Transport in ordered and disordered porous media III: Closure and comparison between theory and experiment

In this paper we examine the closure problem associated with the volume averaged form of the Stokes equations presented in Part II. For both ordered and disordered porous media, we make use of a spatially periodic model of a porous medium. Under these circumstances the closure problem, in terms of theclosure variables, is independent of the weighting functions used in the spatial smoothing process. Comparison between theory and experiment suggests that the geometrical characteristics of the unit cell dominate the calculated value of the Darcy's law permeability tensor, whereas the periodic conditions required for thelocal form of the closure problem play only a minor role.Roman Letters A interfacial area of the- interface contained within the macroscopic region, m² - A _e area of entrances and exits for the-phase contained within the macroscopic system, m² - A interfacial area of the- interface associated with the local closure problem, m² - A _p surface area of a particle, m² - b vector used to represent the pressure deviation, m^–1 - B ⁰ B+I, a second order tensor that maps v _m ontov - B second-order tensor used to represent the velocity deviation - d _p 6V _p/A_p, effective particle diameter, m - d a vector related to the pressure, m - D a second-order tensor related to the velocity, m² - g gravity vector, m/s² - I unit tensor - K traditional Darcy's law permeability tensor calculated on the basis of a spatially periodic model, m² - K _m permeability tensor for the weighted average form of Darcy's law, m² - L general characteristic length for volume averaged quantities, m - L _p characteristic length for the volume averaged pressure, m - L characteristic length for the porosity, m - L _v characteristic length for the volume averaged velocity, m - characteristic length (pore scale) for the-phase - _i i=1, 2, 3 lattice vectors, m - weighting function - m(-y) , convolution product weighting function - m _v special convolution product weighting function associated with the traditional averaging volume - m _g general convolution product weighting function - m _V unit cell convolution product weighting function - m _C special convolution product weighting function for ordered media which produces the cellular average - n unit normal vector pointing from the-phase toward the -phase - p pressure in the-phase, N/m² - p _m superficial weighted average pressure, N/m² - p _m intrinsic weighted average pressure, N/m² - p traditional intrinsic volume averaged pressure, N/m² - p – p _m , spatial deviation pressure, N/m² - r ₀ radius of a spherical averaging volume, m - r _m support of the convolution product weighting function - r position vector, m - r position vector locating points in the-phase, m. - V averaging volume, m³ - B volume of the-phase contained in the averaging volume, m³ - V _cell volume of a unit cell, m³ - v velocity vector in the-phase, m/s - v _m superficial weighted average velocity, m/s - v _m intrinsic weighted average velocity, m/s - v traditional superficial volume averaged velocity, m/s - v – v _m , spatial deviation velocity, m/s - x position vector locating the centroid of the averaging volume or the convolution product weighting function, m - y position vector relative to the centroid, m - y position vector locating points in the -phase relative to the centroid, m Greek Letters indicator function for the-phase - Dirac distribution associated with the- interface - V /V, volume average porosity - _m m * , weighted average porosity - mass density of the-phase, kg/m³ - viscosity of the-phase, Ns/m²     

Correlations between porous medium flow data and turbulent tube flow results for aqueous hydroxypropylguar solutions (Part 2)

Turbulent tube flow and the flow through a porous medium of aqueous hydroxypropylguar (HPG) solutions in concentrations from 100 wppm to 5000 wppm is investigated. Taking the rheological flow curves into account reveals that the effectiveness in turbulent tube flow and the efficiency for the flow through a porous medium both start at the same onset wall shear stress of 1.3 Pa. The similarity of the curves = ( _w ) and = ( _w ), respectively, leads to a simple linear relation / =k, where the constantk or proportionality depends uponc. This offers the possibility to deduce (for turbulent tube flow) from (for flow through a porous medium). In conjunction with rheological data, will reveal whether, and if yes to what extent, drag reduction will take place (even at high concentrations).The relation of our treatment to the model-based Deborah number concept is shown and a scale-up formula for the onset in turbulent tube flow is deduced as well.     

