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The A?1A2-X?1A1 electronic absorption spectra of CH2S and CD2S have been photographed under high resolution. Selected bands have been rotationally analyzed by least squares line fitting and by band contour methods. Improved rotational constants have been obtained for the ground states of CH2S and CD2S by use of combination differences. Bands of all three polarizations appear in the electronic spectrum. The type A origin band is magnetic dipole allowed, whereas the 401 band is type B. Perturbations are identified in the 000 and 301403 bands of CH2S. The rotational constant A in the upper state decreases rapidly, in accordance with theoretical calculations, as successive quanta of the inversion mode ν4 are excited. The planar inertial defect has a small positive value in the zero level of the upper state although the molecule is slightly nonplanar; the r8 geometry is r(CH) = 1.082 A?, r(CS) = 1.701 A?, angle HCH = 120°, and the out-of-plane angle is approximately 10°.  相似文献   

3.
The electronic absorption spectra of thioformaldehyde and thioformaldehyde-d2 have been obtained. A vibrational analysis of the discrete band system in the 6100-4400-Å region is reported. The type A origin bands are at 16 39416 484cm?1 for CH2SCD2S, and are magnetic dipole allowed. The electronic transition is A?1A2-X?1A1 under the C2v point group. Most of the intensity of the system is in type B bands, and is due to vibronic mixing with higher 1B2 states when the inversion mode ν4 is excited. The molecule in the excited 1A2 state is “floppy-planar,” having a broad potential function with a barrier of the order of 20 cm?1 to the inversion motion.  相似文献   

4.
In this paper, we study the boundary state and its dual state in A1(1) face model with a fixed boundary weight condition, which corresponds to the diagonal solution to boundary Yang-Baxter equation in face model. We also give the correlation functions in this boundary A1(1) face model.  相似文献   

5.
We studied the structural, electrical, and mechanical properties of an InAs thin film grown on GaAs (1 1 1)A substrates by molecular beam epitaxy. In contrast to conventionally used (0 0 1) surfaces, where Stranski–Krastanov growth dominates the highly mismatched heteroepitaxy, layer-by-layer growth of InAs can be established. One of the largest advantages of this unique heteroepitaxial system is that it provides a two-dimensional electron gas system in the near-surface region without the problem of electron depletion. We review the fundamental properties and applications of this unique heteroepitaxial system.  相似文献   

6.
A 1+1-dimensional U(1+1) gauge theory is proposed and the exact solution of its spectrum and corresponding energy eigenstates is found.  相似文献   

7.
We give a birational realization of affine Weyl group of type A (1) m–1 × A (1) n–1. We apply this representation to construct some discrete integrable systems and discrete Painlevé equations. Our construction has a combinatorial counterpart through the ultra-discretization procedure.  相似文献   

8.
P-terphenyl in cyclohexane, has been pumped by a KrF laser in a longitudinal configuration. Dye laser pulses of 11 mJ, 1 MW were obtained with over 10% conversion efficiency. N2 purge of the dye solution is shown to increase the conversion efficiency. The tuning curve between 321.8 nm and 365.3 nm is presented.  相似文献   

9.
本文介绍一个数值孔径0.4、视场10×10mm~2可用于1:1分步投影光刻机的镜头的光学设计及其模型实验结果.光学设计在Wynne-Dyson的1:1折反式系统的基础上,对该系统作了某些改变.实验结果表明,该镜头具有亚微米的光刻分辨率.  相似文献   

10.
The spontaneous breakdown of supersymmetry for a single chiral superfield in 1+1 dimensions is investigated and a number of puzzling features are resolved by noting that the loop expansion is not always valid. It is found that both broken and unbroken supersymmetry are stable with respect to radiative corrections.  相似文献   

11.
Magnetic resonance tagging usually relies on controlling the phase dispersion of the transverse magnetization component. Phase dispersion is, however, affected by the inherent phase of selective excitation pulses, thus limiting their combination with tagging sequences to the application of refocusable pulses, as in the localized spatial modulation of magnetization (L-SPAMM) technique. In this study, we examine the effect of selective excitation pulses on a L-SPAMM 1-1 sequence, showing that in the case of two identical pulses the phase component is canceled out, and thus preemphasis and refocus gradients are not needed, allowing us to take advantage of a constant gradient throughout the tagging sequence, and also that one might choose nonrefocusable maximum and minimum phase pulses.  相似文献   

