超短脉冲激光辐照下金属薄膜的热行为

对双温模型的重要热学参量电子热容、电子弛豫时间、电子热导率进行量子化处理，使双温模型能适用于自由电子温度比较高的情况.利用前向差分算法，数值求解了电子-晶格双温双曲两步热传导模型，所得的结果更接近实验值.经过分析得出： 1）薄膜前表面自由电子温度达到最大值的时间约为0.27 ps,得到的损伤阈值与实验值符合较好.2）电子热容对电子温升规律影响非常大.电子热导率对自由电子温升规律也有较大的影响.3）在趋肤层内自由电子温升非常快，不同厚度自由电子温度达到最大值所需的时间延迟不明显.趋肤层以下自由电子温度升高较慢，不同厚度自由电子达到最大值所需的时间延迟明显.     

Synthesis of zinc ultrafine powders via the Guen–Miller flow-levitation method

Zinc ultrafine powders (UFPs) with the average particle size of 0.175 to 1.24 μm are synthesized via the flow-levitation method. The peculiarities of the formation of zinc UFPs are considered with respect to the carrier gas properties (heat capacity, thermal conductivity, and diffusion coefficient), as well as the gas flow parameters (pressure and flow rate). The obtained zinc particles are studied via scanning electron microscopy and X-ray diffraction. The factors determining the crystal structure of zinc particles and their size distribution are discussed as well. The data on oxidation of zinc stored in unsealed containers under normal conditions are also presented.     

物理参数变化对短脉冲激光激励温度场的影响

 为研究多物理参数（耦合系数、电子热导率、电子热容、晶格热容）同时随温度变化对短脉冲激光辐照金属材料产生温度场分布的影响,基于双温耦合理论,建立了短脉冲激光辐照金属材料金的加热过程的有限元求解模型。在同时考虑脉冲激光的空间、时间分布和多参数同时随温度变化的情况下,得到短脉冲激光辐照金属材料金激励产生的温度场二维瞬态分布,并进一步比较了多物理参数同时随温度变化和采用室温物理参数两种情况下温度场分布的区别。数值结果表明：多物理参数同时随温度变化使电子温度和晶格温度的上升变快,最大值变大,而且使得材料中激光穿透直接辐照到的区域温度变高。     

Position passage through an electron gas

The analysis of the passage of a charged particle through an electron gas is given in this paper. The electron gas is considered as a plasma which oscillates with the Debye frequency. At the same time the electron gas polarization by the electric field of a passing positron is taken into account. The positron energy loss per unit time is calculated. The thermalization time of high velocity positrons is obtained. This time depends on the density of a metal, namely on the electron gas density according to the experimental data.     

Molecular structure and optical properties of PTFE-based nanocomposite polymer-metal coatings

The molecular organization of polytetrafluoroethylene (PTFE) thin coatings with incorporated Ag, Cu, and Mo nanoparticles that are deposited from an active gas component has been studied. Polyethylene terephtalate film coated by aluminium served as a substrate. The active gas component was produced by electron beam dispersion of original components in vacuum. The effect of metal particle size and its nature on the molecular structure of coatings have been investigated. Dichroism of thin nanocomposite coatings has been examined by polarized Fourier transform infrared spectroscopy using an attenuated total reflection unit. The morphology of the coatings has been analyzed by transmission (TEM), atomic-force (AFM), and scanning electron (SEM) microscopy. It is found that introduction of a metal (Ag or Cu) yields oriented layers at a lesser efficient thickness of a coating. The surface plasmon resonance of such structures was studied by measuring optical absorption of the coatings in the ultraviolet and visible ranges. The results show that the composite coatings containing Ag clusters are diameter less than 30 nm and absorb within the short-wave range from 400 to 550 nm.     

