飞秒激光烧蚀硅表面产生等离子体的发射光谱研究

对中心波长为800 nm,脉宽为100 fs的激光脉冲烧蚀空气中硅(111)产生的等离子体发射光谱进行了时间和空间分辨研究. 结果表明,在等离子体羽膨胀初期(小于50 ns时间范围内),等离子体发射光谱主要由连续光谱构成,此后连续光谱强度逐渐减弱,线状光谱开始占主导地位;在羽体膨胀过程中离子谱线的存在时间短于原子谱线的存在时间. 由时间分辨发射光谱发现在羽体膨胀过程中等离子体辐射波长存在红移现象,波长红移量随时间演化呈二次指数衰减. 最后给出等离子体发射光谱谱线强度的时空演化规律. 关键词： 飞秒激光 脉冲激光烧蚀 等离子体 发射光谱     

低压下飞秒激光诱导Cu等离子体的诊断及空间分布实验研究

本文分别利用Gauss、Lorentz和Voigt函数对10Pa背景气压下飞秒激光诱导Cu等离子体光谱进行了拟合分析,结果表明,光谱在150ns内与Lorentz线型符合较好,200ns后与Gauss线型符合较好,Voigt线型与实验谱线一直符合较好。本文还对等离子体的电子密度和温度进行了诊断,并给出了它们随时间的演化;由发射光谱强度的时空演化,推知了等离子体的空间分布;利用时间飞行谱(TOF)得出了等离子体初期沿垂直靶面的膨胀速度。     

超高速碰撞喷出物气化与等离子体形成的物理机制

 为了了解超高速碰撞产生等离子体的物理机制,采用理论方法对超高速碰撞LY12铝靶各物理过程的能量分配进行了分析,涉及到熔化相变、气化相变及等离子体形成过程的能量消耗。揭示了碰撞喷出物形成过程中各物理阶段对气化、等离子体形成的影响因素,包括碰撞的附加热机制、材料碰撞后等离子体羽的形成及等离子体羽膨胀的物理机制,并给出了模型描述。     

激光大气等离子体光谱特性实验研究

报道了对波长为1．06μm的脉冲激光在气体样品中产生的等离子体进行光谱研究的结果。气体样品为一个标准大气压的纯氮、纯氧和空气,光谱探测范围为300～900nm。结果表明,各种气体样品的激光等离子体光谱均表现为连续谱和线状谱的叠加,文中分别给出了连续谱和线状谱的基本特征,讨论了这些特征与等离子体物理特性的关系,并分析了纯氮、纯氧与空气激光等离子体光谱之间的异同。给出了激光等离子体光谱的时间演化和空间分布的基本特征,并初步讨论了与这些特征相关的等离子体物理特性。这些结果有助于加深对激光等离子体特性和机理,特别是对等离子体产生后的弛豫过程和复合机制的了解。     

硅烷低温等离子体阶跃响应的仿真(1)

了解含有负离子的低温等离子体的过渡特性，在等离子体控制过程中，尤其在选择性等离子 体腐蚀工艺和改善电荷堆积等现象中是十分重要的课题.对电源驱动频率为1356MHz，压力 为05Torr(05×10333Pa)状态下的硅烷（SiH₄）低温等离子体的阶跃响应 进行仿真. 当电源电压振幅从550V阶跃减小到350V时，硅烷低温等离子体表现出以数千RF周期为周期的振荡现象，等离子体中的带电粒子的运动变化决定了振荡现象的产生和振荡周期等特性. 关键词： 迁移率 扩散系数 阶跃响应 等离子体振荡     

纯欧姆加热下托卡马克放电启动的0维数值模拟

利用0维数值模型对国际热核实验聚变堆(ITER)的启动放电进行了模拟,给出等离子体密度、等离子体电流、电子温度等参量随时间的演化,并给出电子和离子能量损失的变化。通过分析等离子体参量变化,发现对于特定的环电压,初始放电气压存在上限值,并且分析了启动过程中能量损失机制。在气体完全电离后,电子的平衡损失和输运损失占主导作用。     

强流电子二极管中阴极等离子体的膨胀

研究了强流四脉冲条件下电子真空二极管中阴极等离子体产生、膨胀和由于阴极等离子体膨胀导致二极管短路现象，通过所建立模型和大量实验数据给出了阴极等离子体膨 胀速率为0.5—4cm/μs，且脉冲过程中不均匀.分析了阴极等离子体膨胀对真空二极管电压、阻抗的影响和对多脉冲强流电子束参数的影响，并给出初步解决方案. 关键词： 多脉冲二极管 阴极等离子 膨胀速率     