The Thermodynamic Significance of the Local Volume Averaged Temperature

Since the temperature is not an additive function, the traditional thermodynamic point of view suggests that the volume integral of the temperature has no precise physical meaning. This observation conflicts with the customary analysis of non-isothermal catalytic reactors, heat pipes, driers, geothermal processes, etc., in which the volume averaged temperature plays a crucial role. In this paper we identify the thermodynamic significance of the volume averaged temperature in terms of a simple two-phase heat transfer process. Given the internal energy as a function of the point temperature and the density

Transport in ordered and disordered porous media IV: Computer generated porous media for three-dimensional systems

In the method of volume averaging, the difference between ordered and disordered porous media appears at two distinct points in the analysis, i.e. in the process of spatial smoothing and in the closure problem. In theclosure problem, the use of spatially periodic boundary conditions isconsistent with ordered porous media and the fields under consideration when the length-scale constraint,r ₀L is satisfied. For disordered porous media, spatially periodic boundary conditions are an approximation in need of further study.In theprocess of spatial smoothing, average quantities must be removed from area and volume integrals in order to extractlocal transport equations fromnonlocal equations. This leads to a series of geometrical integrals that need to be evaluated. In Part II we indicated that these integrals were constants for ordered porous media provided that the weighting function used in the averaging process contained thecellular average. We also indicated that these integrals were constrained by certain order of magnitude estimates for disordered porous media. In this paper we verify these characteristics of the geometrical integrals, and we examine their values for pseudo-periodic and uniformly random systems through the use of computer generated porous media.

Nomenclature

Roman Letters A interfacial area of the- interface associated with the local closure problem, m² - A _e area of entrances and exits for the-phase contained within the averaging system, m² - a _i i=1, 2, 3 gaussian probability distribution used to locate the position of particles - I unit tensor - L general characteristic length for volume averaged quantities, m - L characteristic length for , m - L characteristic length for , m - characteristic length for the -phase particles, m - ⁰ reference characteristic length for the-phase particles, m - characteristic length for the-phase, m - _i i=1, 2, 3 lattice vectors, m - m convolution product weighting function - m _v special convolution product weighting function associated with the traditional volume average - n _i i=1, 2, 3 integers used to locate the position of particles - n unit normal vector pointing from the-phase toward the-phase - n _e outwardly directed unit normal vector at the entrances and exits of the-phase - r _p position vector locating the centroid of a particle, m - r gaussian probability distribution used to determine the size of a particle, m - r ₀ characteristic length of an averaging region, m - r position vector, m - r _m support of the weighting functionm, m - averaging volume, m³ - V volume of the-phase contained in the averaging volume,, m³ - x positional vector locating the centroid of an averaging volume, m - x ₀ reference position vector associated with the centroid of an averaging volume, m - y position vector locating points relative to the centroid, m - y position vector locating points in the-phase relative to the centroid, m Greek Letters indicator function for the-phase - Dirac distribution associated with the- interface - V /V, volume average porosity - /L, small parameter in the method of spatial homogenization - standard deviation ofa _i - _r standard deviation ofr - _r intrinsic phase average of      

Flow in porous media III: Deformable media

Stokes flow in a deformable medium is considered in terms of an isotropic, linearly elastic solid matrix. The analysis is restricted to steady forms of the momentum equations and small deformation of the solid phase. Darcy's law can be used to determine the motion of the fluid phase; however, the determination of the Darcy's law permeability tensor represents part of the closure problem in which the position of the fluid-solid interface must be determined.Roman Letters A interfacial area of the- interface contained within the macroscopic system, m² - A interfacial area of the- interface contained within the averaging volume, m² - A _e area of entrances and exits for the-phase contained within the macroscopic system, m² - A ^* interfacial area of the- interface contained within a unit cell, m² - A _e ^* area of entrances and exits for the-phase contained within a unit cell, m² - E Young's modulus for the-phase, N/m² - e i unit base vectors (i = 1, 2, 3) - g gravity vector, m²/s - H height of elastic, porous bed, m - k unit base vector (=e ₃) - characteristic length scale for the-phase, m - L characteristic length scale for volume-averaged quantities, m - n unit normal vector pointing from the-phase toward the-phase (n = -n ) - p pressure in the-phase, N/m² - P p – g·r, N/m² - r ₀ radius of the averaging volume, m - r position vector, m - t time, s - T total stress tensor in the-phase, N/m² - T ⁰ hydrostatic stress tensor for the-phase, N/m² - u displacement vector for the-phase, m - V averaging volume, m₃ - V volume of the-phase contained within the averaging volume, m³ - v velocity vector for the-phase, m/s Greek Letters V /V, volume fraction of the-phase - mass density of the-phase, kg/m³ - shear coefficient of viscosity for the-phase, Nt/m² - first Lamé coefficient for the-phase, N/m² - second Lamé coefficient for the-phase, N/m² - bulk coefficient of viscosity for the-phase, Nt/m² - T –T ⁰ , a deviatoric stress tensor for the-phase, N/m²     