Investigation of ultrafast electron dynamics of nickel film and micro-nano-structure film

The electron thermalization and relaxation processes in ferromagnetic nickel thin film and micro-nano- structure film have been studied by measuring the transient change after excitation by a femtosecond laser pulse. The measurements indicate that the electron thermalization time is between 18 and 47 fs. This is somewhat faster than the value reported before. And the thermalization time of the micro-nano-structure film is much longer than the nickel film. We deduce that it is caused by the discontinuity of the electron band close to the Fermi level in the micro-nano-structure nickel film.     

A mathematical method for the analysis of heat capacity and thermal conductivity measurements by the heat pulse technique

We present a new mathematical method for the analysis of heat capacity and thermal conductivity measurements by the heat pulse technique for the case of samples of finite length with a one-dimensional heat flow. In these experiments a heat pulse is produced by a heater, and the temperature is measured as a function of time at a different location on the sample. Finite length effects are taken care of in a natural way, and the thermal conductivity is obtained very simply. In addition, this method is capable of separating the heat capacities of the sample, of the heater and of the thermometer, which may be of practical importance for the case of thin samples with a small heat capacity. The mathematical analysis is based on Laplace transform techniques similar to those used for electrical transmission lines. The analysis of the experimental data is performed by calculating several moments of the temperature rise in the thermometer as a function of time. The method is particularly suitable for on-line computer experiments.     

Heat conduction and Fourier's law by consecutive local mixing and thermalization

We present a first-principles study of heat conduction in a class of models which exhibit a new multistep local thermalization mechanism which gives rise to Fourier's law. Local thermalization in our models occurs as the result of binary collisions among locally confined gas particles. We explore the conditions under which relaxation to local equilibrium, which involves no energy exchange, takes place on time scales shorter than that of the binary collisions which induce local thermalization. The role of this mechanism in multiphase material systems such as aerogels is discussed.     

Poly (3,4-ethylenedioxythiophene): polystyrene sulfonate (PEDOT:PSS) Zr(IV) phosphate composite cation exchanger : sol-gel synthesis and physicochemical characterization

An organic-inorganic composite cation exchanger poly (3,4-ethylenedioxythiophene): polystyrene sulfonate (PEDOT:PSS) Zr(IV) phosphate was prepared by the sol-gel method for removal of cadmium, a toxic heavy metal pollutant causing adverse effects on human health. The synthesized material was characterized by various techniques such as thermo gravimetric analysis/differential thermal analysis/differential thermo gravimetry (TGA/DTA/DTG), scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray powder diffraction (XRD), and Fourier transform infrared spectroscopy (FT-IR). Organic polymer PEDOT:PSS binds with the inorganic counterpart and prevents the leaching of the inorganic parts, hence PEDOT:PSS Zr(IV) phosphate composite cation exchanger has improved ion exchange capacity than inorganic ion exchanger. The composite cation exchanger was found selective towards Cd(II) ions. The nature and composition of contacting solvents influence the selectivity of composite cation exchanger. The composite cation exchanger may be used for the removal of cadmium a toxic heavy metal ion.     

Improved two-temperature model including electron density of states effects for Au during femtosecond laser pulses

The electron temperature dependences of the electron–phonon coupling factor and electron heat capacity based on the electron density of states are investigated for precious metal Au under femtosecond laser irradiation. The thermal excitation of d band electrons is found to result in large deviations from the commonly used approximations of linear temperature dependence of the electron heat capacity, and the constant electron–phonon coupling factor. Results of the simulations performed with the two-temperature model demonstrate that the electron–phonon relaxation time becomes short for high fluence laser for Au. The satisfactory agreement between our numerical results and experimental data of threshold fluence indicates that the electron temperature dependence of the thermophysical parameters accounting for the thermal excitation of d band electrons should not be neglected under the condition that electron temperature is higher than 10⁴ K.     

Pion interferometry at RHIC: porobing a thermalized quark-gluon plasma?

