La0.7Ca0.3MnO3超大磁电阻材料正电子湮没研究

对La0.7Ca0.3MnO3材料样品在77K至室温范围的一系列温度, 测量了正电子寿命谱和多普勒展宽谱.结果表明在居里温度附近正电子平均寿命和多普勒线形参数S出现明显变化, 反映了此类化合物晶格结构的不稳定性.本文对此进行了讨论.     

MoO3/Al2O3催化剂中Mo分散的正电子研究

用浸渍法制备了一系列不同Mo含量的MoO3/Al2O3催化剂.测量了这些样品的正电子湮没寿命谱(PALS)与符合多普勒展宽(CDB)谱,以研究其孔洞结构以及Mo分散.正电子寿命测量结果表明,Al2O3载体中存在两种不同尺寸的孔洞.掺入MoO3之后,Mo原子主要进入Al2O3的大孔中,使孔洞体积减小.符合多普勒展宽谱结果表明,当MoO3的质量含量仅为3%时,多普勒展宽谱即发生了显著的改变.这表明Mo已分散至Al2O3的孔洞中,使得正电子测量所得到的电子动量分布发生改变.在MoO3含量达到18%之后,Al2O3中大孔的体积减小到尺寸与小孔相当,此后正电子寿命和多普勒展宽谱不再随MoO3含量变化,表明Mo分散逐渐达到饱和.     

二维粗糙海面散射回波多普勒谱频移及展宽特征

基于二维线性海面模型及粗糙面电磁散射的一阶小斜率近似公式,研究了海面回波各阶多普勒谱的频移特性,得到了多普勒谱频移所对应的理论公式,与经典多普勒频移公式相比考虑到了风速、大尺度波浪轨道运动等因素对多普勒谱频移的影响;同时根据粗糙面的双尺度模型,基于多普勒谱频移的物理机理,给出了求解散射场多普勒谱展宽的理论公式.最后将理论公式计算所得结果与模拟结果及实测数据进行了比较,讨论了风速、入射波频率及入射角等因素对多普勒频移及多普勒谱展宽的影响.通过比较可以发现,给出的理论公式可以对多普勒谱频移和展宽进行一定程度的预测. 关键词： 粗糙海面 电磁散射 多普勒谱     

金属元素的正电子鉴别技术

测量了20种金属元素的符合多普勒展宽谱,并与理论计算的结果比较．CDB谱的高动量部分反映了正电子与核心电子的湮灭,由于核心电子在原子组成材料时仍然保留了元素特性,CDB谱的高动量部分可以用来鉴别元素．     

MoO3/Al2O3催化剂中Mo分散的正电子研究

用浸渍法制备了一系列不同Mo含量的MoO₃/Al₂O₃催化剂.测量了这些样品的正电子湮没寿命谱(PALS)与符合多普勒展宽(CDB)谱,以研究其孔洞结构以及Mo分散.正电子寿命测量结果表明,Al₂O₃载体中存在两种不同尺寸的孔洞.掺入MoO₃之后,Mo原子主要进入Al₂O₃的大孔中,使孔洞体积减小.符合多普勒展宽谱结果表明,当MoO 关键词： 3/Al₂O₃催化剂')" href="#">MoO₃/Al₂O₃催化剂 正电子湮没寿命谱 符合多普勒展宽 Mo 分散     

一种消除无多普勒双光子光谱中的多普勒背景方法

本文利用内调制光谱和无多普勒双光子吸收的原理,提出了消除在无多普勒双光子吸收测量和荧光测量中的多普勒展宽背景的测量技术。     

符合多普勒展宽谱的源修正研究

测量了Ti,Ni,Cu,Al以及Si的符合多普勒展宽谱。对于Ni的多普勒展宽谱,采用最小二乘法拟合得出其中的源强度。给出了源修正前后湮没量子在Si中的多普勒展宽谱,讨论了源成分的影响。用高斯-抛物线模型拟合多普勒展宽谱,将多普勒展宽谱中自由电子的湮没贡献和束缚电子的湮没贡献分开,进而探讨了只对束缚电子的湮没贡献做源修正的方法。In the present work, Coincidence Doppler Broadening （CDB） measurements have been performed for five elements i.e. Ti, Ni, Cu, Al and Si. As to the CDB spectra of Ni, we obtained the annihilation fraction of positron-electron pairs in the source by least square fitting. After source correction, spectra for Si are also given to indicate the influence of source components. CDB spectra were simulated with Gauss-Parabola model to separate annihilation contribution of core electrons from outermost electrons. Furthermore, a new source correction method, i.e. source correction will be done only in the contribution of core electron, has been presented     

