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多孔氧化铝膜的荧光研究 总被引:2,自引:2,他引:0
采用电化学方法在草酸溶液中制备铝基多孔阳极氧化铝膜,用原子力显微镜观察其形貌,得到平均孔径为 38 nm的有序排列.用F-4500型荧光分光光度计测量其三维荧光谱,与未经氧化的铝片作对比,发现前者的激发谱在280 nm~340 nm有一个较宽的谱带,并且在253.8 nm附近有一个肩峰,发射谱有一个以417.4 nm为峰值的较宽谱带,而后者却无任何明显的发射峰和激发峰.再分别用波长为248 nm的准分子激光器和波长355 nm的三倍频YAG激光器激发,得到明亮的蓝光光谱,在同样条件下激发未经阳极氧化的高纯铝片,将二者的光致发光谱进行对比处理.实验认为,这种发光机理可能是来源于薄膜中与氧空位有关的缺陷态,而且,在成膜过程中伴随着草酸根离子的介入,导致多孔阳极氧化铝膜中亦有与草酸根离子相关的发光中心,同时,量子限域效应也使氧化铝薄膜的光学性质发生了变化. 相似文献
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在490-500nm波长范围内观测了超声射流冷却PH2自由基的激光诱导荧光激发谱,得到了在转动K的情况下PH2A^2A1←X2B1适中(0,0,0)←(0,0,0),(0,1,0)←(0,0,0)和(0,2,0)←(0,0,0)三个振动谱带的转动分辨光谱,对这三个谱带中的约220条转动谱线进行了归属,其中52条谱线是我们新标识的。从转动结构,我们获得了气相PH2自由基的全部分子常数,其中εbb,ε 相似文献
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有机抽提对泥炭中的木栓质体荧光光谱特性的影响 总被引:3,自引:1,他引:2
钟建华 《光谱学与光谱分析》1997,17(3):119-122
对泥炭中的木栓质体及泥炭有机抽提残渣中的木栓质进行了荧光(光谱)对比研究,研究发现有机抽提对泥炭中的木栓质体的荧光(光谱)性影响很大,有机抽提前泥炭中的木栓质体发鲜艳的黄绿至绿色荧光:λmax=470~520nm;Q650/500=0.10~0.54。有机抽提后泥炭中的木栓质体则发暗黄色橙黄色荧光:λmax=605~660nm,Q650/500=1.85~4.09,有机抽提使木栓质体的荧光强度(I 相似文献
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NO2分子589.3~594.0 nm荧光激发谱转动分析 总被引:1,自引:0,他引:1
本文报道了实验测定的NO2分子在589.3 ̄594.0nm范围的高分辨荧光激发谱,对其中11个振动带较完整的转动分析表明,荧光谱线主要来自^2B2(K=0)→^2A1(K=0)的平行跃迁,得到了各带光谱数,并对光谱结构复杂性进行了讨论。 相似文献
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J.H. Chen C.P. Huang C.G. Chao T.M. Chen 《Applied Physics A: Materials Science & Processing》2006,84(3):297-300
To investigate the origin of blue photoluminescence (PL) in porous alumina membrane, we have prepared an anodic aluminum oxide film with a pore diameter of 40 nm in oxalic acid solution by a two-step anodization process. Our results show that the as-prepared alumina membrane is amorphous and exhibits a broad emission band peaking at around 452 nm with two sub-peaks located at 443 nm and 470 nm. As indicated by the PL excitation spectra, there are two excitation peaks which can account for the sub-peaks observed in the PL emission band. We have proposed that the broad emission band with two sub-peaks can be attributed to two luminescence centers in porous alumina membranes, namely, oxygen defects and oxalic impurities. Furthermore, we have rationalized that the two emission centers show similar influence on the PL band in the blue region based on a simple model. PACS 81.07.-b; 81.16.Dn; 79.60.Jv 相似文献
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报道了用15wt%H2SO4为电解液,在恒温0℃,40V电压条件下制备阳极氧化铝膜,用原子力显微镜观察其形貌,表明在简单条件下在石英衬底上制备了致密的氧化铝微晶膜。研究了不同电压条件下制备的氧化铝膜的常温光致发光,并监测了其激发光谱,发现其常温光致发光相对强度和发射峰位置与阳极氧化电压关系密切,有相对强度变小和发射峰位置红移的趋势,在40V电压条件下出现了356nm新的发射峰,而其不同的发射峰激发光谱都为210nm,说明其来源存在关联。详细分析了40V电压下的阳极氧化铝膜中出现的356,386nm近紫外发射,并认为其发光来源于与F心和F^ 心有关的氧缺陷。 相似文献
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Q.P. Wang X.J. Zhang G.Q. Wang S.H. Chen X.H. Wu H.L. Ma 《Applied Surface Science》2008,254(16):5100-5104
