We measured the infrared reflectivity of BaFe1.904Ni0.096As2 single crystal from room temperature down to 20 K.Two Drude terms and a Lorentz term well describe the real part of the optical conductivity σ1(ω). We fit the reciprocal of static optical conductivity 1/σ1(0) by the power law ρ(T)=ρ0+ATnwith n=1.6. The "broad" Drude component exhibits an incoherent background with a T-independent scattering rate 1/τb, while the other "narrow" one reveals a T-quadratic scattering rate 1/τn, indicating a hidden Fermi-liquid behavior in BaFe1.904Ni0.096As2 compound. 相似文献
The layered oxysulfide (LaO)CuS is a wide-gap semiconductor. In general, the wide-gap semiconductor has strong mono-polarity and non-stoichiometry which affect their physical properties. In this study, the relation between the non-stoichiometry of (LaO)CuS and their physical properties has been investigated. Several kinds of non-stoichiometric samples were prepared. In the Cu non-stoichiometry, (LaO)CuS can accommodate the excess Cu in preference to a deficiency. In the La and S non-stoichiometric samples, deficiencies are preferred. The Cu and S non-stoichiometry affects their electrical and emission properties as expected from the valence band structure. It should be noted that the La non-stoichiometry is also quite effective on the band edge emission and the resistivity as well as other non-stoichiometry. These results reveal that not only Cu but also La deficiency is important in controlling the physical properties. 相似文献
Among the intermediate temperature (500–900 K) thermoelectric materials, both the p- and n-type lead telluride (PbTe) compounds have attracted extensive interests. Till date various approaches were adopted to enhance the thermoelectric performance of n-type PbTe-based materials as they show greater potential space for further improvement compared to p-type ones. Herein, a pseudo-ternary n-type (PbTe)0.95-x(Sb2Se3)x(PbS)0.05 system was designed and a large value of ZT = 1.61 at 850 K in case of x = 0.01 was achieved. Two factors are responsible for the improved thermoelectric performance. The incorporation of lead sulfide is the key factor to maintain a high level of power factor above 700 K and the multi-scale hierarchical architectures yield ultra-low thermal conductivity. 相似文献
The (GeTe)x(AgSbTe2)100-x alloys, also called TAGS-x in short, have long been demonstrated as a promising candidate for thermoelectric applications with successful services as the p-type leg in radioisotope thermoelectric generators for space missions. This largely stems from the complex band structure for a superior electronic performance and strong anharmonicity for a low lattice thermal conductivity. Utilization of the proven strategies including carrier concentration optimization, band and defects engineering, an extraordinary thermoelectric figure of merit, zT, has been achieved in TAGS-based alloys. Here, crystal structure, band structure, microstructure, synthesis techniques and thermoelectric transport properties of TAGS-based alloys, as well as successful strategies for manipulating the thermoelectric performance, are surveyed with opportunities for further advancements. These strategies involved are believed to be in principle applicable for advancing many other thermoelectrics. 相似文献
Spin crossover compounds are considered to be a viable alternative for creating display, memory and switching devices due to the bistability of their magnetic, optical, mechanical and electrical properties. This Letter presents the study of the dielectric and transport properties of the [Fe(Htrz)2(trz)](BF4) (Htrz = 1H‐1,2,4‐triazole) complex in a wide temperature and frequency range. Our results reveal a singular behavior of the dielectric modulus upon the spin transition in conjunction with the switching of the conductivity between the high spin and low spin states.
The binding details and electronic properties of the co-crystal composed of poly(diiododiacetylene) and bis(nitrile) oxalamide are investigated using self-consistent field crystal orbital method. It is found that the cooperative effects exist in the stack of bis(nitrile) oxalamides and the hydrogen bond interaction between bis(nitrile) oxalamides plays an important role in the stability of the co-crystal. The calculated band structures show that the co-crystal is a semiconductor and the poly(diiododiacetylene) can be considered as a quasi one-dimensional chain. The calculated mobility for the one-dimensional poly(diiododiacetylene) chain has the order of 103 cm2 V−1 s−1. 相似文献
The electrical conduction mechanism in polyvinyl chloride (PVC)-polymethyl methacrylate (PMMA) blend film has been studied
at various temperatures in the range 313 K to 353 K. The results are presented in the form of I-V characteristics. Analysis has been made in the light of Poole-Frenkel, Fowler-Nordheim, Schottky, log(J) vs. T plots and Arrhenius plots. It is observed that, Schottky-Richardson mechanism is primarily responsible for the observed conduction.
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