Methods of Small and Large δ in the Nonlinear Dynamics – A Comparative Analysis

New asymptotic approaches for dynamical systems containing a power nonlinear term x ⁿ are proposed and analyzed. Two natural limiting cases are studied: n 1 + , 1 and n . In the firstcase, the 'small method' (SM)is used and its applicability for dynamical problems with the nonlinearterm sin as well as the usefulness of the SMfor the problem with small denominators are outlined. For n , a new asymptotic approach is proposed(conditionally we call it the 'large method' –LM). Error estimations lead to the followingconclusion: the LM may be used, even for smalln, whereas the SM has a narrow application area. Both of the discussed approaches overlap all values ofthe parameter n.     

Existence theorem for a minimum problem with free discontinuity set

We study the variational problem Where is an open set in ⁿ ,n2gL ^q () L (), 1q<+, O<, <+ andH _n–1 is the (n–1)-dimensional Hausdorff Measure.     

Theoretical derivation of tangential velocity profiles in a flat vortex chamber-influence of turbulence and wall friction

Summary As part of a study on the hydrodynamics of a cyclone separator, a theoretical investigation of the flow pattern in a flat box cyclone (vortex chamber) has been carried out. Expressions have been derived for the tangential velocity profile as influenced by internal friction (eddy viscosity) and wall friction. The most important parameter controlling the tangential velocity profile is = –u ₀ R/(v+ ), where u ₀ is the radial velocity at the outer radius R of the cyclone, the kinematic liquid viscosity and is the kinematic eddy viscosity. For values of greater than about 10 the tangential velocity profile is nearly hyperbolic, for smaller than 1 the tangential velocity even decreases towards the centre. It is shown how and also the wall friction coefficient may be obtained from experimental velocity profiles with the aid of suitable graphs. Because of the close relation between eddy viscosity and eddy diffusion, measurements of velocity profiles in flat box cyclones will also provide information on the eddy motion of particles in a cyclone, a motion reducing its separation efficiency.List of symbols A cross-sectional area of cyclone inlet - h height of cyclone - p static pressure in cyclone - p static pressure difference in cyclone between two points on different radius - r radius in cyclone - r ₁ radius of cyclone outlet - R radius of cyclone circumference - u radial velocity in cyclone - u ₀ radial velocity at circumference of flat box cyclone - v tangential velocity - v ₀ tangential velocity at circumference of flat box cyclone - w axial velocity - z axial co-ordinate in cyclone - friction coefficient in flat box cyclone (for definition see § 5) - ₁ value of friction coefficient for ₁<< ₂ - ₂ value of friction coefficient for ₂<<1 - = - ₁ value of for ₁<< ₂ - ₂ value of for ₂<<1 - thickness of laminar boundary layer - =/h - turbulent kinematic viscosity - ratio of z to h - k ratio of height of cyclone to radius R of cyclone - parameter describing velocity profile in cyclone =–u ₀ R/(+) - kinematic viscosity of fluid - density of fluid - ratio of r to R - ₁ value of at outlet of cyclone - ₂ value of at inner radius of cyclone inlet - _w shear stress at cyclone wall - angular momentum in cyclone/angular momentum in cyclone inlet - ₁ value of at = ₁ - ₂ value of at = ₂     

The Thermodynamic Significance of the Local Volume Averaged Temperature

Since the temperature is not an additive function, the traditional thermodynamic point of view suggests that the volume integral of the temperature has no precise physical meaning. This observation conflicts with the customary analysis of non-isothermal catalytic reactors, heat pipes, driers, geothermal processes, etc., in which the volume averaged temperature plays a crucial role. In this paper we identify the thermodynamic significance of the volume averaged temperature in terms of a simple two-phase heat transfer process. Given the internal energy as a function of the point temperature and the density

