Ag复合对La2/3(Ca0.45Sr0.55)1/3MnO3/xAg体系电输运和室温磁电阻效应影响

文中采用甘氨酸-硝酸盐法分别制备了La2/3(Ca0.45Sr0.55)1/3MnO3/xAg纳米复合材料(x=0;0.1;0.2;0.3).通过X射线衍射、扫描电子显微镜和磁电阻效应测试,对合成产物的结构及性能进行表征.结果表明,随Ag复合量增加,样品均为正交钙钛矿结构,低场室温磁电阻效应增强,电阻率减小.     

Ca2Li2BiV3O12∶Eu3+荧光粉的制备和发光性能

采用高温固相法成功合成了一种可用于白光LED的Ca₂Li₂BiV₃O₁₂∶Eu³⁺新型红色荧光粉,使用X射线衍射仪和荧光分光光度计对合成样品进行了表征,研究了合成温度和Eu³⁺含量对合成样品相组成和发光性能的影响。结果表明,采用高温固相法在650~700 ℃能合成纯度较高、结晶度好的Ca₂Li₂BiV₃O₁₂∶Eu³⁺荧光粉,合成样品激发带覆盖200~400 nm,发射光谱的线状发射峰可归属于Eu³⁺的⁵D₀→⁷F_J(J= 1, 2, 3,4)特征锐线发射,Eu³⁺摩尔分数为14%时荧光粉的发光强度最大。     

Ni2(OCH3)2/SiO2催化剂上CO2和CH3OH的吸附和反应性能

采用表面改性和离子交换相结合的方法制备了Ni2 (OCH3 ) 2 /SiO2 负载型双核金属甲氧基配合物催化剂 ,利用红外光谱 (IR)、程序升温脱附 (TPD)、程序升温表面反应 (TPSR)和微反技术考察了催化剂的表面结构以及CO2 和CH3 OH的化学吸附和反应性能 .结果表明 :Ni2 (OCH3 ) 2 /SiO2 中Ni2 + 与载体SiO2 表面O2 -以双齿配位形式键合 ,甲氧基以桥基形式联结双金属离子形成双核物种Ni2 (OCH3 ) 2 ;CO2 在催化剂表面存在甲氧碳酸酯基物种和桥式两种吸附态 ,CH3 OH则只有一种分子吸附态 ;在 10 0～ 2 0 0℃条件下 ,CO2 和CH3 OH在催化剂上的反应产物主要是DMC和H2 O ;根据反应结果 ,讨论了催化反应机理 .     

红色长余辉材料Zn3(PO4)2：Mn2+,Ga3+的合成及光谱性质

采用高温固相法合成α、β和γ-Zn₃(PO₃)₂:Mn²⁺,Ga³⁺(ZPMG),XRD分析表明,高温合成过程中淬火条件有利于β相的形成,退火条件有利于γ相的形成。三种磷光粉的激发光谱分别位于246nm(α)、234nm(β和γ)的宽带谱。α相的发射光谱为位于508nm的锐线谱,β和γ相的发射光谱均存在两个谱带,分别位于508nm的绿色光谱区和616nm的红色光谱区。两种发射均归属为Mn²⁺的⁴T₁(⁴G)→⁶A_1g(⁶S)跃迁,但是由于Mn²⁺在Zn₃(PO₃)₂结构中的配位数不同,故发光颜色及强度均不同。对于余辉发射,只能观察到红色余辉光谱。     

铁电单晶0.62Pb(Mg1/3Nb2/3)O3-0.38PbTiO3折射率的研究

用最小偏向角法在20℃下精确测量了0.62Pb(Mg1/3Nb2/3)O3-0.38PbTiO3(0.62PMN-0.38PT)单晶的折射率,给出了该温度下折射率色散的Sellmeier方程.研究了能带结构与折射率的关系,计算了样品的Sellmeier光学系数:对no,E0=5.50eV,λ0=0.226μm,S0=1.004×1014m-2,Ed=28.10eV;对ne,E0=5.57eV,λ0=0.223μm,S0=1.017×1014m-2,Ed=28.10eV.ABO3型钙钛矿材料中,BO6八面体基元决定了晶体的能带结构,对折射率产生重要影响.     