等离子体电极普克尔盒电光开关单脉冲过程数值模拟

采用流体模型对等离子体电极普克尔盒(PEPC)电光开关单脉冲过程进行了数值模拟分析.模型包括带电粒子连续性方程、动量守恒方程、电子平均能量方程及空间电位泊松方程.分别采用隐式指数差分格式，超松弛迭代法(SOR)和经典四阶龙格-库塔法(R-K)对带电粒子连续性方程，泊松方程和电子平均能量方程进行数值求解.模拟分析了PEPC单脉冲过程中的带电粒子浓度、电子温度、空间电场、PEPC的放电电流、晶体两侧电压和开关效率的时间演化特性.模型得出了PEPC中气体放电等离子体的微观物理过程与PEPC宏观参量的关系，对设计 关键词： 等离子体电极普克尔盒 电光开关 数值模拟 气体放电     

HL-2A等离子体垂直振荡缓解边缘局域模实验观测

在HL-2A 装置实验中，通过对水平场加入方波扰动，实现了等离子体垂直运动。当等离子体向上垂直运动时，观察到了边缘局域模(ELM)缓解现象。研究发现，等离子体向上运动过程中边缘不断形成新的闭合磁面，导致等离子体体积膨胀，进而使台基宽度增加。此外，ELM 缓解期间杂质和工作气体再循环有所增加。等离子体向上运动过程中体积膨胀、工作气体再循环及杂质增加可能是导致ELM 缓解的主要物理因素。该实验可为未来聚变实验装置ELM 的控制提供一些参考。     

球形夸克-胶子等离子体演化源的π干涉学分析

本文对球形演化的夸克–胶子等离子体膨胀源进行了2π干涉学分析.夸克–胶子等离子体的演化由相对论流体力学和熵密度的物态方程描述,而2πHanbury-Brown-Twiss(HBT)关联函数由量子几率振幅的路径积分公式计算.研究结果表明,由2π干涉学得到的源的空间参量敏感地依赖于π介子发射源的相空间分布,源的膨胀速度导致HBT半径变小,并会改变HBT半径与冻结温度之间的关系.     

脉冲激光烧蚀材料等离子体反冲压力物理模型研究与应用

分析了脉冲激光烧蚀材料等离子体等温膨胀阶段的物理特性,建立了脉冲激光烧蚀材料等离子体压力三维方程与动力学模型.应用所建模型,数值分析了单脉冲激光烧蚀青铜金刚石砂轮等离子体相关特性,得到等离子体的反冲压力最大值870 Pa出现在约25 ns后,距离砂轮表面距离约0.05 mm处.相关条件下开展脉冲激光烧蚀青铜金刚石砂轮试验,采用高速相机观测烧蚀砂轮过程中的飞溅现象;采用光栅光谱仪测量等离子体空间发射光谱,计算了等离子体电子温度、电子密度以及反冲压力.实验表明脉冲激光烧蚀青铜金刚石砂轮等离子体反冲压力可以不计,同时也验证了气体方程与动力学模型的正确性和可行性,对脉冲光纤激光烧蚀工艺优化具有启示意义.     

Dynamics of a pulsed laser generated tin plasma expanding in an oxygen atmosphere

Semiconducting tin oxide can be successfully deposited by means of the laser ablation technique. In particular by ablating metallic tin in a controlled oxygen atmosphere, thin films of SnO _x have been deposited. The partial oxygen pressure at which the films are deposited strongly influences both the stoichiometry and the structural properties of the films. In this work, we present a study of the expansion dynamics of the plasma generated by ablating a tin target by means of a pulsed laser using time and space resolved optical emission spectroscopy and fast photography imaging of the expanding plasma. Both Sn I and Sn II optical emission lines have been observed from the time-integrated spectroscopy. Time resolved-measurements revealed the dynamics of the expanding plasma in the ambient oxygen atmosphere. Stoichiometry of the films has been determined by means of X-ray photoelectron spectroscopy and correlated to the expansion dynamics of the plasma.     

Pulsed reactive crossed-beam laser ablation

An adaptation of pulsed laser deposition has been recently developed in which some of the internal energy of an ablation plasma is coupled via collisions into a synchronized pulsed gas expansion that crosses the plasma close to its origin. The physical processes specific to this technique, known as pulsed reactive crossed-beam laser ablation, are described, and its potential advantages are discussed with reference to thin films grown by use of this method.     

FEM simulation of the laser plasma interaction during laser nitriding of titanium

Laser nitriding of materials is based on the interaction of short pulsed laser radiation with the treated material and the hitherto formed laser plasma. The process is very promising for the fast formation of surface coatings with superior properties. Due to the short interaction times and the thin surface films an experimental observation of the underlying processes is very difficult. In order to access the basic mechanism, finite element method simulations of laser heating, evaporation, plasma formation and expansion, plasma composition and interaction with the materials surface have been performed. As a result, evaporation and expansion velocities, pressure balances and dissociation degrees have been derived. The results give a better insight into the physical processes and dependencies of the coating formation, in this case for the titanium-nitrogen system. This finally allows an optimization of the coating synthesis.     