基于铷原子双光子跃迁的原子谱线展宽机制教学演示

测量原子光谱是揭示微观粒子微观结构与运动规律的重要手段，因而从本科到研究生阶段都会涉及到相关领域的教学，特别是光谱的相关教学。然而，由多普勒效应等引起的非均匀展宽及原子碰撞等引起的均匀展宽极大限制了谱线的分辨精度。在科学技术的发展中，为了获得更高的分辨精度，消除原子谱线的展宽成为重点研究方向。而在相关教学方面，碱金属原子体系由于其优异的能级特性，成为了研究展宽机制的有效途径。而在目前的本科教学中，缺乏除对多普勒展宽以外的多种原子谱线展宽机制的演示。因此，本文利用铷原子5S_1/2→5P_3/2→5D_5/2双光子跃迁谱线，测量改变激光功率、原子池温度等条件下引起的原子谱线半宽变化，验证双光子跃迁的同时，重点演示了原子谱线展宽的机制以及谱线半宽的测量方法。通过本实验，本科生一方面可以掌握原子谱线展宽与双光子跃迁的相关知识，以更深刻地理解了理论知识的内涵，另一方面通过自主搭建实验仪器锻炼了本科生的动手能力，对提升物理专业本科学生的素养尤为重要。本文所展示的实验装置简单，易于搭建，适合课堂演示和实验教学。     

Fe3O4-C核壳型纳米纤维的正电子研究

利用正电子手段研究新型多功能材料Fe₃O₄-C 纳米管核壳结构纳米纤维的内部电子结构,通过测量和分析正电子湮没寿命谱和符合双多普勒展宽谱,发现在这种材料中部分正电子在Fe₃O₄内部的单空位中发生湮灭,部分正电子在Fe₃O₄的微空洞中发生湮灭,部分正电子在壳层碳纳米管中湮灭.并估算了各个部分的湮灭比例,在一定程度上揭示了Fe₃O₄-C 关键词： 正电子 纳米纤维 寿命 符合多普勒     

LDA的相干性展宽

LDA(激光多普勒流速计)的光电流谱宽中包含各种不同的多普勒模糊展宽,当多普勒模糊展宽还不能确定时,就无法由光电流谱来得到湍流脉动速度的谱。由两个散射粒子产生的互差拍在谱展宽中起重要作用,当散射粒子对处于“相干体”内时,互差拍将在光电检测器的输出中产生差拍频率信号,与相干体尺度有关的互差拍持续时间是散射粒子的有效泼越时间,它所对应的谱宽称为相干性展宽,此展宽与空间相干条件是密切相关的.互差拍项以及它与检测模式的关系可以用组合三元散射模型及特殊光学系统来显示,实验研究结果指出:当相干体和测量体的尺度是同量级时,相干性展宽达到最小值。     

Magnetic Resonance Study of Detonation Nanodiamonds with Surface Chemically Modified by Transition Metal Ions

We report on electron magnetic resonance (EMR) and nuclear magnetic resonance (NMR) study of detonation nanodiamonds (DND) with the surface modified by copper and cobalt ions. The EMR spectrum of the pure DND sample shows an intense singlet originating from broken carbon bonds, while the spectra of copper- and cobalt-modified samples reveal additional signals with g > 2 and pronounced hyperfine structure (for copper). Increase in the Cu/Co concentration causes an increase of the corresponding EMR signals and broadening of the intense carbon-inherited singlet line. Subsequent annealing of the copper-modified samples in a hydrogen gas stream at 550 and 900°C causes narrowing of the singlet line and reduction of the Cu²⁺-related components. Applying the same annealing process to the cobalt-modified samples leads to broadening of the singlet line, reduction of Co²⁺ component and appearance of new intense low-field signals. NMR data correlate well with the EMR findings and yield information on interactions and locations of transition metal ions. ¹³C nuclear spin–lattice relaxation rate R ₁ in pure DND is driven by the interaction of nuclear spins with unpaired electron spins of broken bonds. Chemical modification of the DND surface by Cu and Co causes an increase in the relaxation rate, revealing appearance of paramagnetic Cu²⁺ and Co²⁺ complexes at the DND surface and their interaction with the carbon nuclear spins, both directly and via a coupling of Cu²⁺ and Co²⁺ electrons with those of the broken bonds. The aforementioned annealing of the Cu- and Co-DND results in an inverse process, i.e., a reduction of the relaxation rate, indicating that these complexes are destroyed and metal ions presumably join each other forming copper and cobalt nanoclusters. In the case of Co the nanoclusters are ferromagnetic, which results in the noticeable broadening of the ¹³C NMR lines.     

利用正电子湮没技术研究钾掺杂钨合金中的缺陷

钨合金中钾的掺杂会引入大量的缺陷,如尺寸几十纳米的钾泡、高密度的位错以及微米量级的晶粒带来的晶界等,这些缺陷的浓度和分布直接影响合金的服役性能.本文运用正电子湮没谱学方法研究钾掺杂钨合金中的缺陷信息,首先模拟计算了合金中各种缺陷的正电子湮没寿命,发现钾的嵌入对空位团、位错、晶界等缺陷的寿命影响很小;然后测量了不同钾含量掺杂钨合金样品的正电子湮没寿命谱,建立三态捕获模型,发现样品中有高的位错密度和低的空位团簇浓度,验证了钾对位错的钉扎作用,阐述了在钾泡形成初期是钾元素与空位团簇结合并逐渐长大的过程;最后使用慢正电子多普勒展宽谱技术表征了样品中缺陷随深度的均匀分布和大量存在,通过扩散长度的比较肯定了钾泡、晶界等缺陷的存在.     

