A wideband sensitive holographic photopolymer

A novel wideband sensitive dry holographic photopolymer sensitized by rose bengal (RB) and methylene blue (MB) is fabricated, the holographic storage characteristics of which are investigated under different exposure wavelengths. The result shows that the sensitive spectral band exceeds 200 nm in visible light range, the maximum diffraction efficiency under different exposure wavelengths is more than 40% and decreases with the decrease of exposure wavelength, the exposure sensitivity is not change with the exposure wavelength.This photopolymer is appropriate for wavelength multiplexing or multi-wavelength recording in digital holographic storage.     

一种核黄素敏化的宽带全息记录材料

制备了一种核黄素敏化的以聚乙烯醇为基质的新型全息存储材料,并研究了材料的全息特性.用Ar+激光器激发的488 nm的蓝光对材料曝光,结果表明该材料具有较高的衍射效率和曝光灵敏度,衍射效率高达53%,灵敏度为3.3 cm2/J,折射率调制度为4.5×10－4.研究了材料的透过率与随时间和入射角度变化的关系,说明在曝光记录过程中有噪音光栅生成.在存储介质膜中存储了全息图像,再现图像较为清晰,说明该材料适合用作高密度全息存储介质.     

双染料敏化光致聚合物的光化动力学研究

研究了光致聚合物的光化学反应理论模型及其动力学参量。合成了染料藻红B和亚甲基蓝作为联合光敏剂共同敏化的全息光存储光致聚合物材料。对材料测试分别得到在曝光波长为633 nm与曝光强度为65 mW/cm2时,透射率随曝光条件的变化关系以及材料各光化学参量。结果表明,随着曝光波长与曝光强度的增加,光致聚合物的光化漂白速率常数k与量子产率Φ增大,当曝光强度为65 mW/cm2时透射率在短波长下出现了下降,光化漂白速率常数k出现负值,而摩尔吸收系数ε在条件不同时则表现了不同的变化趋势。     

新型双染料敏化的宽带光聚物全息特性研究

报道了一种新型、两种染料共同敏化的宽带响应光聚物材料.该材料使用孟加拉玫瑰红和亚甲基蓝作为联合光敏剂,由于混合染料的加入,使材料的感光光谱范围大大加宽.用四种波长的光对样品进行曝光,衍射效率均大于40%,最高可达80%,适合于多波长存储,分别用不同波长的激光在样品同一位置存储了四幅不同的图像,其再现图像效果良好,表明该材料是一种较理想的多波长全息存储材料.     

一种全可见光敏感的光致聚合物全息特性研究

制备了一种对整个可见光波段都敏感的光全息存储材料,并研究了该材料的透过率、衍射效率、灵敏度等全息特性.用He-Ne激光器633 nm和Ar+ 激光器514 nm,488 nm,476 nm四种波长的光曝光,材料的饱和衍射效率最大为66%,最小为48%;最高灵敏度为8.06×10－3 cm2/mJ.最高折射率调制度为4.22×10－4.用多波长存储时,不同波长的光可存储多幅全息图,且再现图像清晰.结果表明,该材料是较好的高密度数字全息存储材料.     

Recording media that exhibit high dynamic range for digital holographic data storage

A general strategy for fabricating thick, optically flat photopolymer recording media with high dynamic range (M/#) that exhibit low levels of recording-induced Bragg detuning for holographic data storage is presented. In particular, media with M/# values as high as 42 in 1-mm-thick formats are obtained. We believe that these results are the first demonstration of a holographic storage medium with a dynamic range of this magnitude. In addition, we report the holographic recording and recovery of high-capacity (480-kbit) digital data pages in these media, further illustrating their data-storage capabilities.     