近紫外激发具有颜色可调的Er3+/Eu3+共掺BiOCl荧光粉

本文采用固相法在500℃合成了Er³⁺/Eu³⁺共掺BiOCl 荧光粉, 并通过XRD, SEM, 吸收, 激发和发射光谱研究了其结构、形貌和发光特性. XRD 和SEM结果表明在500℃下即可成功合成纯四方相片层结构的Er³⁺/Eu³⁺共掺BiOCl荧光粉. 吸收光谱表明掺杂Er³⁺/Eu³⁺离子使BiOCl形成杂质能级; 激发光谱显示该荧光粉具有来自于基质BiOCl价带(VB)到导带(CB)跃迁的优异宽带近紫外激发特性. 在380 nm近紫外光激发下, 同时获得了Er³⁺离子和Eu³⁺离子的特征发射峰, 其中发光中心位于410 nm (²H_9/2→⁴I_15/2), 525 nm (²H_11/2→⁴I_15/2), 554 nm (⁴S_3/2→⁴I_15/2), 673 nm (⁴F_9/2→⁴I_15/2)的发射峰来自于Er³⁺离子的跃迁, 而581 nm(⁵D₀→⁷F₀), 594 nm (⁵D₀→⁷F₁), 622 nm (⁵D₀→⁷F₂), 653 nm (⁵D₀→⁷F₃), 699 nm (⁵D₀→⁷F₄)的发射峰则来自于Eu³⁺离子的跃迁. 值得注意的是, 与传统Er³⁺/Eu³⁺掺杂的材料不同, 该荧光粉还具有独特高效的紫光(Er³⁺)和长波红光(Eu³⁺)发射特性, 分析表明这与BiOCl的结构有关; 并且通过改变掺杂浓度, 实现了发光颜色由黄绿光→黄光→橙红光的调节. 研究结果表明Er³⁺/Eu³⁺共掺BiOCl荧光粉有望成为一种潜在的近紫外激发白光LED荧光粉.     

LED用红色发光材料 Li3Ba2Ln3-xEux(MoO4)8的制备及性能

采用溶胶-凝胶法合成了发光二极管(LED)用的系列红色荧光粉Li₃Ba₂Ln_3-xEu_x(MoO₄)₈ (Ln=La, Gd, Y)。利用差热-热重(TG-DTA)分析和粉末X 射线衍射(XRD)测定了其最佳合成温度和不同温度下所得样品的结构,发现所有样品均具有单斜结构;采用荧光光谱对所得荧光粉发光性能进行了表征,发现在相同条件下所得样品的发光强度顺序为:Li₃Ba₂Y_2.8Eu_0.2(MoO₄)₈＞Li₃Ba₂Gd_2.8Eu_0.2(MoO₄)₈＞Li₃Ba₂La_2.8Eu_0.2-(MoO₄)₈。它们在395 nm和465 nm的激发光源激发时均有强的吸收,与LED芯片发射波长相匹配。同时分析了柠檬酸及分散剂聚乙二醇(PEG-10000)的用量、Eu³⁺离子的浓度以及焙烧温度等因素对荧光粉发光性能的影响。     

铁电单晶0.62Pb(Mg1/3Nb2/3)O3-0.38PbTiO3折射率的研究

用最小偏向角法在20℃下精确测量了0.62Pb(Mg_1/3Nb_2/3)O_{3< /sub>-0.38PbTiO3( 0.62PMN-0.38PT)单晶的折射率，给出了该温度下折射率色散的Sellmeier方程.研究了能带 结构与折射率的关系，计算了样品的Sellmeier光学系数：对no，E0=5.50eV,λ0=0.2 26μm，Ｓ０=1.004×10¹⁴m^-2，Ed=28.1 0eV；对ne，Ｅ0=5.57eV,λ 0=0.223μm，S0=1.017×10¹⁴m^-2，Ed=28.10eV.A BO3型钙钛矿材料中，BO6八面体基元决定了晶体的能带结构，对折 射率产生重要影响. 关键词： PMNT单晶 折射率 Sellmeier光学系数}     