Flow in porous media I: A theoretical derivation of Darcy's law

Stokes flow through a rigid porous medium is analyzed in terms of the method of volume averaging. The traditional averaging procedure leads to an equation of motion and a continuity equation expressed in terms of the volume-averaged pressure and velocity. The equation of motion contains integrals involving spatial deviations of the pressure and velocity, the Brinkman correction, and other lower-order terms. The analysis clearly indicates why the Brinkman correction should not be used to accommodate ano slip condition at an interface between a porous medium and a bounding solid surface.The presence of spatial deviations of the pressure and velocity in the volume-averaged equations of motion gives rise to aclosure problem, and representations for the spatial deviations are derived that lead to Darcy's law. The theoretical development is not restricted to either homogeneous or spatially periodic porous media; however, the problem ofabrupt changes in the structure of a porous medium is not considered.Roman Letters A interfacial area of the - interface contained within the macroscopic system, m² - A _e area of entrances and exits for the -phase contained within the macroscopic system, m² - A interfacial area of the - interface contained within the averaging volume, m² - A ^* interfacial area of the - interface contained within a unit cell, m² - Ae area of entrances and exits for the -phase contained within a unit cell, m² - B second order tensor used to represent the velocity deviation (see Equation (3.30)) - b vector used to represent the pressure deviation (see Equation (3.31)), m^–1 - d distance between two points at which the pressure is measured, m - g gravity vector, m/s² - K Darcy's law permeability tensor, m² - L characteristic length scale for volume averaged quantities, m - characteristic length scale for the -phase (see Figure 2), m - characteristic length scale for the -phase (see Figure 2), m - n unit normal vector pointing from the -phase toward the -phase (n =–n ) - n _e unit normal vector for the entrances and exits of the -phase contained within a unit cell - p pressure in the -phase, N/m² - p intrinsic phase average pressure for the -phase, N/m² - p –p , spatial deviation of the pressure in the -phase, N/m² - r ₀ radius of the averaging volume and radius of a capillary tube, m - v velocity vector for the -phase, m/s - v phase average velocity vector for the -phase, m/s - v intrinsic phase average velocity vector for the -phase, m/s - v –v , spatial deviation of the velocity vector for the -phase, m/s - V averaging volume, m³ - V volume of the -phase contained within the averaging volume, m³ Greek Letters V/V, volume fraction of the -phase - mass density of the -phase, kg/m³ - viscosity of the -phase, Nt/m² - arbitrary function used in the representation of the velocity deviation (see Equations (3.11) and (B1)), m/s - arbitrary function used in the representation of the pressure deviation (see Equations (3.12) and (B2)), s^–1     

On laminar flow through a uniformly porous pipe

Numerous investigations ([1] and [4–9]) have been made of laminar flow in a uniformly porous circular pipe with constant suction or injection applied at the wall. The object of this paper is to give a complete analysis of the numerical and theoretical solutions of this problem. It is shown that two solutions exist for all values of injection as well as the dual solutions for suction which had been noted by previous investigators. Analytical solutions are derived for large suction and injection; for large suction a viscous layer occurs at the wall while for large injection one solution has a viscous layer at the centre of the channel and the other has no viscous layer anywhere. Approximate analytic solutions are also given for small values of suction and injection.

Nomenclature

General r distance measured radially - z distance measured along axis of pipe - u velocity component in direction of z increasing - v velocity component in direction of r increasing - p pressure - density - coefficient of kinematic viscosity - a radius of pipe - V velocity of suction at the wall - r ²/a ² - R wall or suction Reynolds number, Va/ - f() similarity function defined in (6) - u ₀() eigensolution - U(0) a velocity at z=0 - K an arbitrary constant - B _K Bernoulli numbers Particular Section 5 perturbation parameter, –2/R - ² a constant, –K - x / - g(x) f()/ Section 6 perturbation parameter, –R/2 - ² a constant, –K - g() f() - g _c ()=g() near centre of pipe - * point where g()=0 Section 7 2/R - ² K - t (1–)/ - w(t, ) [1–f(t)]/ - ₀, ₁ constants - g() f()– ₀ - ₀/ - ₀ a constant - * point where f()=0     

