共查询到19条相似文献,搜索用时 187 毫秒
1.
聚β—羟基丁酸酯/聚醋酸乙烯酯共混体系的相容性与结晶行为 总被引:4,自引:0,他引:4
研究了制样过程聚β-羟基丁酸酯/聚醋酸乙烯酯共混体系的相容性和结晶行为的影响。DSC、SAXS、POM等实验结果表明,PHB/PVAc共混物经溶液成膜后处于分相的状态,PVAc对PHB的结晶能力影响不大;而经融处理后,PHB/PVAc共混物则处于相容的均相状态,随PVAc的含量含量的增加。 相似文献
2.
乳液共聚反应过程与聚合物结构关系及~(13)C-NMR对聚合物结构的表征 总被引:1,自引:0,他引:1
用间歇法和半连续法进行了丙烯酸丁酯(BuA)与醋酸乙烯酯(VAc)乳液共聚合.13C-NMR对共聚产物分子结构测试表明,在间歇法共聚合中随着反应进行其组成及结构发生很大变化,而半连续法确能制得成份及结构均匀一致的P(BuA-VAc)共聚物.由于BuA水溶性小于VAc,而其竟聚率远大于VAc,间歇法共聚合反应初期只有少量VAc参加共聚合.通过对间歇法共聚合中不同反应时间聚合物的13C-NMR测试,表明反应初期聚合的VAc以单链节或二元序列形式存在于主要由BuA单元构成的分子链中,而并未形成较长VAc链段.对上述试样玻璃化转变温度的测试结果与13C-NMR实验结果颇为一致. 相似文献
3.
乳液共聚反应过程与聚合物结构关系及13C-NMR对聚合物结构的表征 总被引:2,自引:1,他引:2
用间歇法和半连续法进行了丙烯酸丁酯(BuA)与醋酸乙烯酯(VAc)乳液共聚合.13C-NMR对共聚产物分子结构测试表明,在间歇法共聚合中随着反应进行其组成及结构发生很大变化,而半连续法确能制得成份及结构均匀一致的P(BuA-VAc)共聚物.由于BuA水溶性小于VAc,而其竟聚率远大于VAc,间歇法共聚合反应初期只有少量VAc参加共聚合.通过对间歇法共聚合中不同反应时间聚合物的13C-NMR测试,表明反应初期聚合的VAc以单链节或二元序列形式存在于主要由BuA单元构成的分子链中,而并未形成较长VAc链段.对上述试样玻璃化转变温度的测试结果与13C-NMR实验结果颇为一致. 相似文献
4.
聚氯乙烯/线性低密度聚乙烯共混体系的相容性 总被引:5,自引:0,他引:5
用动态力学分析(DMA)和傅利叶变换红外光谱(FTIR)研究了氢化聚丁二烯-b-聚甲基丙烯酸甲酯(HPBD-b-PMMA)共聚物增容剂对聚氯乙烯(PVC)与线性低密度聚乙烯(LLDPE)共混体系的增容作用.增容剂使共混物中两相的玻璃化温度发生变化,说明其相容性增加.FTIR的结果表明,增容剂中羰基与PVC的α氢形成氢键,使CO,H─C及C─Cl的振动频率变化,峰形加宽. 相似文献
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丙烯酸甲酯与醋酸乙烯酯的种子乳液聚合 总被引:15,自引:0,他引:15
以过硫酸铵(APS) 为引发剂,合成了粒径分布较均匀的聚醋酸乙烯酯种子乳液(PVAc) ,然后以丙烯酸甲酯( MA) 为第二单体和以油溶性偶氮二异丁腈(AIBA) 为引发剂,分别进行不溶胀与溶胀条件下的无皂种子乳液聚合,并用透射电子显微镜(TEM) 表征了胶粒形态.表明在不溶胀条件下,胶粒形态随PVAc/ MA 重量比的不同而变化,当PVAc/ MA 为1/2 时,形成以PMA 为核,PVAc 为壳的胶粒.在溶胀条件下则得到类似互穿网络型乳胶粒. 相似文献
7.
聚环氧丙烷聚氨酯/聚(甲基丙烯酸甲酯—苯惭烯)IPN的研究 总被引:2,自引:1,他引:1
改变聚(甲基丙烯酸甲酯-苯乙烯(P(MMA-co-St)中 甲基丙烯酸甲酯的含量(WMMA),通过一步法合成出聚环氧氯丙烷聚氨酯(PU(PECH)/P(MMA-co-St)IPN.DSC、TEM和动态粘弹谱研究结果表明:当P(MMA_co-St)中WMMA大于0.6时,IBN仅有一个Tg;当WMMA小于0.4时,IPN有2个Tg,TEM上出现相区,P(MMA-co-St)深度参数(δ)及δ的氢键作 相似文献
8.