Two-phase flow in heterogeneous porous media II: Numerical experiments for flow perpendicular to a stratified system

In this work, we make use of numerical experiments to explore our original theoretical analysis of two-phase flow in heterogeneous porous media (Quintard and Whitaker, 1988). The calculations were carried out with a two-region model of a stratified system, and the parameters were chosen be consistent with practical problems associated with groundwater flows and petroleum reservoir recovery processes. The comparison between theory (the large-scaled averaged equations) and experiment (numerical solution of the local volume averaged equations) has allowed us to identify conditions for which the quasi-static theory is acceptable and conditions for which a dynamic theory must be used. Byquasi-static we mean the following: (1) The local capillary pressure,everywhere in the averaging volume, can be set equal to the large-scale capillary pressure evaluated at the centroid of the averaging volume and (2) the large-scale capillary pressure is given by the difference between the large-scale pressures in the two immiscible phases, and is therefore independent of gravitational effects, flow effects and transient effects. Bydynamic, we simply mean a significant departure from the quasi-static condition, thus dynamic effects can be associated with gravitational effects, flow effects and transient effects. To be more precise about the quasi-static condition we need to refer to the relation between the local capillary pressure and the large-scale capillary pressure derived in Part I (Quintard and Whitaker, 1990). Herep _c ¦_y represents the local capillary pressure evaluated at a positiony relative to the centroid of the large-scale averaging volume, and {p _c }¦_x represents the large-scale capillary pressure evaluated at the centroid.In addition to{p _c } ^c being evaluated at the centroid, all averaged terms on the right-hand side of Equation (1) are evaluated at the centroid. We can now write the equations describing the quasi-static condition as , , This means that the fluids within an averaging volume are distributed according to the capillary pressure-saturation relationwith the capillary pressure held constant. It also means that the large-scale capillary pressure is devoid of any dynamic effects. Both of these conditions represent approximations (see Section 6 in Part I) and one of our main objectives in this paper is to learn something about the efficacy of these approximations. As a secondary objective we want to explore the influence of dynamic effects in terms of our original theory. In that development only the first four terms on the right hand side of Equation (1) appeared in the representation for the local capillary pressure. However, those terms will provide an indication of the influence of dynamic effects on the large-scale capillary pressure and the large-scale permeability tensor, and that information provides valuable guidance for future studies based on the theory presented in Part I.Roman Letters A scalar that maps {}*/t onto - A scalar that maps {}*/t onto - A interfacial area between the -region and the -region contained within, m² - A interfacial area between the -region and the -region contained within, m² - A interfacial area between the -region and the -region contained within, m² - a vector that maps ({}*/t) onto , m - a vector that maps ({}*/t) onto , m - b vector that maps ({p}– g) onto , m - b vector that maps ({p}– g) onto , m - B second order tensor that maps ({p}– g) onto , m² - B second order tensor that maps ({p}– g) onto , m² - c vector that maps ({}*/t) onto , m - c vector that maps ({}*/t) onto , m - C second order tensor that maps ({}*/t) onto , m² - C second order tensor that maps ({}*/t) onto . m² - D third order tensor that maps ( ) onto , m - D third order tensor that maps ( ) onto , m - D second order tensor that maps ( ) onto , m² - D second order tensor that maps ( ) onto , m² - E third order tensor that maps () onto , m - E third order tensor that maps () onto , m - E second order tensor that maps () onto - E second order tensor that maps () onto - p _c =(), capillary pressure relationship in the-region - p _c =(), capillary pressure relationship in the-region - g gravitational vector, m/s² - largest of either or - - - i unit base vector in thex-direction - I unit tensor - K local volume-averaged-phase permeability, m² - K local volume-averaged-phase