Highly orientated polycrystalline ZnO films were deposited on sapphire, silicon and quartz substrates at room temperature by r.f. magnetron sputtering. Different photoluminescence (PL) spectra were observed when excited with different wavelength light. A UV emission peak (356 nm) and a blue peak (446 nm) were generated for the films on sapphire, silicon and quartz substrates, and only the 446 nm blue emission appeared for the films on glass substrates when the wavelength of the excitation light was 270 nm. With increasing the wavelength of the excitation light up to 300 and 320 nm, the UV emission disappeared for films on various substrates and the wavelength of the PL peaks increased up to 488 and 516 nm, respectively. When the wavelength of the excitation light increased to 398 nm, the PL spectrum becomes a wide band that is consistent with three emission peaks. 相似文献
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以草酸为电解液,采用二次阳极氧化法制备出了纳米多孔氧化铝薄膜,经不同退火温度和退火气氛处理氧化铝薄膜后,通过分析其光致发光光谱得出:相同的退火气氛中, 退火温度T≤600 ℃ 时,T=500 ℃具有最大的光致发光强度;退火温度T≥700 ℃时,随着退火温度的升高,样品的发光强度增大。在不同的退火气氛中,多孔氧化铝薄膜随着退火温度的升高,发光峰位改变不同,即在空气中退火处理后,随着退火温度的升高,发光峰位蓝移,而在真空中退火处理后,发光峰位并不随退火温度的升高而变化;通过对1 100 ℃高温退火处理后的氧化铝薄膜的光致发光曲线的高斯拟合,可以看出,经退火处理后的多孔氧化铝,主要存在三个发光中心,发光曲线在350~600 nm范围内对应三个发射峰, 发射波长分别为387,410,439 nm。相同的退火温度下,空气中退火得到的氧化铝薄膜的光致发光强度大于真空中退火处理后的氧化铝薄膜。基于实验结果,结合X射线色散能谱(EDS)、红外反射光谱等表征手段,探讨了多孔氧化铝薄膜的发光机制,并对经过不同退火条件得到的多孔氧化铝薄膜的光致发光特性的改变做出了合理的解释。 相似文献
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In the present work IR spectroscopy, electron probe microanalysis (EPMA) and photoluminescence (PL) spectral measurements were applied to study the effect of treatment temperature (T) on compositional and luminescent properties of malonic acid alumina films. Our studies have shown that the heat treatment of anodic alumina films at investigated temperatures from 100 up to 700 °C changes their photoluminescence spectra considerably. An increase in T results in the PL intensity growth. When reaching its maximum at 600 °C the luminescence intensity then decreases drastically with further T growth. The films heat-treated at 500 and 600 °C demonstrate asymmetrical PL band with Gaussian peaks at 437 and 502 nm. We proved that the malonic acid species incorporated into the alumina bulk during the film formation are responsible for photoluminescence band with its peak at 437 nm. 相似文献
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LiGaO2衬底上ZnO外延膜的结构与光学特性 总被引:3,自引:2,他引:1
采用磁控溅射法在(001),(100)及(010)LiGaO2衬底上制备了ZnO薄膜,通过X射线衍射(XRD)、原子力显微镜(AFM)、透过光谱以及光致发光谱(PL)对薄膜的结构、形貌及光学性质进行了表征.结果表明LiGaO2衬底不同晶面上制备的ZnO薄膜具有不同的择优取向,在(001)、(100)及(010)LiGaO2上分别获得了[001]、[1100]及[1120]取向的ZnO薄膜;不同取向的ZnO薄膜表面形貌差异较大;薄膜在可见光波段具有较高的透过率;在ZnO薄膜的光致发光谱中只观察到了位于378 nm的紫外发射峰,而深能级发射几乎观察不到,(1100)取向的薄膜紫外发射峰强度最大,半高宽也最小,薄膜光致发光件质的差异丰要和晶粒尺寸有关. 相似文献