1,4—双(氯甲基)—2—甲氧基—5—壬氧基苯的均聚和共聚研究 总被引:1,自引:0,他引:1
以1,4-双(氯甲基)-2,5一二甲基苯(BCMDMB)和1,4-双氯甲基-2-甲氧基-5-壬氧基苯(BCMMONOB)为单体,采用脱氯化氢法,合成了聚(2,5-二甲基)对亚苯基亚乙烯(PDMPV)和聚(2-甲氧基-5-壬氧基)对亚苯基亚乙烯(PMONOPV);并对BCMDMB和BCMMONOB的共聚进行了研究。结果表明,适宜的反应条件为:碱与单体的摩尔比为20∶1,在室温下聚合时间为30h,碱的pH=14时产率最高。用IR、1H-NMR、UV—Vis对聚合物进行了表征。 相似文献
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聚醋酸乙烯酯与铜(Ⅱ)离子的配位反应及其催化作用 总被引:1,自引:1,他引:1
以ESR、UV和IR表征Cu(2+)离子与PVAC的配位反应。根据CUCl2·2H2O乙醇溶液与PVAc-CuCl2·2H2O乙醇溶液的电导率差值随Cu(2+)离子摩尔浓度变化的明显转析点得知,1个Cu(2+)离子大约能与PVAc4个链节单元配位。证实MMA在Cu(Ⅱ)-PVAc配合物/Na2SO3体系的聚合体是无规PMMA,得率为70%。讨论了MMA在Cu(Ⅱ)-PVAc配合物/Na2SO3体系络合催化引发下的游离基反应历程。 相似文献
11.
Living radical polymerization (LRP) of methyl acrylate (MA), acrylic acid (AA), and vinyl acetate (VAc) mediated by cobalt(II) porphyrin complexes ((TMP)CoII·, (TMPS)CoII·) are reported. The polymeric products with relatively low polydispersity and controlled number average molecular weight (Mn) based on one polymer chain per cobalt complex demonstrate the living characters of the polymerization process. The formation of block copolymers of poly(methyl acrylate)‐b‐poly(vinyl acetate) (PMA‐b‐PVAc) and poly(methyl acrylate)‐b‐poly(vinyl pyrrolidone) (PMA‐b‐PVP) demonstrate another important feature of LRP and extend the application of cobalt porphyrin mediated radical polymerization to a wider array of functionalized monomers. Kinetic studies using 1H NMR to follow the formation of orGano‐cobalt complexes reveal that two mechanisms, reversible termination (RT) and degenerative transfer (DT), occur during the polymerization process. MA and VAc polymerization mediated by cobalt porphyrin complexes are used to illustrate the properties of these two LRP pathways and evaluate the kinetic and thermodynamic properties for several of the central reactions. 相似文献
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The emulsion polymerization of acrylic and vinyl acetate monomers using poly(vinyl alcohol) (PVA) as protective colloid has been studied for a long time, whereas rare reports ranged over the lateral comparison of the two systems and the reason for the unstability of the PVA/MMA polymerization system was still indistinct. Here in this paper, a collection of experiments of methyl methacrylate (MMA) and vinyl acetate (VAc) were performed respectively with varied amount of PVA as the sole stabilizer. The grafting extent of the polymerisate was characterized through the fraction and FTIR and it was found that the grafted amount of PVA was even larger in the PVA/MMA copolymers than PVA/VAc copolymers, so the grafted mode of PVA was considered. Based on the kinetics, the slower initiation rate of sulfate radical towards MMA was found to be responsible for the unstability of corresponding colloids accompanied with the relatively quicker hydrogen abstraction of radical to PVA, which resulted in “layer-by-layer” grafting structure inside and the particle surface-grafting density was lowered thereof. This was proved with TEM and static contact angle measurements and a pseudo-homopolymer model was employed to describe the relationship of colloidal stability and the PVA density on surfaces. 相似文献
14.