We calculate the Gaussian radius parameters of the pion-emitting source in high-energy heavy-ion collisions, assuming a first-order phase transition from a thermalized quark-gluon plasma (QGP) to a gas of hadrons. Such a model leads to a very long-lived dissipative hadronic rescattering phase which dominates the properties of the two-pion correlation functions. The radii are found to depend only weakly on the thermalization time tau(i), the critical temperature Tc (and thus the latent heat), and the specific entropy of the QGP. The model calculations suggest a rapid increase of R(out)/R(side) as a function of KT if a thermalized QGP were formed.     

Temperature dependences of the electron-phonon coupling, electron heat capacity and thermal conductivity in Ni under femtosecond laser irradiation

The electron temperature dependences of the electron-phonon coupling factor, electron heat capacity and thermal conductivity are investigated for Ni in a range of temperatures typically realized in femtosecond laser material processing applications, from room temperature up to temperatures of the order of 10⁴ K. The analysis is based on the electronic density of states obtained through the electronic structure calculations. Thermal excitation of d band electrons is found to result in a significant decrease in the strength of the electron-phonon coupling, as well as large deviations of the electron heat capacity and the electron thermal conductivity from the commonly used linear temperature dependences on the electron temperature. Results of the simulations performed with the two-temperature model demonstrate that the temperature dependence of the thermophysical parameters accounting for the thermal excitation of d band electrons leads to higher maximum lattice and electron temperatures achieved at the surface of an irradiated Ni target and brings the threshold fluences for surface melting closer to the experimentally measured values as compared to the predictions obtained with commonly used approximations of the thermophysical parameters.     

金属泡沫填充水平圆管内单相对流换热研究

本文用R134a的过热蒸汽为工质对金属泡沫填充管的管内单相对流换热特性进行了试验研究,讨论了不同参数的金属泡沫对管内单相对流换热和压力损失的影响.针对金属泡沫填充管的特点(金属泡沫和管壁之闻存在接触热阻),本文讨论了不同填充方法和不同成分的金属泡沫对总体换热特性的影响.     

杂质离子对等离子体边界参量的影响

采用一维流体模型研究了含有杂质离子的等离子体与器壁材料相互作用给边界等离子体参量带来的影响.通过数值模拟，研究了分别选用碳和钨作为器壁材料时，器壁温度不同情形下热发射产生的电子对等离子体器壁电势、电场强度、热发射电子流以及沉积器壁离子动能流的影响.研究结果发现，当面向等离子体材料表面温度升高时，器壁电势和热发射产生的电流将增加，器壁电场强度和离子沉积器壁动能流则会减小，并且钨作为器壁材料要比碳作为器壁材料对于等离子体边界参量影响更明显.此外，研究了钨作为器壁材料时，碳杂质离子（浓度和电荷数）对等离子体器壁参量的影响.     

超短脉冲激光辐照金属薄膜温升效应的模拟研究

 考虑到材料的质量热容、热导率、驰豫时间等热力学参数随温度非线性变化因素的影响，利用具有人工粘性的、自适应时间步长的前向差分算法，数值求解了电子-晶格双温双曲两步热传导模型，讨论了厚度为50 nm的金膜在0.1 ps脉冲激光辐照下的温升规律。数值结果表明：薄膜前表面自由电子的温度在大约0.27 ps时达到最大值，不同厚度上自由电子达到温度平衡所需的时间大约为1.6 ps，而薄膜温度在整个厚度上达到平衡所需时间为60 ps左右。由电子温度及其温度梯度引起的热电子崩力很可能是造成材料破坏的一个主要因素。     

Effect of electron beam irradiation on the structural,thermal and optical properties of poly(vinyl alcohol) thin film

