共查询到16条相似文献,搜索用时 640 毫秒
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通过原子层沉积技术在熔石英玻璃表面制备了同质材料的单层SiO2薄膜,对光学薄膜的物理化学性质和强激光辐照下的激光诱导损伤性能进行了深入研究。实验中采用双叔丁基氨基硅烷(BTBAS)和臭氧(O3)作为反应前驱体,在熔石英光学元件表面进行了SiO2薄膜的原子层沉积工艺研究,以不同沉积温度条件制备了一系列膜样品。首先对原子层沉积特性和薄膜均匀性展开了研究,发现薄膜生长厚度与沉积循环次数之间符合线性生长规律,验证了制备薄膜的原子级逐层生长特性,并且表面沉积膜层的均匀性很好,其测得膜厚波动不超过2%。然后针对不同温度条件下沉积的SiO2薄膜,对其粗糙度及各类光谱特性展开了研究,对比结果表明:样品的表面粗糙度在镀膜后有轻微的降低;薄膜样品在200~1 000 nm范围内具有出色的透过率,均超过90%并逐渐趋近于93.3%,且其透射光谱与在裸露熔石英衬底上测得的光谱没有明显差异;镀膜前后荧光光谱和傅里叶变换红外光谱的差异证实了原子层沉积SiO2膜中点缺陷(非桥键氧、氧空位、羟基等)的存在,这将会影响薄膜耐损伤性能。最后对衬底和膜样品进行了紫外激光诱导损伤测试,损伤阈值的变化表明熔石英元件表面沉积薄膜后的激光损伤性能有所降低,其零概率损伤阈值从31.8 J·cm-2减小到20 J·cm-2左右,与光谱缺陷情况表征相符合。薄膜中点缺陷部位会吸收紫外激光能量,导致局域温度升高,进而出现激光诱导损伤现象并降低抗激光损伤阈值。在选定的沉积温度范围内,较高温度条件下沉积的SiO2薄膜其激光诱导损伤性能更好,可以控制沉积温度条件使得元件的抗损伤性能更为接近衬底本身,后续有望通过其他反应参数的优化来获得薄膜抗损伤性能的进一步提升。 相似文献
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以锆酸丙酯[Zr(OPr)4]、正硅酸乙酯(TEOS)为原料, 用溶胶-凝胶(sol-gel)提拉法涂膜, 制备高透过的λ/ 4~λ/ 4型ZrO2/SiO2双层减反膜.该减反膜的表面均匀, 均方根(RMS)粗糙度为1.038 nm, 平均粗糙度(RA)为0.812 nm.制备的双层减反膜具有很好的减反效果, 在石英玻璃基片二面涂膜, 在激光三倍频波长351 nm处透射比达到99.41%, 比未涂膜石英玻璃基片的透射比提高了6.14%;在基频波长1053 nm处透射比达到99.63%, 比未涂膜K9光学玻璃基片的透射比提高了7.67%.膜层具有较高的激光损伤阈值, 在激光波长为1053 nm, 脉冲宽度为1 ns时, 薄膜的激光损伤阈值达到16.8 J/cm2.膜层具有良好的耐擦除性能. 相似文献
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采用溶胶凝胶法制备得到以正丙醇锆和正硅酸乙酯为前驱体的ZrO2和SiO2溶胶,通过TFCalc光学薄膜软件模拟了ZrO2/SiO2三层“宽M型”基频二倍频减反膜,并使用提拉法制备得到了该均匀膜层。三层减反膜在527 nm和1053 nm处的透过率约为99.5%,且透过率大于99%的波长范围均超过150 nm。经热处理后的膜层表面均方根粗糙度为1.34 nm,表面平整性良好;并运用1-on-1激光损伤阈值测试方法测得该减反膜的零几率激光损伤阈值达到36.8 J·cm-2(1064 nm,10.7 ns)。 相似文献
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利用改进的晶体生长设备和工艺提高了PbWO4闪烁晶体的光产额。通过对生长获得的PbWO4、退火PbWO4和BaF2∶PbWO4晶体的透过光谱,衰减时间和光产额等闪烁性质的研究,发现晶体退火和掺杂技术特别是阴离子掺杂技术能够显著提高晶体的闪烁发光性能。其中晶体掺杂全面提高了晶体的透过光谱强度,但是退火的影响较复杂。高温退火改善了PbWO4晶体在360 nm以上波段的透过光谱的透过率,但是在320~360 nm波段其透过率反而降低。这些现象与晶体中缺陷在可见光波段产生的特征吸收有关。晶体的良好退火和掺杂提高了晶体的光产额,其中BaF2∶PbWO4掺杂晶体室温闪烁发光强度达到65 p.e.·(MeV)-1,接近PET的使用要求。这种提高与晶体F-离子掺杂引发晶体[WO4]2-四面体基团畸变有关,F-离子进入该四面体产生了新的发光中心。 相似文献
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Liwang Ye Zhengdong Li Genbo Su Xinxin Zhuang Guozong Zheng 《Optics Communications》2007,275(2):399-403
KDP crystals were grown at growth rates from 5.0 to 19.0 mm/d. Transmittance, laser damage threshold and light scatter were detected. It has been shown that laser damage thresholds of KDP crystals decrease with the increase of the absorption coefficients. Large-scale impurity is an important factor that causes light absorption in UV range and reduces the damage threshold. 相似文献
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T. Suresh S. Vetrivel S. Gopinath R.U. Mullai 《Chinese Journal of Physics (Taipei)》2018,56(6):2773-2781
Single crystal of l-Asparagine Indium chloride (LAIn), a new semi-organic crystal was grown by slow evaporation method with deionized water as solvent at ambient condition. The crystal structure of LAIn has been determined by single crystal X-ray diffraction and the result shows that the crystal belongs to the orthorhombic system with P212121 space group. The crystalline nature of grown crystal was analyzed by powder X-ray diffraction analysis. Optical parameters, such as absorbance, transmittance and optical band gap energy were analyzed using UV–Vis NIR transmittance data at the range of 190–800?nm. The ultraviolet (UV) emission nature of the sample was established from the sharp emission peaks in photoluminescence (PL) spectrum. The photo conductivity test exhibits that the grown crystal has positive photo conductive nature. The induced surface laser damage threshold (LDT) for the grown crystal was measured using Nd:YAG laser. The nonlinear optical efficiency of the LAIn crystal was studied using modified Kurtz-Perry powder technique. The hardness, Meyer index, yield strength and elastic stiffness constant were calculated for the grown crystal using Vickers microhardness tester. The variation of dielectric constant and dielectric loss of the grown crystals as a function of frequency has been investigated at different temperatures. The melting point and thermal stability of the LAIn single crystal have been studied by thermo gravimetric analysis and differential thermal analysis (TG/DTA). 相似文献