Asymptotic analysis of equilibrium states for rotating turbulent flows

The equilibrium states of homogeneous turbulence simultaneously subjected to a mean velocity gradient and a rotation are examined by using asymptotic analysis. The present work is concerned with the asymptotic behavior of quantities such as the turbulent kinetic energy and its dissipation rate associated with the fixed point (/kS)=0, whereS is the shear rate. The classical form of the model transport equation for (Hanjalic and Launder, 1972) is used. The present analysis shows that, asymptotically, the turbulent kinetic energy (a) undergoes a power-law decay with time for (P/)<1, (b) is independent of time for (P/)=1, (c) undergoes a power-law growth with time for 1<(P/)<(C ₂–1), and (d) is represented by an exponential law versus time for (P/)=(C ₂–1)/(C ₁–1) and (/kS)>0 whereP is the production rate. For the commonly used second-order models the equilibrium solutions forP/,II, andIII (whereII andIII are respectively the second and third invariants of the anisotropy tensor) depend on the rotation number when (P/kS)=(/kS)=0. The variation of (P/kS) andII versusR given by the second-order model of Yakhot and Orzag are compared with results of Rapid Distortion Theory corrected for decay (Townsend, 1970).     

On surface waves in generalized thermoelasticity

Knowles' representation theorem for harmonically time-dependent free surface waves on a homogeneous, isotropic elastic half-space is extended to include harmonically time-dependent free processes for thermoelastic surface waves in generalized thermoelasticity of Lord and Shulman and of Green and Lindsay.r , , r , , .This work was done when author was unemployed.     

Saint-Venant's principle in linear two-dimensional elasticity for non-striplike domains

Let be a simply connected domain in the x ₁-x ₂ plane which lies within the strip 0<x ₂, is a simple closed piecewise smooth curve. Let l= [(x ₁, x ₂): (x ₁, x ₂) and x ₁>0], _l = [(x ₁ x ₂): (x ₁ ,x ₂) and x ₁>1>0].Suppose that a two-dimensional homogeneous isotropic elastic body occupies , that a self-equilibrated stress loading is applied to - l, and that l is stress-free. Knowles [2] and Flavin [6] showed that the elastic energy in _l decays exponentially with respect to l with an exponential decay constant of the form k/b, where k is a universal constant. It is shown here that a decay constant of the form c/ may be obtained where c is a universal constant and is a characteristic dimension of , which is more appropriate than b for general non-striplike domains. In addition, an appropriate decay theorem is obtained for coil-like domains.     

A third order scheme in the vlasov theory and some consequences in the evolution of few body systems

Summary A set of implemented evolution equations, describing the coherent nonlinear interaction of plasma waves, based on the perturbation method, has been derived, taking into account initial value effects and third order nonlinearities in the modal amplitudes.The equations reduce, in the appropriate limit, to well known stochastic triplets of hydrodynamic type.It is argued that, the stochastization mechanism of the decay instability in strongly damped regime, may be interpreted as a Duffing-type behavior.

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Sommario Si presenta un sistema di equazioni di evoluzione descrivente l'interazione coerente nonlineare di onde di plasma, tenendo conto di effetti di condizioni iniziali e nonlinearità del terzo ordine nelle ampiezze modali. Le equazioni si riducono, nel limite appropriato, a ben noti tripletti stocastici di tipo idrodinamico.Si ipotizza che il processo di stocastizzazione della instabilità di decadimento, in regime di forte dissipazione, possa essere interpretato da un modello dinamico del tipo Duffing.

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Lyst of greek symbols omega (lower case)=frequency - delta (1.c.)=partial derivative - pi (1.c.)=greek pi (=3,14r. units) in (26) - Sigma (Capital case)=Summation symbol - Delta (C.c)=def. as in (14) - epsilon (1.c.) def. as in (10) - sigma (1.c.)=def. as in (36) - gamma (1.c.)=def. as in (37) - beta (1.c.)=def. as in (37) - ro, (1.c.)=def. as in (37) - alfa (1.c.)=def. in connection with _k in (60) - Gamma (C.c.)=def. as in (63) and (66), (67) - delta (1.c.)=def. as in (66) - psi (1.c.)=def. as in (75) - fi (1.c.)=def. in (71) in connection with ₀ - Fi (C.c.)=def. as in (75) - Omega (C.c.)=def. in (78)     