12.
Beam-foil spectra of aluminum have been recorded between 1100 and 1900 Å using ion energies from 0.3 to 1.5 MeV. Most of the observed lines are due to A1 IV and A1 V. First lifetime measurements have been made for 9 and 8 levels in A1 IV and A1 V, respectively.  相似文献   

13.
We construct a supersymmetric model where the left-handed top and bottom quarks are mainly the gauginos of a vector supermultiplet and hence their superpartners are spin 1. The right-handed top quark is unified with the Higgs field; the top Yukawa coupling arises from the gaugino coupling.  相似文献   

14.
本文叙述了一个为1MV强流脉冲电子束加速器配置的主开关.多级气体开关的设计和实验结果。是国内首次将此种类型的开关应用于兆伏级加速器。  相似文献   

15.
Multispectral tissue classification using magnetic resonance T1, T2, and rho images may be useful in diagnosing and locating certain pathology. Techniques for generating the T1 images necessary for this classification scheme often require longer data collection and post processing times than are practical. As a consequence, further development of this classification scheme may be limited. This paper addresses an improvement in the post processing time required to generate T1 images. A nonlinear least-squares algorithm is described for rapidly generating spin-lattice relaxation time images from variable repetition time magnetic resonance images. The algorithm generates a 256 x 256 pixel T1 image from nine variable repetition time images in approximately 60 sec on a VAX-6510 computer.  相似文献   

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A scheme using neonlike krypton ions is under intensive theoretical and experimental investigation to determine the feasibility of developing a pulsed power-driven laboratory X-ray laser. The scheme depends on discharging hundreds of kilojoules of electrical energy through coaxial cylindrical krypton gas puffs, generating a dense, hot, uniform, homogeneous, and highly ionized krypton plasma. The dynamics of energy absorption are such that self-generated magnetic fields compress and accelerate radially inward the outer plasma with speeds approaching 5×107 cm/s. When the outer plasma impinges and stagnates on the inner plasma, shock waves are sent through the system as the plasma reverberates and bounces outward. Near the interface between the two interacting plasmas and along the axis, conditions appear to be conducive to the establishment of a population inversion with the subsequent emission of coherent soft X-rays with measurable gain. The results of numerical simulations support the notion that it is theoretically possible to achieve a population inversion and gain in three of the lasing lines provided that the appropriate plasma conditions are realized  相似文献   

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We show that the random walk model due to Mark Kac which underlies the telegraph equations may be modified to produce Maxwell's field equations in 1+1 dimensions. This provides the field equations with a representation in terms of classical particles. It also establishes the Kac model as a strong conceptual link between the diffusion, telegraph, and Maxwell equations, and suggests that recent simulations of the Schrödinger and Dirac equations are analogous to Maxwell's equation in terms of interpretation.  相似文献   

20.
The structure and formation of an ultrathin hexagonal boron nitride (h-BN) film on Pt(1 1 1) has been studied by a combination of scanning tunneling microscopy, low energy electron diffraction, low energy electron microscopy, X-ray absorption and high resolution core level spectroscopy. The study shows that a single boron nitride layer is formed on Pt(1 1 1), resulting in a coincidence structure. High resolution scanning tunneling microscopy (STM) images of the h-BN ultrathin film display only one of the atomic species in the unit cell. Probing the boron and nitrogen related local density of states by near edge X-ray absorption fine structure measurements we conclude that the nitrogen sublattice is visible in STM images. The growth of the single hexagonal boron nitride layer by vapourized borazine in the pressure range of 1×10-61×10-8 at 800 °C is further studied by low energy electron microscopy, and reveals that the number of nucleation sites and the perfection of the growth is strongly pressure dependent. A model for the single, hexagonal, boron nitride layer on Pt(1 1 1) is proposed.  相似文献   

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