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Co2+:ZnAl2O4晶体电子光谱及其2E态双重谱线结构的Jahn-Teller效应研究 总被引:5,自引:3,他引:2
在中间场耦合图象中,利用Racak不可约张量算符法和Wigner-Eckart定理,建立了3d7(C3v)电子组态的完全能量矩阵;利用该矩阵研究了Co2+:ZnAl2O4晶体的电子光谱,理论与观测十分吻合.首次定量地解释了2E态的双重谱线结构,并从理论上预言了4A2基态2.93cm-1的零场分裂(ZFS).研究结果定量地表明,Jahn-Teller效应所致Co2+:ZnAl2O4晶体Co2+中心局域结构的畸变假设是合理的. 相似文献
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利用X射线衍射分析和Rietveld结构精修方法研究了基于组分Ca2Pr2Cu5O10三元固溶区的范围和晶体结构。根据X射线分析结果和相消失法,为了保持Ca2+xPr2-xCu5O10结构单位晶胞中恒定的氧含量和电价平衡,基于组分Ca2Pr2Cu5O10的三元固溶区的范围可确定为:在Ca2+xPr2-xCu5O10固溶区的富Ca区(Ca/Pr>1),其表达式仍可以表示为一般的化学计量式Ca2+xPr2-xCu5O10(x=0.4, 0.2, 0);在富Pr区(Ca/Pr<1),其表达式为Ca1.7Pr2.2·Cu5O10、Ca1.4Pr2.4Cu5O10,即:Ca2+xPr2-xCu5O10固溶区范围从Ca2.4Pr1.6Cu5O10至Ca1.4Pr2.4·Cu5O10。研究表明:基于组分Ca2Pr2Cu5O10的三元固溶体晶体结构可以看作是正交晶系NaCuO2型亚晶胞的无公度相;Ca2.4Pr1.6Cu5O10亚晶胞的点阵常数为a0=0.282 46(7) nm,b0=0.636 93(1) nm,c0=1.067 94(1) nm;其正交超结构的点阵常数为a=5a0,b=b0,c=5c0。Ca2.4Pr1.6Cu5O10的结构也可以用单斜超晶胞来表述,该单斜超晶胞的空间群为P21/c,Z=4,a=5a0,b=b0,c=c0/sin β,β=104.79°或136.60°,V=5a0b0c0。在基于组分Ca2Pr2Cu5O10的三元固溶体晶体结构中,Ca和Pr之间在一定范围内是可以相互替代的,而且它们在结构中的占位是无序的。 相似文献
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本文利用X射线粉末衍射和位敏探测技术,研究了R2Fe4/3W2/3O7(R=Er、Yb、Dy)化合物经高温高压处理后的变化情况。在3.7 GPa,1 200 ℃条件下,六方相R2Fe4/3W2/3O7化合物按两种方式分解,而直接由R2O3,Fe2O3和WO3原料出发,经上述同样的高温高压条件合成所得的产物与六方相高温高压分解产物相同,均为R2WO6、RFeO3、WO3和Fe2O3的多相聚合物。同时给出了R2Fe4/3W2/3O7六方相高温高压下的稳定区范围。 相似文献
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提出了解释掺杂离子局域结构畸变的配体平面移动模型,建立了此模型下晶体微观结构与自旋哈密顿参量之间的定量关系.在考虑自旋与自旋、自旋与另一电子轨道和轨道与轨道作用等微小磁相互作用的基础上,采用全组态完全对角化方法,对Al2O3晶体中V3+的局域结构和自旋哈密顿参量进行了系统的研究.结果表明,V3+掺入Al2O3晶体后,上下配体氧平面间距离增大了0.0060 nm.从而成功地解释了Al2O3:V3+晶体的自旋哈密顿参量.在此基础上,研究了三角晶场下3d2离子自旋哈密顿参量的微观起源.研究发现,自旋三重态对自旋哈密顿参量的贡献是主要的,微小磁相互作用对自旋哈密顿参量的贡献只与自旋三重态有关. 相似文献
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以反滴共沉定法制备了NiFe2O4纳米微粉,并在不同压力下将其压制成纳成米固体,然后用XRD谱和ESR谱研究了NiFe2O4纳米固体结构和界百状态随压制压力的变化。实验结果表明,NiFe2O4纳米固体的结构在高压下没有明显的变化,但其ESR谱的共振线宽和g因子值随着压力升高均表示出先逐渐增大至最大值,然手缓慢下降的规律。这种变化可以归因于纳米固体内部界面离子间的磁相互作用在压力的下所发生和变化。这引起实验结果境示,对于NiFe2O4纳米固体而言,最佳的成型压力是4.5 GPa,在此压力下,NiFe2O4纳米粒子既可以被压制成致密的纳米固体,又能够保留下它们的纳米结构和纳米性质。 相似文献
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We calculated theoretically the properties of the nonlinear crystal CsLiB6O10 (CLBO) in third-harmonic generation (THG). These are the phase matching angle, the effective nonlinear coefficient, the walk-off angle, the permitted angle, and the permitted wavelength, and we found that CLBO has a small walk-off angle and large permitted parameters, as compared with BBO. The numerical simulation curves of the conversion efficiency were obtained for the case where CLBO was used in THG of a Q-switched Nd:YAG laser with a wavelength of 1064 nm and different pump powers and the optimized efficiency was as high as 22%. All this suggests that the CLBO crystal is more suitable for generating intense higher order harmonic radiation. 相似文献
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CsLiB6O10晶体光学参变振荡器的光学特性 总被引:3,自引:0,他引:3
根据三波耦合过程中的能量和动量守恒、晶体的塞耳迈耶尔色散方程,通过数值模拟计算了213nm作CLBO光学参变振荡抽运源时,分别得到了在Ⅰ类和Ⅱ类相位匹配时参量光调谐范围为237~289nm、807~2793nm和404~2800nm。获得了在Ⅰ类匹配时的单谐振或双谐振腔的CLBO光学参变振荡转换效率都大于同等条件下的BBO光学参变振荡,Ⅱ类匹配时,CLBO晶体的转换效率略小于BBO晶体,但是CLBO光学参变振荡转换效率的最大值较BBO光学参变振荡出现于更短的紫外波段。从理论上证明了CLBO晶体是优质的深紫外透光波段非线性光学晶体。 相似文献
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Yap YK Inoue T Sakai H Kagebayashi Y Mori Y Sasaki T Deki K Horiguchi M 《Optics letters》1998,23(1):34-36
We have successfully resolved the degradation problem of CsLiB(6)O(10) (CLBO) by means of elevated crystal temperature. CLBO crystals were continuously operated at 160 degrees C in ordinary room humidity. No degradation of performance was observed after more than 1 month. We believe that heating CLBO crystal above 130 degrees C can relieve stresses introduced by crystal hydration, cutting, polishing, and thermal shock owing to laser power absorption. Thus long-term operation of CLBO crystal is achieved for effective application of laser frequency conversion. Output stability from CLBO is also further enhanced at elevated crystal temperature. 相似文献