Mean and turbulent velocity measurements of supersonic mixing layers

The behavior of supersonic mixing layers under three conditions has been examined by schlieren photography and laser Doppler velocimetry. In the schlieren photographs, some large-scale, repetitive patterns were observed within the mixing layer; however, these structures do not appear to dominate the mixing layer character under the present flow conditions. It was found that higher levels of secondary freestream turbulence did not increase the peak turbulence intensity observed within the mixing layer, but slightly increased the growth rate. Higher levels of freestream turbulence also reduced the axial distance required for development of the mean velocity. At higher convective Mach numbers, the mixing layer growth rate was found to be smaller than that of an incompressible mixing layer at the same velocity and freestream density ratio. The increase in convective Mach number also caused a decrease in the turbulence intensity ( _u/U).List of symbols a speed of sound - b total mixing layer thickness between U ₁ – 0.1 U and U ₂ + 0.1 U - f normalized third moment of u-velocity, f u³/(U)³ - g normalized triple product of u² , g u²/(U)³ - h normalized triple product of u ², h u ²/(U)³ - l _u axial distance for similarity in the mean velocity - l _u axial distance for similarity in the turbulence intensity - M Mach number - M _c convective Mach number (for ₁ = ₂), M _c (U ₁ – U ₂)/(a ₁ + a ₂) - P static pressure - r freestream velocity ratio, r U ₂/U ₁ - Re unit Reynolds number, Re U/ - s freestream density ratio, s ₂/₁ - T _t total temperature - u instantaneous streamwise velocity - u deviation of u-velocity, uu – U - U local mean streamwise velocity - U ₁ primary freestream velocity - U ₂ secondary freestream velocity - average of freestream velocities, (U ₁ + U ₂)/2 - U freestream velocity difference, U U ₁ – U ₂ - instantaneous transverse velocity - v deviation of -velocity, – V - V local mean transverse velocity - x streamwise coordinate - y transverse coordinate - y ₀ transverse location of the mixing layer centerline - ensemble average - ratio of specific heats - boundary layer thickness (y-location at 99.5% of free-stream velocity) - similarity coordinate, (y – y ₀)/b - compressible boundary layer momentum thickness - viscosity - density - standard deviation - dimensionless velocity, (U – U ₂)/U - 1 primary stream - 2 secondary stream A version of this paper was presented at the 11th Symposium on Turbulence, October 17–19, 1988, University of Missouri-Rolla     

Representation of the rheological properties of polymer melts in terms of complex fluidity

In dynamic rheological experiments melt behavior is usually expressed in terms of complex viscosity ^* () or complex modulusG ^* (). In contrast, we attempted to use the complex fluidity ^* () = 1/µ ^* () to represent this behavior. The main interest is to simplify the complex-plane diagram and to simplify the determination of fundamental parameters such as the Newtonian viscosity or the parameter of relaxation-time distribution when a Cole-Cole type distribution can be applied. ^* () complex shear viscosity - () real part of the complex viscosity - () imaginary part of the complex viscosity - G ^* () complex shear modulus - G() storage modulus in shear - G() loss modulus in shear - J ^* () complex shear compliance - J() storage compliance in shear - J() loss compliance in shear - shear strain - rate of strain - angular frequency (rad/s) - shear stress - loss angle - ^* () complex shear fluidity - () real part of the complex fluidity - () imaginary part of the complex fluidity - ₀ zero-viscosity - ₀ average relaxation time - h parameter of relaxation-time distribution     

Free convection heat transfer from an isothermal plate with arbitrary inclination

This paper presents a new formulation for the laminar free convection from an arbitrarily inclined isothermal plate to fluids of any Prandtl number between 0.001 and infinity. A novel inclination parameter is proposed such that all cases of the horizontal, inclined and vertical plates can be described by a single set of transformed equations. Moreover, the self-similar equations for the limiting cases of the horizontal and vertical plates are recovered from the transformed equations by setting=0 and=1, respectively. Heated upward-facing plates with positive and negative inclination angles are investigated. A very accurate correlation equation of the local Nusselt number is developed for arbitrary inclination angle and for 0.001 Pr .