Generally, owing to tautomerism of vinyl alcohol monomer, poly(vinyl alcohol) (PVA) cannot be obtained by direct polymerization but it can be obtained by the saponification of poly(vinyl ester) precursors such as poly(vinyl acetate) (PVAc). In this study, to obtain high-molecular-weight (HMW) PVA with high yield through a one-batch method, we tried continuous saponification of PVAc prepared by suspension polymerization of vinyl acetate (VAc). We controlled various polymerization conditions, such as polymerization temperature, initiator concentration, suspending agent concentration, agitation speed, and VAc/water ratio, and obtained PVAc with a maximum conversion of VAc into PVAc of over 95-98%. PVA beads having various molecular parameters were prepared by continuous saponification of PVAc microspheres. Despite our employing a one-batch process, a maximum degree of saponification of 99.9% could be obtained. Continuous heterogeneous saponification of prepared PVAc yielded HMW PVA having a number-average degree of polymerization of 2,500-5,500, a syndiotactic diad content of 51-52%, and degree of saponification of 85.0-99.9%. 相似文献
15.
Fen Chen 《European Polymer Journal》2008,44(6):1789-1795
A novel ω-azido-functionalized RAFT reagent, O-(2-azido-ethyl) S-benzyl dithiocarbonate (AEBDC), was synthesized and subsequently employed to mediate the reversible addition-fragmentation chain transfer (RAFT) polymerization of vinyl acetate (VAc) to prepare end-functionalized polymers. The polymerization results showed that the RAFT polymerizations of VAc could be well controlled using AEBDC as the RAFT agent. Number-average molecular weights (Mn GPC) increased linearly with monomer conversion, and molecular weight distributions were relatively narrow. 1H NMR spectrum of the poly(vinyl acetate) (PVAc) confirmed the existence of functional azido group at the end of the polymers chains. The ω-azido-terminated polymers were coupled by “click” chemistry with a fluorescent alkyne, 7-propinyloxy coumarin, to prepare fluorescent PVAc. The fluorescence properties of the PVAc homopolymers before and after coupling with 7-propinyloxy coumarin in CH2Cl2 solution were investigated. 相似文献
16.
Q. Ching Wang Frantiek vec Jean M. J. Frchet 《Journal of polymer science. Part A, Polymer chemistry》1994,32(13):2577-2588
The porous structure of monodisperse macroporous beads can be controlled by using soluble polymers with well-defined structural characteristics as part of the porogenic mixture. In general, the use of linear polystyrene as a porogen in the preparation of poly (styrene-co-divinylbenzene) beads shifts the pore size distribution towards larger pores. While a direct correlation between pore size and molecular weight of the porogen has been established, the chemical composition of the polymer porogen has no effect on the porous and chromatographic properties of the beads. These findings suggest that the average molar volume of the porogenic system is important while the miscibility of the polymer porogen with the crosslinked polymer that is formed is of little relevance. © 1994 John Wiley & Sons, Inc. 相似文献
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18.
W. S. Lyoo S. G. Lee J. P. Kim S. S. Han C. J. Lee 《Colloid and polymer science》1998,276(11):951-959
To obtain high molecular weight (HMW) poly(vinyl acetate) (PVAc) with high conversion and high linearity for a precursor
of HMW poly(vinyl alcohol) (PVA), vinyl acetate (VAc) was suspension-poly-merized using a low-temperature initiator, 2,2′-azobis
(2,4-dimethyl-valeronitrile) (ADMVN), and the effects of polymerization conditions on the polymerization behavior and molecular
structures of PVAc and PVA prepared by saponifying PVAc were investigated. On the whole, the experimental results well corres-ponded
to the theoretically predicted tendencies. Suspension polymerization was slightly inferior to bulk polymerization in increasing
molecular weight of PVA. In contrast, the former was absolutely superior to the latter in increasing conversion of the polymer,
which indicated that the suspension polymerization rate of VAc was faster than the bulk one. These effects could be explained
by a kinetic order of ADMVN concentration calculated by initial-rate method and an activation energy difference of polymerization
obtained from the Arrhenius plot. Suspension polymerization at 30 °C by adopting ADMVN proved to be successful in obtaining
PVA of HMW (number-average degree of polymerization (P
n)): (4200–5800) and of high yield (ultimate conversion of VAc into PVAc: 85–95%) with diminishing heat generated during polymerization.
In the case of bulk polymerization of VAc at the same conditions, maximum P
n and conversion of 5200–6200 and 20–30% was obtained, respectively. The P
n, lightness, and syndiotacticity were higher with PVA prepared from PVAc polymerized at lower temperatures.
Received: 10 February 1998 Accepted: 15 April 1998 相似文献