation of tin-doped γ-Fe₂O₃ which subsequently undergoes a phase transformation to tin-doped α-Fe₂O₃. ⁵⁷Fe Mössbauer spectroscopy at elevated temperatures shows the Néel temperature for tin-doped γ-Fe₂O₃ to be lower than that of pure γ-Fe₂O₃. The ¹¹⁹Sn Mössbauer spectra recorded from all the tin-doped iron oxides show the presence of a hyperfine magnetic field at the Sn⁴⁺ site which is more complex in the spectra recorded from tin-doped γ-Fe₂O₃ and α-Fe₂O₃.     

Exchange bias behavior of monodisperse Fe3O4/γ-Fe2O3 core/shell nanoparticles

We have carried out systematic studies on well-characterized monodisperse Fe₃O₄/γ-Fe₂O₃ core/shell nanoparticles of 2-30 nm having a very narrow size distribution and possessing a uniquely mono-layer of surface γ-Fe₂O₃. This unique core-shell structure, probably having a disordered magnetic surface state, leads us to three key observations of unusual magnetic properties: i) a very large magnetic exchange anisotropy reaching over 7 × 10⁶ erg/cm³ for the smaller particles, ii) exchange bias behavior in the magnetization data of the core/shell Fe₃O₄/γ-Fe₂O₃ nanoparticles, and iii) the temperature dependence of the coercive field following an unusual exponential behavior.     

XRD and Mössbauer spectroscopy investigation of Fe2O3–Al2O3 nano-composite

Fe₂O₃–Al₂O₃ nano-composites were synthesized by sol–gel means. The properties of samples sintered at various thermal treatment temperatures were investigated by X-ray diffraction (XRD) and Mössbauer spectroscopy (MS). The experimental results show that the γ- to α-Al₂O₃ transformation occurs at lower temperature after iron oxide doping. The samples obtained at 1173 K contained poorly crystallized γ-Al₂O₃ phase and an amorphous iron oxide. When the temperature of heating was increased to 1373 K, the sample was composed of α-Fe₂O₃/α-Al₂O₃ nano-composite and some solid solution. A superparamagnetic phenomenon was observed until the thermal treatment temperature reached 1373 K.     

Application of Mössbauer spectroscopy for the complex structural analysis of iron oxide-based nanomaterials

The results of complex structural investigation by XRD, TEM, and Mössbauer spectroscopy of nanomaterials based on iron oxides Fe₃O₄ and γ-Fe₂O₃ are presented. The investigated nanomaterials include nanopowders produced chemically and nanostructural powders produced mechanochemically. The magnetic properties of the nanomaterials, measured at ambient temperature, are discussed.