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Wärmeübertragung bei freier Konvektion an einer isothermen Platte mit beliebiger Neigung

Zusammenfasssung Diese Untersuchung stellt eine neue Formulierung der laminaren freien Konvektion von Flüssigkeiten mit einer Prandtl-Zahl zwischen 0,001 und unendlich an einer beliebig schräggestellten isothermen Platte dar. Ein neuer Neigungsparameter wird eingeführt, so daß alle Fälle der horizontalen, geneigten oder vertikalen Platte von einem einzigen Satz transformierter Gleichungen beschrieben werden können. Die unabhängigen Gleichungen für die beiden Fälle der horizontalen and vertikalen Platte wurden für=0 und=1 aus den transformierten Gleichungen wieder abgeleitet. Es wurden erwärmte aufwärtsgerichtete Platten mit positiven und negativen Neigungswinkeln untersucht. Eine sehr genaue Gleichung wurde für die lokale Nusselt-Zahl bei beliebigen Neigungswinkeln und für 0,001 Pr entwickelt.

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Nomenclature C _p specific heat - f reduced stream function - g gravitational acceleration - Gr local Grashof number,g(T _w –T _w ) x³/v² - h local heat transfer coefficient - k thermal conductivity - n constant exponent - Nu local Nusselt number,hx/k - p pressure - Pr Prandtl number, v/ - Ra local Rayleigh number,g(T _w –T )J x³/v - T fluid temperature - T _w wall temperature - T temperature of ambient fluid - u velocity component in x-direction - v velocity component in y-direction - x coordinate parallel to the plate - y coordinate normal to the plate Greek symbols thermal diffusivity - thermal expansion coefficient - (Ra¦sin¦)^1/4/( Ra cos()^1/5 - pseudo-similarity variable, (y/) - dimensionless temperature, (T–T )/(T _w–T ) - ( Ra cos)^1/5+(Rasin)^1/4 - v kinematic viscosity - 1/[1 +(Ra cos)^1/5/( Ra¦sin)^1/4] - density of fluid - Pr/(1+Pr) - _w wall shear stress - angle of plate inclination measured from the horizontal - stream function - dimensionless dynamic pressure     

Topological entropy of a dynamical system on the space of one-dimensional maps

We study properties of the topological entropy of the map F: f , C(I), generated by a fixed continuous map f C(I) of an interval of the straight line. In particular, we show that the topological entropy h(F) > 0 if and only if h(f) > 0.Translated from Neliniini Kolyvannya, Vol. 7, No. 2, pp. 180–187, April–June, 2004.     

Transport in ordered and disordered porous media I: The cellular average and the use of weighting functions

In this work we consider transport in ordered and disordered porous media using singlephase flow in rigid porous mediaas an example. We defineorder anddisorder in terms of geometrical integrals that arise naturally in the method of volume averaging, and we show that dependent variables for ordered media must generally be defined in terms of thecellular average. The cellular average can be constructed by means of a weighting function, thus transport processes in both ordered and disordered media can be treated with a single theory based on weighted averages. Part I provides some basic ideas associated with ordered and disordered media, weighted averages, and the theory of distributions. In Part II a generalized averaging procedure is presented and in Part III the closure problem is developed and the theory is compared with experiment. Parts IV and V provide some geometrical results for computer generated porous media.Roman Letters A interfacial area of the- interface contained within the macroscopic region, m² - A_e area of entrances and exits for the-phase contained within the macroscopic system, m² - g gravity vector, m/s² - I unit tensor - K traditional Darcy's law permeability tensor, m² - L general characteristic length for volume averaged quantities, m - characteristic length (pore scale) for the-phase - (y) weighting function - m(–y) (y), convolution product weighting function - _v special weighting function associated with the traditional averaging volume - N unit normal vector pointing from the-phase toward the-phase - p pressure in the-phase, N/m² - p0 reference pressure in the-phase, N/m² - p traditional intrinsic volume averaged pressure, N/m² - r0 radius of a spherical averaging volume, m - r position vector, m - r position vector locating points in the-phase, m - averaging volume, m³ - V volume of the-phase contained in the averaging volume, m³ - V _cell volume of a unit cell, m³ - v velocity vector in the-phase, m/s - v traditional superficial volume averaged velocity, m/s - x position vector locating the centroid of the averaging volume or the convolution product weighting function, m - y position vector relative to the centroid, m - y position vector locating points in the-phase relative to the centroid, m Greek Letters indicator function for the-phase - Dirac distribution associated with the- interface - V/V, volume average porosity - mass density of the-phase, kg/m³ - viscosity of the-phase, Ns/m²     