化学共沉淀法制备的(Y1-x-y,Gdy)2O3∶xEu3+红色荧光粉及其发光性能

用化学共沉淀法一次煅烧工艺合成了 (Y_1-x-y,Gd_y)₂O₃∶xEu³⁺(x=0.06~0.10,y=0,0.20~0.25)系列红色荧光粉。用XRD、SEM和荧光分光光度计,对试样的晶体结构、表面形貌及发光性能进行表征。研究了Eu³⁺、Gd³⁺的掺杂浓度、表面活性剂的加入、煅烧温度对样品性能的影响。结果表明:样品为立方晶系;Gd³⁺的加入会使基体晶格发生畸变,晶胞参数增加,起到改善样品色纯度和发光效率的作用;最佳煅烧温度为900 ℃,比传统的高温固相法低500 ℃左右;所合成荧光粉的粒度主要分布在300~400 nm,结构比较松散;当x=0.08,y=0.23时,最大发射峰(λ_em=613 nm)强度最大。所合成的(Y_1-x-y,Gd_y)₂O₃∶xEu³⁺荧光粉是一种性能较好的PDP用红色荧光粉。     

Y_2O_3·Cr_2O_3复合氧化物热力学性质的研究

在1182—1386K温度范围内,用固体电解质氧浓差电池: Mo|Cr,Y_2O_3,Y_2O_3·Cr_2O_3|ZrO_2(+MgO)|Cr,Cr_2O_3|Mo测定了复合氧化物Y_2O_3·Cr_2O_3的热力学性质。对于反应 Y_2O_(3_(s))+Cr_2O_(3(s))=Y_2O_3·Cr_2O_(3(s)),得到 △G_(Y_2O_3·Cr_2O_3)~0=39160-34.97T(实验误差±350cal/mol)或 △G_(Y_2O_3·Cr_2O_3)~0=163900-146.3T(实验误差±1450cal/mol).因为△G_(Y_2O_3·Cr_2O_3)~0与温度T的关系为直线关系,所以若将△G~0=a+bT与△G~0=△H~0-T△S~0两式比较,a和-b的物理意义可认为分别相当于在公式适用温度范围内△H~0与△S~0的平均值。因此 △H_(Y_2O_3·Cr_2O_3)~0=39160cal/mol或193900J/mol, △S_(Y_2O_3·Cr_2O_3)~0=34.97cal/(mol·K)或146.3J/(mol·K)。 如将化合物写作YCrO_3的形式,各热力学数据为上述各值的一半。     

La0.67Ca0.33MnO3复合体系的磁电阻增强效应

在La0.67Ca0.33MnO3(LCMO)纳米颗粒体系中,采用Cu与之复合,考察复合对磁电阻性能的影响.结果表明,复合使低场磁电阻得到大幅度的增强.但和其它LCMO复合体系截然不同的是,复合体系的电阻率大幅下降.认为是在LCMO颗粒周围形成一层良导体,电子输运与颗粒边界的电子散射有关.     

晶界效应对钙钛矿La_(0.7)Ba_(0.3)MnO_3多晶材料的磁输运特性的影响(英文)

本文通过比较La0.7Ba0.3MnO3多晶和外延薄膜样品磁输运行为之间的差异,讨论了晶界对多晶样品输运特性的影响,并计算了晶界电阻率随温度和磁场的变化关系.与晶粒的本征电阻率相比,晶界的电阻率要大一个量级,并且其金属-绝缘转变温度低约50K.此外,在晶界中观察到了新奇的正磁阻效应.我们认为,晶界在其转变温度附近出现了相分离现象,并形成铁磁金属渗流通道.由于晶界的特殊构型,Ba掺杂锰氧化物材料中大的磁致伸缩效应对其输运行为影响很大,导致了晶界中正磁阻现象的出现.     

La4/3Ca5/3Mn2O7的结构、电输运及磁性质研究

采用溶胶-凝胶法,在不同温度烧结制备了名义组分为La4/3Ca5/3Mn2O7的多晶样品.X射线结构分析以及电、磁输运性质的测量表明:La4/3Ca5/3Mn2O7形成的是La2/3Ca1/3MnO3和CaO的混合物.     

