二位快交换条件下的水合Fe3+配合物纵向弛豫速率的测定

通过对水与水合Fe³⁺配合物的二位快交换体系的纵向弛豫速率的测定,得出了在本实验条件下磁化效应与权重平均表达方式的相似性,进而得出了水合Fe³⁺配合物纵向弛豫速率.有助于研究水溶液中的离子配合物.     

基于动态有机钆纳米颗粒的T1-T2双模态MRI造影剂

本文设计、合成并测试了一种新型的基于有机钆纳米颗粒的磁共振成像（MRI）造影剂.以1, 2-氨基硫醇与氰基的缩合反应为基础,成功合成了粒径在8~23 nm范围内的有机钆纳米颗粒.该有机钆纳米颗粒作为磁共振造影剂时,随着时间的推移,其纵向弛豫率逐渐减弱,横向弛豫率先增强后逐渐减弱,这与钆纳米颗粒粒径增大有关.有机钆纳米颗粒同时存在随时间变化的纵向弛豫和横向弛豫,表明它有望成为一种先进的T₁-T₂双模态MRI造影剂.     

纵向弛豫对核磁共振线型的影响

根据经典 Bloch方程的解析解以及考虑辐射阻尼效应的Bloch方程的数值解,通过解析分析和数值模拟,从理论上研究了在射频场扰动下以及在辐射阻尼效应的作用下纵向弛豫对核磁共振线型的影响.结果表明:①射频场的扰动和辐射阻尼效应将导致纵向磁化与横向磁化的耦合,从而使纵向弛豫对线型产生了一定的影响.②在射频场的扰动下,峰强和线宽分别为2M0sin(θ)T1T2/(T1+T2)和(T1+T2)/(2πT1T2),即纵向弛豫将使谱线的峰强增大、线宽变窄,且影响程度随着比值T2/T1的减小而增大,峰强最大可增加1倍而线宽最多可减小1/2.③在强辐射阻尼效应的作用下,纵向弛豫会使谱线的峰强降低,降低的幅度与扳转角θ以及比值T2/T1密切相关.当θ从0到3π/4时,降低的幅度均较小,只有当θ＞3π/4时,降低的幅度才开始逐渐变大,且当 θ接近π时,降低的幅度急剧增大.谱线峰强降低的幅度与T2/T1呈较严格的正比关系,即T1越接近T2,峰强下降得越显著.     

强偶合体系弛豫方程组的计算及J偶合对弛豫的影响

根据WBR理论,采用"改进的矩阵计算方法",计算出了强偶合体系较为完整、准确的弛豫方程组,并根据此方程组分析研究了J偶合对横向弛豫、纵向弛豫和交叉弛豫的影响,获得了一些相应的结论。     

多甘醇-磷酸酯-EDTA酯共聚物铁(Ⅲ)配合物的合成和磁共振成象增强作用

通过乙二胺四乙酸双酸酐、二氯磷酸酯与多甘醇共缩聚,制得一系列三元共聚物配体.用配体与三氯化铁反应,得到相应的铁配合物.表征了配体和配合物的化学结构,测试了配合物的纵向弛豫速率,并考察了配合物的急性毒性和磁共振成象增强作用.     

多甘醇-磷酸酯-EDTA酯共聚物铁(Ⅲ)配合物的合成和磁共振成象增强作用

通过乙二胺四乙酸双酸酐、二氯磷酸酯与多甘醇共缩聚，制得一系列三元共聚物配体．用配体与三氯化铁反应，得到相应的铁配合物．表征了配体和配合物的化学结构，测试了配合物的纵向弛豫速率，并考察了配合物的急性毒性和磁共振成象增强作用．     

射频场照射下同核体系的弛豫

根据WBR理论和同核体系的特点,构造出了一个相应的三维转动,利用Wigner旋转矩阵的特性并借助于计算机代数语言,计算出了射频场照射下同核体系完整的弛豫方程组.在此基础上,给出了射频场照射下纵向与横向弛豫时间的计算公式,并从理论上研究了射频场的照射对同核体系弛豫的影响.研究结果表明:1)射频场的照射对同核体系的弛豫有一定程度的影响.2)在射频场的照射下,同核体系的纵向弛豫时间T1小于无射频场时的T1,而横向弛豫时间T2大于无射频场时的T2.3)纵向弛豫时间T1随射频场的增强而逐渐减小,横向弛豫时间T2随射频场的增强而逐渐增大. 关键词： 核磁共振 弛豫 射频场 三维转动     

用流水法测量纵向驰豫时间的讨论

在核磁共振实验中用流水法测量纵向弛豫时间时,我们观察到当水流速慢时共振信号先随着流速增加而增加,当共振信号达到一极大值后又随着流速进一步增加而减少。下面来讨论这个实验现象。     

钆（Ⅲ）天冬酰胺席夫碱配合物的EPR波谱

考察了两类新的Ｇｄ＾３＋氨基酸席夫碱配合物在不同温度下的多晶粉末和有机溶剂中的ＥＰＲ波谱，首次测定了水扬醛缩天冬酰席夫碱钆配合物在ＤＭＳＯ中变温ＥＰＲ特性，发现随温度降低线宽单调减小，纵向弛豫时间下Ｔ１依次增大，用自旋晶格相互和机理作了解释。     

利用场关联效应抑制瑞利型非简并四波混频的热背底

瑞利型非简并四波混频是测量物质超快纵向弛豫时间的有效手段,将场关联原理应用于具有热吸收的样品中瑞利型非简并四波混频的热背底抑制，给出了抑制热背底的条件，并通过数值模拟证明了其可行性. 关键词： 四波混频 场关联 超快测量     

Spin-Wave Excitations in Anisotropic Kondo Lattice Model

The spin-wave excitations in anisotropic Kondo lattice model are studied using the spin Green's function. Both the ferromagnetic and antiferromagnetic cases are considered. The equations to determine the spectrum of low-energy excitations are given. The anisotropy gaps are obtained, and the long-wavelength and strong-coupling limits are analyzed.     