A three-parameter model describing the experimental relation between shear stress and shear rate for laminar flow of aqueous polymer solutions

Summary A three-parameter model is introduced to describe the shear rate — shear stress relation for dilute aqueous solutions of polyacrylamide (Separan AP-30) or polyethylenoxide (Polyox WSR-301) in the concentration range 50 wppm – 10,000 wppm. Solutions of both polymers show for a similar rheological behaviour. This behaviour can be described by an equation having three parameters i.e. zero-shear viscosity ₀, infinite-shear viscosity , and yield stress ₀, each depending on the polymer concentration. A good agreement is found between the values calculated with this three-parameter model and the experimental results obtained with a cone-and-plate rheogoniometer and those determined with a capillary-tube rheometer.

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Zusammenfassung Der Zusammenhang zwischen Schubspannung und Schergeschwindigkeit von strukturviskosen Flüssigkeiten wird durch ein Modell mit drei Parametern beschrieben. Mit verdünnten wäßrigen Polyacrylamid-(Separan AP-30) sowie Polyäthylenoxidlösungen (Polyox WSR-301) wird das Modell experimentell geprüft. Beide Polymerlösungen zeigen im untersuchten Schergeschwindigkeitsbereich von ein ähnliches rheologisches Verhalten. Dieses Verhalten kann mit drei konzentrationsabhängigen Größen, nämlich einer Null-Viskosität ₀, einer Grenz-Viskosität und einer Fließgrenze ₀ beschrieben werden. Die Ergebnisse von Experimenten mit einem Kegel-Platte-Rheogoniometer sowie einem Kapillarviskosimeter sind in guter Übereinstimmung mit den Werten, die mit dem Drei-Parameter-Modell berechnet worden sind.

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a Pa^–1 physical quantity defined by:a = {1 – ( / ₀)}/ ₀ - c l concentration (wppm) - D m capillary diameter - L m length of capillary tube - P Pa pressure drop - R m radius of capillary tube - u m s^–1 average velocity - v _r m s^–1 local axial velocity at a distancer from the axis of the tube - shear rate (–dv _r /dr) - local shear rate in capillary flow - s^–1 wall shear rate in capillary flow - Pa s dynamic viscosity - _a Pa s apparent viscosity defined by eq. [2] - ( _a ) Pa s apparent viscosity in capillary tube at a distanceR from the axis - ₀ Pa s zero-shear viscosity defined by eq. [4] - Pa s infinite-shear viscosity defined by eq. [5] - l ratior/R - kg m^– density - Pa shear stress - ₀ Pa yield stress - _r Pa local shear stress in capillary flow - _R Pa wall shear stress in capillary flow _R = (PR/2L) - _v m³ s^–1 volume rate of flow With 8 figures and 1 table     

The value of the critical exponent for reaction-diffusion equations in cones

Let D R ^N be a cone with vertex at the origin i.e., D = (0, )x where S ^N–1 and x D if and only if x = (r, ) with r=¦x¦, . We consider the initial boundary value problem: u _t = u+u ^p in D×(0, T), u=0 on Dx(0, T) with u(x, 0)=u ₀(x) 0. Let ₁ denote the smallest Dirichlet eigenvalue for the Laplace-Beltrami operator on and let ₊ denote the positive root of (+N–2) = ₁. Let p ^* = 1 + 2/(N + ₊). If 1 < p < p ^*, no positive global solution exists. If p>p ^*, positive global solutions do exist. Extensions are given to the same problem for u _t=+¦x¦ u ^p .This research was supported in part by the Air Force Office of Scientific Research under Grant # AFOSR 88-0031 and in part by NSF Grant DMS-8 822 788. The United States Government is authorized to reproduce and distribute reprints for governmental purposes not withstanding any copyright notation therein.     