The structure and magnetotransport properties of La2/3Sr1/3MnO3/Ba(La)TiO3 composites

The effect of Ba(La)TiO₃ doping on the structure and magnetotransport properties of La_2/3Sr_1/3MnO₃(LSMO)/xBa(La)TiO₃ (x=0.0, 1.0, 5.0 mol%) have been investigated. The X-ray diffraction patterns and microstructural analysis show that BaTiO₃ and LSMO phases exist independently in BaTiO₃-doped composites. The metal-insulator transition temperature (T_MI) decreases whereas the maximum resistivity increases very quickly by the increase of BaTiO₃ doping level. The partial substitution of Ba by La(0.35 mol%) results in a decrease in resistivity of LSMO/xBa(La)TiO₃ composites. Magnetoresistance of BaTiO₃-doped composites decreases monotonously in the temperature range 200-400 K in a magnetic field of 5 T, which is completely different from that of LSMO compound. The value of MR decreases at low field (H<1 T) and increases at high fields (H>1 T) with increasing the BaTiO₃ doping level at low temperatures below 280 K. These investigations reveal that the magnetotransport properties of LSMO/xBa(La)TiO₃ composites are dominated by spin-dependent scattering and tunneling effect at the LSMO/BaTiO₃/LSMO magnetic tunnel junction.     

La0.7Ca0.3MnO3/MgAl2O4复合样品的电输运特性

我们用传统的固相反应法制备了(La0.7Ca0.3MnO3)1-x(MgAl2O4)x复合样品.通过XRD分析发现在此系列复合样品中La0.7Ca0.3MnO3和MgAl2O4两相共存;电阻率温度关系分析表明MgAl2O4的引入没有改变母体相在温度TP1处本征的金属-绝缘体转变峰,但使复合样品在较低温度TP2处出现另外一个电阻率峰值.有趣的是,随着MgAl2O4掺量的增加,在低掺量时,TP2向低温偏移很快;但在高掺量时,TP2向低温偏移较慢.     

Thermal Hysteresis in La2/3 Ca1/3 MnO3 Films Grown on Tilted SrTiO3 Substrates and Influence of External Magnetic Field

Thermal hysteresis in the resistivity of La2/3 Cu1/3MnO3 thin films grown on tilted SrTiO3 substrates is simulated by using the random network model on the basis of mixed-phase percolation between metallic and insulating domains, The metallic-insulating transition temperatures during the warming process are lower than those during the cooling process due to the difference in fraction of metallic domains between warming and cooling process. With an external magnetic field, the metallic-insulating transition temperatures shift to a higher value and the resistivities are reduced. The excellent agreement between the simulation and the experimental data further verifies that phase separation plays a crucial role in the transport process of La2/3Ca1/3MnO3 thin films.     

Fe3O4 Segregation and Transport Properties of La0.67Ca0.33MnO3

Effect of Fe3O4 segregation at grain boundaries on the electrical transport and magnetic properties of La0.67Ca0.33MnO3 is investigated. The experimental results show that the Fe3O4 segregation not only shifts the paramagnetic-ferromagnetic transition temperature of La0.6TCa0.33MnO3 to a lower temperature region but also induces a new transition in a lower temperature region. Meanwhile, the transition processes observed in both the resistivity and magnetization curves are obviously widened. Compared to pure La0.67Ca0.33MnO3, we assume that the Fe3O4 segregation level at the grain boundaries can modify the electrical transport and magnetic properties of La0.67Ca0.33MnO3.     

Nanoscale multiphase separation at La(2/3)Ca(1/3)MnO3/SrTiO3 interfaces

55Mn nuclear magnetic resonance experiments are reported on a series of fully strained epitaxial La(2/3)Ca(1/3)MnO3 thin films on SrTiO3. We have found evidence of multiple phase segregation into ferromagnetic metallic and nonmetallic regions as well as regions that are nonferromagnetic and insulating. These insulating regions are mainly located close to interfaces and may have a significant impact on the performance of spin-tunnel devices. As a result of phase segregation, the ferromagnetic coupling within the metallic regions is depressed. This accounts for the reduction of the Curie temperature and conductivity in nanometric thin films.     

Noise probe of the dynamic phase separation in La(2/3)Ca(1/3)MnO3

Giant random telegraph noise (RTN) in the resistance fluctuation of a macroscopic film of perovskite-type manganese oxide La(2/3)Ca(1/3)MnO3 has been observed at various temperatures ranging from 4 to 170 K, well below the Curie temperature ( T(C) approximately 210 K). The amplitudes of the two-level fluctuations vary from 0.01% to 0.2%. We discuss the origin of the RTN to be a dynamic mixed-phase percolative conduction process, where manganese clusters switch back and forth between two phases that differ in their conductivity and magnetization.