共查询到20条相似文献,搜索用时 78 毫秒
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本文给出了在红外光谱多外利用热受激后的原子材料产生紫外光谱的方法。文中给出了计算数据和实验结果。 相似文献
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基于光谱分类的端元提取算法研究 总被引:4,自引:0,他引:4
目前成熟的端元提取算法是基于单形体几何学的像元纯度指数(PPO)算法,N-FINDR,VCA等算法.这些算法从图像所有像元中提取纯光谱,具有提取速度慢、精度不高的缺点;部分算法需要进行光谱降维,不利于小目标信息的提取.该文提出先利用基于空间特征的光谱分类算法进行分类,将格个图像划分成空间相邻、光谱相似的若干类,每一类的... 相似文献
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本文报道了TixY1-xBa2Cu3O7-δ(x=0.2和0.4)在4.2—300K的红外、远红外光谱。在50—360cm-1波段内发现七个反射峰。它们分别与Ba,Cu,O离子团,Y,O离子团。Ti,O离子团,以及Cu—O键的振动有关,对于x=0.2的样品,存在两个反转结构。对于x=0.4的样品,则仅发现一个反转结构。在红外光谱中观察到六个反对峰和三个吸收峰,它们的强度大多随Ti含量的增加而增强。与Y1Ba2Cu3O7-δ的光谱结果比校,讨论了声子峰及反转结构的物理起因。
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A. Topacli 《光谱学快报》2013,46(5):729-735
The Ni and new Cd and Co complexes of sulfadimethoxine (SDMX) are prepared and investigated their structural changes and stability by heating at different temperatures. The investigations were earned out by means of the infrared spectroscopy (IR) after heating the samples at several temperatures in the range 50-300 °C for an hour. The IR spectra of the heated samples at different temperatures have been compared with those at room temperature. The changes in the fundamental vibrational bands in their IR spectra gave the temperature values at which the samples decomposited. As a result, it is found that the stability of the complexes are higher than SDMX and their stability is in the order Ni > Co> Cd which depends on the second ionization potential of the metals. 相似文献
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分别以1,10-邻菲咯啉、三苯基氧磷、2,2’-联吡啶为第二配体,以苯甲酰丙酮为第一配体,合成了3种铕(Ⅲ)配合物。通过红外光谱、紫外-可见光吸收光谱和荧光光谱对其性能进行了表征。初步从理论上探讨了不同的第二配体对铕(Ⅲ)配合物光致发光性能的影响,并建立了分子内能量传递模型。结果表明:配体和配合物对紫外光都有强烈吸收,所有配合物在紫外光激发下均能发射Eu3+的特征荧光;第二配体与Eu3+间的能级差以及第一配体与第二配体间的能级差都会影响铕(Ⅲ)配合物的荧光量子效率。 相似文献
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Three types of europium complexes were synthesized by introducing benzoylacetone as the first ligand and 1, 10-phenanthroline, triphenylphosphine oxide, 2,2'-bipyridyl as the second ligand, respectively. The properties of above materials were characterized by infrared absorption spectra, UV-Vis absorption spectra and fluorescence spectra. Then, it was discussed that the different second ligands of europium complexes can affect their luminescence properties, and their intramolecular energy transfer models had been set up. The results indicated that ligands and complexes have a strong absorption of UV light and the three types of europium complexes exhibit characteristic luminescence of europium ion when excited by UV light. In addition, it is suggested that the fluorescence yield of europium complexes mostly depend on both the energy difference between the second ligand and the Eu3+ ion and the energy difference between the second ligand and the first ligand. 相似文献
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The migration of monovacancies (V0) and self-interstitials (I) has been observed in ion-implanted low-doped float-zone silicon by variable-energy positron annihilation spectroscopy. V0 and I were created by the in situ implantation of approximately 20 keV helium ions below 50 K. Monitoring the time evolution of the vacancy response during isothermal heating enabled the measurement of activation energies for I and V(0) [corrected] migration of 0.078(7) and 0.46(28) eV, respectively. In highly As-doped Si, partial V annihilation occurs via free I migration, with a second stage of annealing, probably associated with V-As complexes, above room temperature. 相似文献
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The hydrogen bonded complexes between hydroxylic derivatives and carbonyl bases have been extensively studied by infrared spectroscopy but meager Raman spectroscopic results are available for such complexes. This work reports on a study of the Raman intensity of the vC[dbnd]0 stretching vibration of hydrogen bonded complexes formed between acetophenone and some phenol derivatives. The formation constants of these complexes are calculated from infrared spectroscopy. 相似文献
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E. A. Katlenok E. V. Ivanova M. V. Puzyk K. P. Balashev 《Optics and Spectroscopy》2012,113(3):279-283
The effect of metalation of 2-phenylbenzothiazole and 1-phenylpyrazole with Pd(II), Pt(II), and Rh(III) on the structure and optical properties of luminophore complexes is studied by 1H NMR spectroscopy, IR spectroscopy, and electronic absorption and emission spectroscopy. It is shown that metalation of luminophores leads to the formation of five-membered {M(C??N)} fragments in the composition of square planar and octahedral complexes, which exhibit a long-wavelength charge-transfer band. The luminescence properties of the complexes are characterized by quenching of the fluorescence and by enhancement of the phosphorescence from the mainly intraligand excited state. Fluorescence quenching of complexes is attributed to the thermally activated energy transfer to metal-centered states and their efficient nonradiative decay. 相似文献
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利用紫外-可见、近红外及中红外光声光谱对钕配合物的激发态能级状况、驰豫过程,荧光性质进行探讨,并深入研究了钕离子和配体对彼此光声谱峰移动和峰强度的影响。 相似文献