Dynamic melt viscoelastic behavior of random copolymers

Summary The viscoelastic properties of 65/35 styrenen-butyl methacrylate random copolymers were determined using the Eccentric Rotating Disks device of the Rheometrics Mechanical Spectrometer. Similar to the behavior observed in homopolymers, an increase in the molecular weight of the copolymer resulted in extension of the rubbery plateau and in a reduction in the terminal region. The dynamic complex viscosity showed onset of non-Newtonian flow at higher frequencies, with the non-Newtonian region increasing with increasing molecular weight.The elastic modulus,G, was dependent upon the frequency,, asG ^1.5 in the terminal region, rather than asG ² observed for polystyrene. The viscous modulus,G, was proportional to the frequency,, asG , similar to what is observed for polystyrene. The dynamic viscosity | ^*| at high frequencies showed a region independent of molecular weight where a power law of | ^*| ^0.9 is applicable, consistent with entanglement models. Thy dynamic viscosity at low frequencies in the Newtonian region is related to molecular weight as |^*| . Using WLF equations, the coefficient of expansion, _f , was obtained that, together with glass transition, showed a negative deviation from the Fox-Flory relationship.

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Zusammenfassung Die viskoelastischen Eigenschaften von statistischen 65/35-Styrol/n-Butyl-Methacrylat-Kopolymeren wurden mit Hilfe einer Maxwell-Rheometer-Anordnung in Verbindung mit dem Mechanischen Spektrometer der Fa. Rheometrics bestimmt. Ähnlich dem bei Homopolymeren beobachteten Verhalten ergab sich auch hier mit wachsendem Molekulargewicht eine Verbreiterung des Kautschuk-Plateaus und eine Verkleinerung des Endbereichs. Die komplexe Viskosität zeigte erst bei höheren Frequenzen das Einsetzen nicht-newtonschen Fließens an, wobei der nichtnewtonsche Bereich mit steigendem Molekulargewicht größer wurde.Der SpeichermodulG ergab sich im Endbereich als proportional zu ^1,5, im Unterschied zu der bei Polystyrol beobachteten Proportionalität mit ². Dagegen war der VerlustmodulG der Frequenz direkt proportional, ähnlich wie es auch bei Polystyrol beobachtet worden war. Die dynamische Viskosität | ^*| zeigte unabhängig vom Molekulargewicht bei hohen Frequenzen einen Bereich, in dem eine Potenz-Beziehung | ^*| ~ ^0,9 herrschte, was auf die Wirkung von Verzweigungen hindeutet. Dagegen galt bei den niedrigen Frequenzen des newtonschen Bereichs|^*| ~ . Mit Hilfe der WLF-Gleichung wurde der Ausdehnungskoeffizient _f bestimmt, der ebenso wie der Glasübergang eine negative Abweichung von der Fox-Flory-Beziehung zeigte.

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With 10 figures and 1 table     

Free convection on an arbitrarily inclined plate with uniform surface heat flux

This paper proposed a proper inclination parameter and transformation variables for the analysis of free convection from an inclined plate with uniform surface heat flux to fluids of any Prandtl number. Very accurate numerical results and a simple correlation equation are obtained for arbitrary inclination from the horizontal to the vertical and for 0.001 Pr. Maximum deviation between the correlated and calculated data is less than 1.2%.

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Freie Konvektion an einer beliebig geneigten Platte mit erheblicher Wärmestromdichte an der Oberfläche

Zusammenfassung Für die Berechnung von freier Konvektion von Fluiden mit beliebiger Prandtl-Zahl an einer geneigten Platte mit einheitlicher Wärmestromdichte an der Oberfläche werden ein zweckmäßiger Neigungsparameter und Transformationsvariablen eingeführt. Sehr genaue numerische Ergebnisse und eine einfache Korrelationsgleichung wurden für beliebige Neigungen zwischen der Horizontalen und der Vertikalen und für 0.001Pr erhalten. Die größte Abweichung zwischen Korrelations- und berechneten Daten liegt bei weniger als 1.2%.