Anisotropic emission in laser-produced aluminum plasma in ambient nitrogen

We report on the dynamical expansion of pulsed laser ablation of aluminum in ambient pressure of nitrogen using images of the expanding plasma. The plasma follows shock model at pressures of 0.1 Torr and drag model at 70 Torr, respectively, with incident laser energy of 265 mJ. The plasma expansion shows unstable boundaries at 70 Torr and is attributed to Rayleigh-Taylor instability. The growth time of Rayleigh-Taylor instability is estimated between 0.09 and 4 μs when the pressure is varied from 1 to 70 Torr. The pressure gradients at the plasma-gas interface gives rise to self-generated magnetic field and is estimated to be 26 kG at 1 Torr ambient pressure using the image of the expanding plasma near the focal spot. The varying degree of polarization of Al III transition 4s ²S_1/2-4p ²P°_3/2 at 569.6 nm gives rise to anisotropic emission and is attributed to the self-generated magnetic field that results in the splitting of the energy levels and subsequent recombination of plasma leading to the population imbalance.     

激光诱导Al等离子体吸收谱分析

用Nd:YAG脉冲激光烧蚀金属Al靶获得等离子体，激光脉冲能量为115mJ.pulse^-1，用氮气作保护气体，压强为1个大气压，获得激光诱导Al等离子体的时间分辨谱。分析了Al等离子体辐射特征。根据连续辐射时间分布，对吸收谱的形成作了简单的解释，认为Al原子对连续辐射的共振中收是形成吸收谱中的“凹谷”的主要机制。     

固体中脉冲激光激发声表面波的理论研究

本文运用本征函数展开的方法对固体材料中脉冲激光激发的声表面波进行了理论研究，在考虑热弹激发的条件下，利用三维的轴对称模型，得到了脉冲激光光源的脉冲宽度以及聚焦半径对固体材料中声表面波信号的时域及频域的影响，对进行超短脉冲激光激发超声的研究具有指导意义。     

Effect of ZnO plasma plume dynamics on laser ablation

The dynamic behaviors and optical properties of a ZnO plasma plume produced by pulsed laser ablation using a Nd:YAG laser (wavelength: 532 nm, pulse width: 3 ns) were studied by fast photography using a commercial gated charge coupled device (CCD) camera linked with a delay circuit and by optical emission spectroscopy at various ambient oxygen pressures. Fast photography was conducted with a resolving power of 0.25 μs and the expansion behaviors of the laser ablation plume were observed. Plasma plume expansion velocity decreased with oxygen partial pressure. The flow of the plasma plume in the early stage of expansion of up to 3 ms agreed well with the drag model.     

Emission spectra investigation of fs induced NPs probed by the ns laser pulse of a fs/ns DP-LIBS orthogonal configuration

A dual-pulse fs/ns laser induced breakdown spectroscopy configuration, where an initial 250 fs ablating pulsed laser followed by a delayed ns laser beam placed at a fixed distance, orthogonally with the expanding plasma plume, has been used in air on a Al₆₅Cu₂₃Fe₁₂ quasicrystal. The obtained emission data were acquired with a set-up arrangement providing space detections, with a resolution up to 15 μm, of the ns laser pulse generated signals. Assuming the fulfillment of local thermodynamic equilibrium conditions, the role played by the time lag between the two laser beams on the induced plasma excitation temperatures and electronic densities, as well as a space resolved process survey, has been followed. The spatial and time resolved spectra show, almost, steady values of the determined elementary plasma features with the development of nanoparticles occurring during the fs laser pulsed ablation process. The ns laser probe of the dual-pulse LIBS configuration here presented confirms that the nanoparticles induced can be largely widespread in both space and time whose compositions, overall, could retain the starting target stoichiometry. It is shown that these nanoparticles formation can actually take place at different times following the initial ultra-short laser beam incidence and that, especially at long inter-pulse delays (>100 μs), modest compositional changes can be observed.     

Pulsed inductive discharge CO2 laser

A pulsed inductive discharge CO₂ laser with a wavelength of 10.6 μm has been created for the first time. The excitation system of a cylindrical pulsed inductive discharge (pulsed inductively coupled plasma) in the gas mixture of CO₂:N₂:He was developed. The temporal and energy parameters of the laser radiation were investigated. The maximum inductive discharge CO₂ laser radiation energy of 104 mJ was achieved. An average power of 3.2 W was obtained at laser generation energy of 65 mJ and pulse repetition rate of 50 Hz. In the cross-section, the laser radiation had the ring shape with an external diameter of 34 mm and thickness of 4-5 mm. The measured divergence of laser radiation was 12 mrad.