The CDW phase transformation in 1T-TaS2 observed by the doppler broadening of positron annihilation

The layered transition metal dichalcogenide 1T-TaS₂ was studied by the Doppler broadening of positron annihilation. The Doppler broadened line- shape was measured over the temperature range between 77 and 292 K. The CDW phase transformation at about 200 K is discussed in terms of the W-parameters calculated from the energy spectra.     

Tunable-laser derivative spectroscopy on spectral lines with combined Doppler and collision broadening

In derivative spectroscopy, we optimize the measurement sensitivity by utilizing the maximum excursion of the derivative of the spectral absorption coefficient as a single spectral line is scanned. Results for lines with pure Doppler or Lorentz contour have been given previously. We present here the required spectroscopic data for spectral lines with combined Doppler and collision broadening.     

The use of positron annihilation Doppler broadening spectroscopy in the characterization of radiochromic dosimetry films

The positron annihilation Doppler broadening (PADB) spectroscopy has been employed to probe the defects and structural changes of various types of materials. In this work, an investigation was carried out for the first time to use PADB spectroscopy in probing the γ irradiated radiochromic films. The GafChromic MD–55 and HD–V2 radiochromic films irradiated with absorbed doses ranges of 0–80 and 0–2000 Gy, respectively, were subjected to Doppler broadening measurements employing a HPGe γ–ray spectrometer. The Doppler broadening line–shape parameters (S and W) of 511 keV annihilation radiations were discussed in terms of the polymerization degree of the active components of these dosimetry films. The S- and W-parameters were found to be dependent on the active component structures of both films. A reasonable correlation was also found between the values of the S–parameter and the optical density of these radiochromic films. In addition, the Doppler broadening line–shape parameters were successfully used to provide explanation of the observed nonlinearity of these films at the end of their dynamic dose ranges. The results demonstrate the applicability of the PADB technique to probe the physical and chemical changes occurred in the active layer of the studied radiochromic films during the solid–state polymerization reaction caused by γ irradiation of different absorbed doses.     

高气压微波氢等离子体发射光谱诊断

在2.45GHz,800W级的高气压微波等离子体放电系统中,通过测量不同微波功率和放电气压下氢等离子体的Balmer线系的发射光谱,从测量的谱线总展宽中卷积去掉具有高斯线形的Doppler展宽和仪器展宽得到谱线的Stark展宽,并通过Stark展宽测量氢等离子体的电子数密度和电场强度。结果表明:等离子体的电子数密度和电场强度随着放电气压的升高都是先增大后减小,随着微波功率的增加呈现逐渐增大的趋势。微波功率为800W时,气压在25kPa时电子数密度和电场强度都达到最大值,等离子体的电子数密度和内部的电场强度分别为3.55×1012cm-3及4.01kV/cm。     

Excessive hydrogen and deuterium Balmer lines broadening in a hollow cathode glow discharges

Results of a Doppler spectroscopy study of hydrogen and deuterium Balmer lines in the stainless steel and copper hollow cathode glow discharge, operated in pure hydrogen, deuterium and mixtures of inert gases with hydrogen, are reported. For all gases and gas mixtures plasma observations perpendicular to electric field revealed the excessively large Doppler broadening. By changing mode of glow discharge operation, the Doppler broadened line profiles in helium-hydrogen mixture are recorded parallel to the discharge electric field as well. The excessively broadened part of the H line profile is shifted towards blue or red wavelength by changing the direction of electric field vector. The presence of large excessive Balmer lines broadening in pure hydrogen and in its gas mixture with neon as well as shifting of the excessively broadened part of line profile by means of electric field is in contradiction with the resonance transfer model proposed by Mills et al. in several publications, see e.g. [IEEE Trans. Plasma Sci. 31, 338 (2003)].     

用正电子湮没多普勒增宽谱测量金属中电子的费米能级

高校中不少实验室具有半导体探头能谱仪,可扩展用作正电子湮没多普勒增宽谱仪,并测量金属中电子的费米能级     

Revision on the calculation of optically pumped FIR laser spectrum with Doppler broadening and pressure broadening effects

By means of iteration method and also taking into account Doppler broadening and pressure braodening effect of IR pumping laser, the output power density of optically pumped NH₃ molecules FIR laser is calculated by solving density matrix equations of three-level system. The results of theoretical calculation shows that, in comparison with the FIR laser under the assumption of ideal monochromatic IR pumping, the output power density of FIR laser in the case of Doppler broadening and pressure broadening IR pumping decreases much more. Meanwhile, via the revision of Doppler broadening and pressure broadening effect, the theoretical value of optimum operating gas pressure reduces, which is in better agreement with the experimental value. Further study shows that the revision of Doppler broadening effect is more fit for the conventional FIR laser with a 2m sample tuble and the revision of pressure broadening effect is much more suitable for the miniature FIR laser with a short sample tube of 5 to 20cm in length.Supported by the National Natural Sciences Foundation of P.R.China and the NSF of Guangdong Province.