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Nomenclature f reduced stream function - g gravitational acceleration - h local heat transfer coefficient - k thermal conductivity - Nu local Nusselt number - p static pressure difference - Pr Prandtl number - q _w wall heat flux - Ra* modified local Rayleigh number,g(q _w x/k)x ³/ - T fluid temperature - T temperature of ambient fluid - u velocity component inx-direction - v velocity component iny-direction - x coordinate parallel to the plate - y coordinate normal to the plate Greek symbols thermal diffusivity - thermal expansion coefficient - (Ra* |sin|)^1/5/( Ra* cos)^1/6 - ( Ra* cos)^1/6+( Ra*|sin|)^1/5 - (y/x) - dimensionless temperature, (T–T )/(q _w x/k) - kinematic viscosity - [1+( Ra* cos)^1/6/( Ra*|sin|)^1/5]^–1 - density of fluid - Pr/(1+Pr) - _w wall shear stress - angle of inclination measured from the horizontal - stream function - dimensionless static pressure difference, p x ²/ ⁴     

The theory of a vibrating-rod viscometer

The paper presents a complete theory for a viscometer based upon the principle of a circular-section rod, immersed in a fluid, performing transverse oscillations perpendicular to its axis. The theory is established as a result of a detailed analysis of the fluid flow around the rod and is subject to a number of criteria which subsequently constrain the design of an instrument. Using water as an example it is shown that a practical instrument can be designed so as to enable viscosity measurement with an accuracy of ±0.1%, although it is noted that many earlier instruments failed to satisfy one or more of the newly-established constraints.Nomenclature A, D constants in equation (46) - A _m , B _m , C _m , D _m constants in equations (50) and (51) - A _j , B _j constants in equation (14) - a _j ⁺ , a _j ^– wavenumbers given by equation (15) - C _f drag coefficient defined in equation (53) - c speed of sound - D _b drag force of fluid b - D ₀ coefficient of internal damping - E extensional modulus - f(z) initial deformation of rod - f(), F _m () functions of defined in equation (41) - F force in the rod - force per unit length near t=0 - F dimensionless force per unit length near t=0 - g _m amplitude of transient force - G modulus of rigidity - h, h* functions defined by equations (71) and (72) - H functions defined by equation (69) and (70) - I second moment of area - I _0,1, J _0,1, K _0,1 modified Bessel functions - k, k functions defined in equations (2) - L half-length of oscillator - Ma Mach number - m _b added mass per unit length of fluid b - m _s mass per unit length of solid - n _j eigenvalue defined in equations (15) and (16) - R radius of rod - R _c radius of container - r radial coordinate - T tension - T _visc temperature rise due to heat generation by viscous dissipation - t time - v _r , v radial and angular velocity components - y lateral displacement - y ₀ initial lateral displacement - y ₁, y ₂ successive maximum lateral displacement - z axial coordinate - dimensionless tension - dimensionless mass of fluid - dimensionless drag of fluid - amplification factor - logarithmic decrement in a fluid - _a , _b logarithmic decrement in fluids a and b - ₀ logarithmic decrement in vacuo - _j logarithmic decrement in mode j in a fluid - spatial resolution of amplitude - _v voltage resolution - r, , , _s, , increments in R, , , _s , , - dimensionless amplitude of oscillation - dimensionless axial coordinate - angular coordinate - _f thermal conductivity of fluid - viscosity of fluid - viscosity of fluid calculated on assumption that * - _a , _b viscosity of fluids a and b - _m constants in equation (10) - dimensionless displacement - _j j the component of - density of fluid - _a , _b density of fluids a and b - _s density of tube or rod material - dimensionless radial coordinate - * dimensionless radius of container - dimensionless times - spatial component of defined in equation (11) - _j , _tm jth, mth component of - dimensionless streamfunction - ⁰, ¹ components of in series expansion in powers of - streamfunction - dimensionless frequency (based on ) - angular frequency - ₀ angular frequency in absence of fluid and internal damping - _j angular frequency in mode j in a fluid - _a , _b frequencies in fluids a and b