Fabrication and characterization of poly(methyl methacrylate) photopolymer doped with 9,10-phenanthrenequinone (PQ) based derivatives for volume holographic data storage

We present our studies on the photopolymer of poly(methyl methacrylate) (PMMA) doped with 9,10-phenanthrenequinone based derivatives for volume holographic storage. By introducing different functional groups on the side-chain of 9,10-phenanthrenequinone molecule, the holographic characteristics of the material can be modified. The photoreaction involved with the holographic recording in the samples was investigated by measuring UV-Vis absorption spectrum and mass spectrum. The experimental results show that the similar behaviors were exhibited in these photopolymers. It is found that phase hologram recording in our PQ derivatives doped PMMA photopolymer involves a structure change of the quinone based molecule, which induces a strong change of the refractive index. Experimental characterizations on holographic data storage, including material sensitivity, dynamic range (M#) and bit-error-rate have been performed. We found that, by selecting appropriate functional groups, an improvement in sensitivity and M# for holographic data storage can be achieved.     

Holographic storage of three-dimensional image and data using photopolymer and polymer dispersed liquid crystal films

We present holographic storage of three-dimensional(3D) images and data in a photopolymer film without any applied electric field.Its absorption and diffraction efficiency are measured,and reflective analog hologram of real object and image of digital information are recorded in the films.The photopolymer is compared with polymer dispersed liquid crystals as holographic materials.Besides holographic diffraction efficiency of the former is little lower than that of the latter,this work demonstrates that the photopolymer is more suitable for analog hologram and big data permanent storage because of its high definition and no need of high voltage electric field.Therefore,our study proposes a potential holographic storage material to apply in large size static 3D holographic displays,including analog hologram displays,digital hologram prints,and holographic disks.     

吖啶橙敏化的光致聚合物及其数字全息存储研究

制备了一种吖啶橙敏化的光致聚合物材料,并研究了材料的全息特性.用Ar+激光器三种波长的光对材料进行记录.结果表明,该材料具有较高的衍射效率、较高的曝光灵敏度和较大的折射率调制度,最大衍射效率均大于40%.将计算机二进制文件经过编码生成的二值图像存入样品,其再现图像较为清晰,译码后能够准确地还原出原文,表明该光致聚合物适合数字全息存储.     

High-density holographic recording parameters under different wavelength of a two dyes-sensitized photopolymer

The high-density holographic recording parameters of a novel two dyes-sensitized photopolymer under different exposure wavelengths are studied. The results show that the maximum diffraction efficiency, exposure sensitivity, maximum refraction index modulation, dynamic range, and the exposure time constant increases with the increase of the exposure wavelength. The analysis indicates that the scattering has an important role in the forming of the holographic grating.     

Distortions in pixel-matched holographic data storage due to lateral dimensional change of photopolymer storage media

Dimensional changes in polymerizable storage materials during exposure are a source of pixel misregistration in digital holographic storage. Lateral shrinkage or expansion of photopolymer recording materials can be deduced from quantitative measurement of the shift and the magnification errors of reconstructed holograms.     

含双引发剂的光致聚合物全息特性研究

制备了一种三乙醇胺与N-苯基苷氨酸为共同引发剂的丙烯酰胺基光致聚合物全息存储材料,并用He-Ne 激光器633 nm波长的光对样品进行曝光测试.实验表明,与单引发剂的光致聚合物相比,薄膜的质量有一定的提高,在曝光灵敏度变化不大的情况下,衍射效率有很大提高.优化两种引发剂浓度后,此种共同引发的光致聚合物材料呈现的衍射效率达到54%,曝光灵敏度为1.85×10－2cm2/mJ.还研究了此种光致聚合物的透过率随曝光时间和曝光强度的变化,说明此种光致聚合物材料内部均匀性好,对光的散射小.     

厚度对光聚物高密度全息存储记录参量的影响

本文用实验方法研究了光致聚合物的曝光时间常量、曝光能量常量、动态范围、曝光灵敏度和折射率调制度等高密度全息存储参量随样品厚度的变化规律,结果表明随着样品厚度的增加,曝光能量常量、曝光时间常量及材料的动态范围也增加,但材料的曝光灵敏度却减小,而折射率调制度却没有明显的变化规律.     