Poly(vinyl alcohol) (PVA) polymer was prepared using the casting technique. The obtained PVA thin films have been irradiated with electron beam doses ranging from 20 to 300 kGy. The resultant effect of electron beam irradiation on the structural properties of PVA has been investigated using X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR), while the thermal properties have been investigated using thermo-gravimetric analysis and differential thermal analysis (DTA). The onset temperature of decomposition T ₀ and activation energy of thermal decomposition E _a were calculated, results indicate that the PVA thin film decomposes in one main weight loss stage. Also, the electron beam irradiation in dose range 95–210 kGy led to a more compact structure of the PVA polymer, which resulted in an improvement in its thermal stability with an increase in the activation energy of thermal decomposition. The variation of transition temperatures with electron beam dose has been determined using DTA. The PVA thermograms were characterized by the appearance of an endothermic peak due to melting. In addition, the transmission of the PVA samples and any color changes were studied. The color intensity Δ E was greatly increased with increasing electron beam dose, and was accompanied by a significant increase in the blue color component.     

Vortex sink under conditions of a thermal choking with regard to the real properties of gases

Changes in the formulation of the problem for a vortex source and a vortex sink upon taking into account the change in the heat capacity and the adiabatic exponent for a diatomic gas (for the example of air) in response to an increase in the temperature from 300 K to a few thousands of Kelvin are discussed. A thermal choking is studied for a vortex sink, and critical values of the energy parameter are calculated. It is shown that the minimal radius of the vortex sink decreases upon a heat release. Similarity parameters including the dimensionless circulation (or mass flow), the energy parameter, and the position and thickness of the heat-release region are varied. Errors of the gas model that assumes constant heat capacities and a constant adiabatic exponent are estimated.     

Determining the thermophysical properties of Al-doped ZnO nanoparticles by the photoacoustic technique

The thermal conductivity and specific heat capacity of undoped and Al-doped (1-10 at.%) ZnO nanoparticles prepared using the solvent thermal method are determined by measuring both thermal diffusivity and thermal effusivity of a pressed powder compact of the prepared nanoparticles by using the laser-induced photoacoustic technique. The impact of Al doping versus the microstructure of the samples on such thermal parameters has been investigated. The results reveal an obvious enhancement in the specific heat capacity when decreasing the particle size, while the effect of Al doping on the specific heat capacity is minor. The measured thermal conductivities are about one order of magnitude smaller than that of the bulk ZnO due to several nested reducing heat transfer mechanisms. The results also show that Al doping significantly influences the thermal resistance. Using a simple thermal impedance model, the added thermal resistance due to Al dopant has been estimated.     

一种基于激光辐照热效应的薄膜参数反演方法

本文研究并建立了一种基于激光辐照热效应的薄膜参数反演方法.首先给出激光辐照薄膜产生温升问题的热传导理论模型,并利用拉普拉斯变换得到了膜层和基底温度场的解析解;然后以膜层和基底的导热系数为反演参数,基于非线性共轭梯度算法给出反演基本原理及流程,并推导得到了反演过程中灵敏度系数的解析表达式;以aluminum,silver,copper和gold四种金属薄膜为例,通过与有限元法的计算结果对比验证了温度场解析解的正确性;最后结合四种金属薄膜进行了参数反演,通过考察分析不同随机噪声等条件下的参数反演结果,验证了本文方法在薄膜参数反演精度与反演效率等方面的有效性.反演结果显示:本文方法具有较高的反演精度和效率,在迭代截止误差为10~(-7)时只需用少于20次迭代就能收敛;在测量数据中加入的随机噪声越小,反演的迭代收敛次数就越少,即使是在迭代初值与反演结果相差较大时,用包含5%随机噪声的测量数据反演也能快速收敛.本文提出的薄膜参数反演方法不仅适用于反演导热系数,也可扩展用于反演膜层反射系数或吸收率等参数,具有一定的适用性.本文方法对于激光加工或激光损伤过程中的参数反演及优化具有一定的指导意义.     

Thermodynamic properties of electron gas in complex-shaped quantum well

Thermodynamic properties of degenerate two-dimensional electron gas in complex-shaped quantum well are studied. We determine the equation of state, chemical potential, entropy and heat capacity of the electron gas. An influence of profile and parameters of the quantum well on thermodynamic characteristics are investigated.