permeability in the-region, m² - K local volume-averaged-phase permeability in the-region, m² - {K } large-scale intrinsic phase average permeability for the-phase, m² - K –{K }, large-scale spatial deviation for the-phase permeability, m² - K –{K }, large-scale spatial deviation for the-phase permeability in the-region, m² - K –{K }, large-scale spatial deviation for the-phase permeability in the-region, m² - K ^* large-scale permeability for the-phase, m² - L characteristic length associated with local volume-averaged quantities, m - characteristic length associated with large-scale averaged quantities, m - I _i i = 1, 2, 3, lattice vectors for a unit cell, m - l characteristic length associated with the-region, m - ; characteristic length associated with the-region, m - l _H characteristic length associated with a local heterogeneity, m - - n unit normal vector pointing from the-region toward the-region (n =–n ) - n unit normal vector pointing from the-region toward the-region (n =–n ) - p pressure in the-phase, N/m² - p local volume-averaged intrinsic phase average pressure in the-phase, N/m² - {p } large-scale intrinsic phase average pressure in the capillary region of the-phase, N/m² - p local volume-averaged intrinsic phase average pressure for the-phase in the-region, N/m² - p local volume-averaged intrinsic phase average pressure for the-phase in the-region, N/m² - p –{p }, large scale spatial deviation for the-phase pressure, N/m² - p –{p }, large scale spatial deviation for the-phase pressure in the-region, N/m² - p –{p }, large scale spatial deviation for the-phase pressure in the-region, N/m² - P _c p –{p }, capillary pressure, N/m² - {p_c}^c large-scale capillary pressure, N/m² - r ₀ radius of the local averaging volume, m - R ₀ radius of the large-scale averaging volume, m - r position vector, m - , m - S /, local volume-averaged saturation for the-phase - S ^* {}*{}*, large-scale average saturation for the-phaset time, s - t time, s - u , m - U , m² - v -phase velocity vector, m/s - v local volume-averaged phase average velocity for the-phase in the-region, m/s - v local volume-averaged phase average velocity for the-phase in the-region, m/s - {v } large-scale intrinsic phase average velocity for the-phase in the capillary region of the-phase, m/s - {v } large-scale phase average velocity for the-phase in the capillary region of the-phase, m/s - v –{v }, large-scale spatial deviation for the-phase velocity, m/s - v –{v }, large-scale spatial deviation for the-phase velocity in the-region, m/s - v –{v }, large-scale spatial deviation for the-phase velocity in the-region, m/s - V local averaging volume, m³ - V volume of the-phase in, m³ - V large-scale averaging volume, m³ - V capillary region for the-phase within, m³ - V capillary region for the-phase within, m³ - V _c intersection of m³ - V volume of the-region within, m³ - V volume of the-region within, m³ - V () capillary region for the-phase within the-region, m³ - V () capillary region for the-phase within the-region, m³ - V () , region in which the-phase is trapped at the irreducible saturation, m³ - y position vector relative to the centroid of the large-scale averaging volume, m Greek Letters local volume-averaged porosity - local volume-averaged volume fraction for the-phase - local volume-averaged volume fraction for the-phase in the-region - local volume-averaged volume fraction for the-phase in the-region - local volume-averaged volume fraction for the-phase in the-region (This is directly related to the irreducible saturation.) - {} large-scale intrinsic phase average volume fraction for the-phase - {} large-scale phase average volume fraction for the-phase - {}* large-scale spatial average volume fraction for the-phase - –{}, large-scale spatial deviation for the-phase volume fraction - –{}, large-scale spatial deviation for the-phase volume fraction in the-region - –{}, large-scale spatial deviation for the-phase volume fraction in the-region - a generic local volume-averaged quantity associated with the-phase - mass density of the-phase, kg/m³ - mass density of the-phase, kg/m³ - viscosity of the-phase, N s/m² - viscosity of the-phase, N s/m² - interfacial tension of the - phase system, N/m - , N/m - , volume fraction of the-phase capillary (active) region - , volume fraction of the-phase capillary (active) region - , volume fraction of the-region ( + =1) - , volume fraction of the-region ( + =1) - {p }– g, N/m³ - {p }– g, N/m³     