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Photoluminescent and optical properties of porous oxide films formed by two-step aluminum anodization at a constant potential of 30 V in sulfamic acid have been investigated after their annealing, ranging from room temperature up to 600 °C. X-ray diffraction reveals the amorphous nature of porous oxide films. Infrared and energy dispersive spectroscopy indicates the presence of sulfuric species incorporated in oxide films during the anodization. Photoluminescence (PL) measurements show PL bands in the range from 320 to 600 nm. There are two peaks in emission and excitation spectra. One emission peak is at constant wavelength centered at 460 nm and the other shifts from 390 to 475 nm, depending on excitation wavelength. For excitation spectra, one spectral peak is at constant wavelength at 270 nm and the other also shifts to longer wavelengths while increasing emission wavelength. Upon annealing of the as-prepared oxide films PL increases reaching maximum value at about 300 °C and then decreases. The results indicate the existence of two PL centers, one placed at surface of the pore wall, while the other positioned inside the oxide films. 相似文献
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SiC films doped with aluminum (Al) were prepared by the rf-magnetron sputtering technique on p-Si substrates with a composite target of a single crystalline SiC containing several Al pieces on the surface. The as-deposited films were annealed in the temperature range of 400-800 °C under nitrogen ambient. The thin films have been characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM). The results show that the introduction of Al into films hinders crystalline formation process. And with the increase of annealing temperature, more Si particles are formed in the films, which strongly affect the optical absorption properties. The photoluminescence (PL) spectra of the samples show two peaks at 370 nm and 412 nm. The intensities of the PL peaks are evidently improved after Al doped. We attribute the origin of the two PL peaks to a kind of Si-related defect centres. The obtained results are expected to have important applications in modern optoelectronic devices. 相似文献
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为制备薄膜无机电致发光显示器件中的硫代铝酸钡(BaAl2S4:Eu)蓝色发光层薄膜,采用粉末烧结的方法,经过对BaS,Al2S3,等原材料的粉碎、研磨、高温烧结,以及热压等过程,制备出用于溅射镀制BaAl2S4:Eu蓝色发光层薄膜的靶材样品。对制备的BaAl2S4:Eu发光层薄膜进行的光致发光分析表明,在300nm紫外光激发下,薄膜能够发射出峰值位于470nm处的蓝光。对发光层薄膜的XPS分析结果表明,发光层薄膜中含氧量较高,随着溅射功率的提高,薄膜中铝元素有显著增加;而随着淀积压强的增大,硫元素则显著减少。 相似文献
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氧气分压对反应溅射制备TiO2薄膜带隙的影响 总被引:1,自引:0,他引:1
在不同的氧气分压下 ,用直流反应磁控溅射法制备了玻璃基TiO2 薄膜试样 ,测试了试样的荧光发射光谱。结果表明 ,氧气分压为 0 35和 0 6 5Pa时 ,荧光光谱在 370 ,4 72和 5 14nm处出现发射峰 ;氧气分压为 0 10和 0 15Pa时 ,发射光谱峰出现在 370和 4 90nm处。试样带隙为 3 35eV。0 35和 0 6 5Pa氧气分压下溅射的试样在带隙中有两个分别低于导带底 0 72和 0 94eV的缺陷能级 ,0 10和 0 15Pa氧气分压下溅射的试样在带隙中有一个位于导带底 0 2 3和 1 2 9eV之间的缺陷能带 ;增加氧气分压 ,缺陷能带转变成两个缺陷能级 ,在 0 6 5Pa氧气分压下 ,缺陷能级几乎消失。 相似文献