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A new organic NLO material l-asparaginium l-tartarate (AST) was synthesized and good quality crystals were grown from aqueous solution. The solubility and metastable zone width for AST solution were determined. Single crystal X-ray diffraction and powder X-ray diffraction analyses were carried out to confirm structure and crystalline nature of AST crystal. Optical transmittance and second harmonic generation efficiency (SHG) of the grown crystal were studied by UV?vis?NIR spectrum and Kurtz powder technique respectively. The transmittance of AST crystal was used to calculate the refractive index (n), the extinction coefficient (k) and reflectance (R). The laser induced surface damage threshold for the grown crystal was measured using Nd:YAG laser. 相似文献
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采用籽晶法制备了大体积高质量的4-(4-二甲基氨基苯乙烯基)甲基吡啶对甲基苯磺酸盐(DAST)晶体,对制备条件进行了优化,对DAST晶体X射线衍射谱图中的主要峰进行了指标化.另外,还对所制备的DAST晶体的透光性、热稳定性进行了研究, 并对265℃的焙烧产物进行了X射线衍射 (XRD)和傅里叶变换红外光谱(FT-IR)测试,证明了260℃是DAST晶体的熔化相变温度, 说明采用熔融法制备DAST晶体是可行的;同时还对DAST晶体的热失重过程进行了初步探讨.
关键词:
4-(4-二甲基氨基苯乙烯基)甲基吡啶对甲基苯磺酸盐
晶体生长
X射线衍射
热稳定性 相似文献
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S. Manivannan S. Dhanuskodi S.K. Tiwari J. Philip 《Applied physics. B, Lasers and optics》2008,90(3-4):489-496
N-alkyl-2,6-dimethyl-4(1H)-pyridinones, salts of 4-dimethylaminopyridine and 2-amino-5-nitropyridine are considered to be
potential candidates for nonlinear optical (NLO) applications, in particular for the generation of blue-green laser radiation.
Single crystals were grown following the slow evaporation technique at constant temperature. Single-shot laser-induced surface
damage thresholds in the range 3–10 GW/cm2 were measured using a 18 ns Q-switched Nd:YAG laser. The surface morphologies of the damaged crystals were examined under
an optical microscope and the nature of damage identified. The Vicker’s microhardness was determined at a load of 98.07 mN.
The thermal transport properties, thermal diffusivity (α), thermal effusivity (e), thermal conductivity (K) and heat capacity
(Cp), of the grown crystals were measured by an improved photopyroelectric technique at room temperature. All the results are
presented and discussed.
PACS 42.70.Mp; 61.66.Hq; 67.80.Gb; 42.65.-k 相似文献
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An efficient nonlinear optical single crystal of 2-phenylethylammonium p-hydroxybenzoate (2PPHB) was grown from aqueous solution by slow evaporation solution growth method. Single crystal X-ray diffraction studies confirmed that 2PPHB crystallizes in orthorhombic crystal system with non-centrosymmetric space group of Pna21. The presence of functional groups in the synthesized compound was identified by FTIR spectral analysis. The grown crystals were thermally stable up to 155 °C. UV–vis absorption, photoluminescence and birefringence optical properties of grown crystal were explored. The laser induced surface damage threshold and relative second harmonic generation properties of the grown crystal were studied using Q-switched Nd:YAG laser. The variation of dielectric properties of the grown crystal with frequency was investigated for different temperatures. The mechanical response of the crystal was studied by Vicker's microhardness technique. 相似文献