用于高速数据通信的梯度塑料光纤

概述了梯度塑料光纤的开发历史和现状。从应用于高速数据通信的角度 ,介绍了聚甲基丙烯酸甲酯(PMMA)、全氘化和全氟化梯度塑料光纤的损耗、带宽、稳定性和寿命。详细介绍了梯度塑料光纤的损耗光谱和损耗机制 ,介绍了制作梯度塑料光纤的界面凝胶聚合技术和两种扩散法 ,分析了梯度塑料光纤的制作方法同折射率剖面和带宽的关系 ,讨论了梯度塑料光纤的稳定性同掺杂物质的关系。同时介绍了高稳定性梯度塑料光纤的研究进展及今后的发展动向     

亲水性材料固相萃取-紫外导数光谱法检测血中茚满二酮灯抗凝 …

本文报导了血中茚满二酮类抗凝血杀鼠剂敌鼠、氯敌鼠、杀鼠酮的亲水性材料固相萃取－紫外导数光谱检测法。血样用pＨ５缓冲液等体积稀释后加于西雷脱硅藻土柱上,柱用乙酸乙 酯洗脱,将洗脱液挥发干净,剩余物用pＨ１０缓冲液溶解,测定所得溶液的二阶导数光谱进行定性和定量分析。三种杀鼠剂以１０mg／Ｌ的量加于空白血中测得萃取率为８５％以上,血中三种杀鼠剂的检出限低于２ｍｇ／Ｌ。萃取中亲水性硅藻土可用硅胶和氧化铝代替,     

约束对Birkhoff系统Noether对称性和守恒量的影响

研究约束对Birkhoff系统的Noether对称性和守恒量的影响．首先，建立了Birkhoff系统的运动微分方程．其次，给出了系统Noether对称性的判据．然后，讨论了受约束作用后，Birkhoff系统的Noether对称性发生的变化，并给出了系统的Noether对称性以及守恒量保持不变的条件．最后，举例说明结果的应用． 关键词： 分析力学 Birkhoff系统 约束 Noether对称性 守恒量     

Aerial Video Trackers Review

Target tracking technology that is based on aerial videos is widely used in many fields; however, this technology has challenges, such as image jitter, target blur, high data dimensionality, and large changes in the target scale. In this paper, the research status of aerial video tracking and the characteristics, background complexity and tracking diversity of aerial video targets are summarized. Based on the findings, the key technologies that are related to tracking are elaborated according to the target type, number of targets and applicable scene system. The tracking algorithms are classified according to the type of target, and the target tracking algorithms that are based on deep learning are classified according to the network structure. Commonly used aerial photography datasets are described, and the accuracies of commonly used target tracking methods are evaluated in an aerial photography dataset, namely, UAV123, and a long-video dataset, namely, UAV20L. Potential problems are discussed, and possible future research directions and corresponding development trends in this field are analyzed and summarized.     

低压下飞秒激光诱导Cu等离子体的诊断及空间分布实验研究

本文分别利用Gauss、Lorentz和Voigt函数对10Pa背景气压下飞秒激光诱导Cu等离子体光谱进行了拟合分析,结果表明,光谱在150ns内与Lorentz线型符合较好,200ns后与Gauss线型符合较好,Voigt线型与实验谱线一直符合较好。本文还对等离子体的电子密度和温度进行了诊断,并给出了它们随时间的演化;由发射光谱强度的时空演化,推知了等离子体的空间分布;利用时间飞行谱(TOF)得出了等离子体初期沿垂直靶面的膨胀速度。     

Advanced research in millimeter-wave vacuum electronics

Selected basic research efforts currently sponsored by the U.S. Department of Defense (DOD) and the National Science Foundation (NSF) are reviewed. Major achievements are highlighted and remaining obstacles are discussed. Future advances are suggested. Opinions expressed are solely those of the author.     

Some remarks concerning stability for nonstationary quantum systems

The problem of characterizing stability and instability for general nonstationary quantum systems is investigated. Some characterizations are reported and some elementary properties of a topological characterization are established. Then, it is proven, by considering a simple example, that there are nonperiodic driven systems whose orbits are neither precompact nor leave on average any compact set. Autocorrelation measures are computed and the possible roles of the generalizes quasienergy operator and energy growth are briefly discussed.     

Ablation of Transparent Materials Using Excimer Lasers for Photonic Applications

For many years, the development of effective ablation or laser machining techniques for making micro-optical components has been the key factor in the birth of new photonic devices and systems. In this article, the ablation characteristics of two types of the most important transparent materials, transparent polymers and glasses, are studied. Simple shaped microcavities are first machined for studying the fundamental ablation parameters, including threshold fluence, effective absorption coefficient, and ablation rate. In studying polymer ablation, five standard grades and five proprietary polymeric compounds are selected. Ablation techniques using these transparent polymers for making arrayed ferrules and curved microlenses are presented. Applications of these ablated microstructures for optical fiber connectors, optical fiber coupling and alignment, and transparent chip encapsulants, are introduced and demonstrated with emphasis on the quality of the ablated profiles and dimensions to satisfy the required performance. In glass ablation, borosilicate glasses are considered and their associated ablation behaviors are studied. The procedures to ablate glass-based arrayed microstructures with flat and curved surfaces are described. The utilizations of these arrayed microstructures for optical waveguide, wave absorber, and beam guider, are specifically discussed. Finally, concluding remakes for future trends are presented.