红敏聚乙烯醇/丙烯酰胺体系光致聚合物全息记录材料的空间分辨力增强研究

针对目前聚乙烯醇/丙烯酰胺体系光致聚合物材料的空间分辨力不高的问题,提出了一种采用低相对分子质量的聚乙烯醇作为成膜剂来改进光致聚合物分辨力的新方法.采用不同相对分子质量(72000,15000,9000)的聚乙烯醇成膜剂制成光致聚合物,对其衍射效率和空间分辨力等指标进行了对比实验.实验表明选用低相对分子质量(9000)的成膜剂可将该体系光致聚合物的分辨力提高到3000 line/mm以上,实验中仅需40 mJ/cm2左右的曝光量即可获得85%的衍射效率.另外,还对该材料的全息存储特性及其在角度复用全息存储方面的初步应用结果进行了报道.     

番红花红T光敏感光致聚合物全息存储材料

制备了一种以番红花红T为光敏剂的新型全息存储材料,主要用Ar⁺激光器的514.5nm波长的绿光研究材料的全息特性.研究表明,该材料具有较高的衍射效率、曝光灵敏度和较大的折射率调制度,衍射效率近40%,灵敏度为7.22×10^-4cm²/mJ,折射率调制度为3.65×10^-4,同时,在读出时必须考虑布拉格偏移对全息存储的影响.在介质膜中存储了全息图像,再现图像较为清晰,说明该材料适合用作高密度全息存储介质. 关键词： 全息存储 光致聚合物 衍射效率 布拉格偏移     

碱性品红敏化的光致聚合物在441nm短波长的全息存储特性研究

制备了一种以碱性品红为光敏剂的新型全息存储材料,且使用波长为441nm的He—Cd激光器成功研究了材料的全息特性。研究表明,该材料在短波长处仍具有较高的衍射效率、曝光灵敏度和较大的折射率调制度,衍射效率近60％,灵敏度为2．93×101c群／mJ,折射率调制度为8．85×10．。。在存储介质膜中存储了全息图像,再现图像较为清晰,对比度与保真度较为理想,说明该材料具有较好的全息存储性能,适合作为高密度全息存储介质。     

紫光至红光敏感的多波长复用全息存储材料

制备了一种对紫光至红光波段敏感的光致聚合物全息存储材料,用476 nm、488 nm、496 nm、514.5 nm及632.8 nm五种波长曝光对其进行光全息性能的研究.研究表明,该材料在各种波长下的最大衍射效率均不低于45%,曝光灵敏度大于4.22×10－3 cm2·mJ－1,折射率调制度高于1.62×10－4,光栅频率接近3 000 lp/mm等.     

番红花红T敏化的新型光致聚合物全息存储材料

制备了一种以番红花红T为光敏剂的新型全息存储材料,实验结果表明,该材料具有较高的衍射效率、曝光灵敏度和较大的折射率调制度等,最大衍射效率约38.5%,折射率调制度为0.547×10－3,在存储介质膜中存储了模拟全息图像,再现图像有较好的保真度,说明该材料适合用作高密度体全息存储介质。     

Holographic storage of multiple high-capacity digital data pages in thick photopolymer systems

Multiple digital data pages (480 kbits per page) were holographically recorded and retrieved with low bit-error rates in thick (~250- and ~500-mum) photopolymer media. The photopolymer systems were fabricated with the optical quality and low level of scatter required for digital data storage. We believe that these results represent the first demonstration of holographic storage of high-capacity digital data pages in photopolymer media with the thickness that will be required for such storage densities.     

干法在线处理全息存储材料

综述了干法在线处理全息存储材料在高密度数字全息存储中的应用。详细介绍了光折变材料、光致聚合物和光寻址聚合物的基本组成、全息存储性能及其优缺点等。最后,对干法在线处理全息存储材料的发展现状和前景进行了简要介绍。