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We have generated 15 W of UV (255-nm) radiation with an optical conversion efficiency of 28% by frequency doubling the 510.6-nm output of a high-beam-quality, high-power copper laser system in cesium borate lithium (CLBO). We found that the superior performance of CLBO relative to beta-barium borate is attributable largely to the small UV absorption and wide temperature acceptance bandwidth of CLBO, which reduces thermal dephasing during high-power UV generation. 相似文献
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三硼酸铯和硼酸铯锂晶体的晶格振动光谱研究 总被引:1,自引:0,他引:1
本文对新型非线性光学晶体三硼酸铯(CsB3O5∶CBO)和硼酸铯锂(CsLiB6O10∶CLBO)进行了晶格振动光谱研究。首先对两种晶体的基本晶格振动模进行了对称性分类,记录了两种晶体低温下的拉曼光谱和室温下的红外反射光谱,对晶体的晶格振动模进行了认定,将振动模归属于平面六元环(B3O6)和四面体(BO4)。然后比较了CBO,CLBO和LBO(LiB3O5)三种晶体的晶格振动光谱,讨论了阳离子对振动光谱的影响。另外,还讨论了硼酸盐晶体晶格振动模LO TO分裂的大小与晶体非线性光学系数之间的关系。 相似文献
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I. N. Ogorodnikov V. A. Pustovarov A. V. Kruzhalov L. I. Isaenko M. Kirm G. Zimmerer 《Physics of the Solid State》2000,42(10):1846-1853
The paper presents the results of a complex investigation into the dynamics of electronic excitations in the CsLiB6O10 crystal (CLBO) by low-temperature luminescence VUV spectroscopy with subnanosecond time resolution under photoexcitation by synchrotron radiation. Strong broad-band low-temperature photoluminescence (PL) of the CLBO crystal has been revealed. Data on the PL decay kinetics, time-resolved PL and PL excitation spectra, and reflectance spectra at 9.3 and 295 K are obtained. It is shown that the intrinsic PL of CsLiB6O10 in the 3.5-eV range is caused by radiative annihilation of self-trapped excitons. The channels of creation and decay of relaxed and unrelaxed excitons in cesium lithium borate are discussed. The band gap of CLBO is estimated as E g≈8.5 eV. A monotonic increase in the excitation efficiency of intrinsic CLBO luminescence at exciting photon energies above 19 eV is identified as the photon multiplication process. 相似文献
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Achievement of more than 100 mW of pure continuous-wave deep-ultraviolet radiation at 213 nm has been demonstrated in an efficient all-solid-state laser system that uses two Brewster-cut CsLiB6O10 (CLBO) crystals. The first crystal is used for 266-nm generation by external resonant doubling of 532-nm radiation from a frequency-doubled Nd:YVO4 laser. Subsequent sum-frequency mixing is performed in a second CLBO crystal placed in a diode-pumped Nd:YAG laser cavity to mix the single-pass 266-nm output with circulating 1064-nm light. 相似文献
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In this paper, a detailed theoretical analysis of the second-harmonic generation (SHG) efficiency as a function of polarization ratio and crystal length of CsLiB6O10 (CLBO) in the phase matching using a computer simulation is presented. The SHG efficiency was as high as 80% when the pumping radiation was a plane wave. The efficiency is 65% and 80% for the pumping waves of type I and type II Gaussian beams, respectively. An important result is that the phase matching of type II is perfectly adopted in the SHG experiment with CLBO. 相似文献
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We have generated 4.7 W of UV (255-nm) radiation with wall plug efficiency of 0.12% by frequency doubling the green (511-nm) output of a kinetically enhanced medium-scale copper-vapor laser (CVL) in cesium lithium borate (CLBO). Frequency doubling in beta -barium borate produced 3.9 W of UV radiation with wall plug efficiency of 0.1%. We found that conversion was better with CLBO because of the reduced constraints on CVL beam quality, less UV absorption, and smaller UV walk-off. 相似文献