Transport in ordered and disordered porous media II: Generalized volume averaging

In this paper we develop the averaged form of the Stokes equations in terms of weighting functions. The analysis clearly indicates at what point one must choose a media-specific weighting function in order to achieve spatially smoothed transport equations. The form of the weighting function that produces the cellular average is derived, and some important geometrical theorems are presented.Roman Letters A interfacial area of the- interface associated with the local closure problem, m² - A _e area of entrances and exits for the-phase contained within the averaging system, m² - A _p surface area of a particle, m² - d _p 6V _p/A_p, effective particle diameter, m - g gravity vector, m/s² - I unit tensor - K _m permeability tensor for the weighted average form of Darcy's law, m² - L general characteristic length for volume averaged quantities, m - L _p general characteristic length for volume averaged pressure, m - L characteristic length for the porosity, m - L _v characteristic length for the volume averaged velocity, m - l characteristic length (pore scale) for the-phase - l _i i=1, 2, 3 lattice vectors, m - (y) weighting function - m(–y) (y), convolution product weighting function - _v special weighting function associated with the traditional averaging volume - m _v special convolution product weighting function associated with the traditional averaging volume - m _g general convolution product weighting function - m _V unit cell convolution product weighting function - m _C special convolution product weighting function for ordered media which produces the cellular average - m _D special convolution product weighting function for disordered media - m _M master convolution product weighting function for ordered and disordered media - n unit normal vector pointing from the-phase toward the-phase - p pressure in the-phase, N/m² - p_m superficial weighted average pressure, N/m² - p _m intrinsic weighted average pressure, N/m² - p traditional intrinsic volume averaged pressure, N/m² - p p p _m , spatial deviation pressure, N/m² - r ₀ radius of a spherical averaging volume, m - r _m support of the convolution product weighting function, m - r position vector, m - r position vector locating points in the-phase, m - V averaging volume, m³ - V volume of the-phase contained in the averaging volume, m³ - V _cell volume of a unit cell, m³ - V velocity vector in the-phase, m/s - vm superficial weighted average velocity, m/s - v _m intrinsic weighted average velocity, m/s - V volume of the-phase contained in the averaging volume, m³ - V _p volume of a particle, m³ - v traditional superficial volume averaged velocity, m/s - v v p _m spatial deviation velocity, m/s - x position vector locating the centroid of the averaging volume or the convolution product weighting function, m - y position vector relative to the centroid, m - y position vector locating points in the-phase relative to the centroid, m Greek Letters indicator function for the-phase - Dirac distribution associated with the- interface - V /V, volume average porosity - _m m * . weighted average porosity - mass density of the-phase, kg/m³ - viscosity of the-phase, Ns/m² - V /V, volume fraction of the-phase     

Lp-estimates for the nonlinear spatially homogeneous Boltzmann equation

This paper studies L^p-estimates for solutions of the nonlinear, spatially homogeneous Boltzmann equation. The molecular forces considered include inverse k^th-power forces with k > 5 and angular cut-off.The main conclusions are the following. Let f be the unique solution of the Boltzmann equation with f(v,t)(1 + ¦v²¦)^(s ₁ ^{+ /p)/2} L¹, when the initial value f ₀ satisfies f ₀(v) 0, f ₀(v) (1 + ¦v¦²)^(s ₁ ^{+ /p)/2} L¹, for some s₁ 2 + /p, and f ₀(v) (1 + ¦v¦²)^s/2 L^p. If s 2/p and 1 < p < , then f(v, t)(1 + ¦v¦²)^{(s s} ₁)^/2 L^p, t > 0. If s >2 and 3/(1+ ) < p < , thenf(v,t) (1 + ¦v¦²)^(s(s ₁ ^{+ 3/p))/2} L^p, t > 0. If s >2 + 2C₀/C₁ and 3/(l + ) < p < , then f(v,t)(1 + ¦v¦²)^s/2 L^p, t > 0. Here 1/p + 1/p = 1, x y = min (x, y), and C₀, C₁, 0 < 1, are positive constants related to the molecular forces under consideration; = (k – 5)/ (k – 1) for k^th-power forces.Some weaker conclusions follow when 1 < p 3/ (1 + ).In the proofs some previously known L-estimates are extended. The results for L^p, 1 < p < , are based on these L-estimates coupled with nonlinear interpolation.     

Two-phase flow in heterogeneous porous media III: Laboratory experiments for flow parallel to a stratified system

Two-phase flow in stratified porous media is a problem of central importance in the study of oil recovery processes. In general, these flows are parallel to the stratifications, and it is this type of flow that we have investigated experimentally and theoretically in this study. The experiments were performed with a two-layer model of a stratified porous medium. The individual strata were composed of Aerolith-10, an artificial: sintered porous medium, and Berea sandstone, a natural porous medium reputed to be relatively homogeneous. Waterflooding experiments were performed in which the saturation field was measured by gamma-ray absorption. Data were obtained at 150 points distributed evenly over a flow domain of 0.1 × 0.6 m. The slabs of Aerolith-10 and Berea sandstone were of equal thickness, i.e. 5 centimeters thick. An intensive experimental study was carried out in order to accurately characterize the individual strata; however, this effort was hampered by both local heterogeneities and large-scale heterogeneities.The theoretical analysis of the waterflooding experiments was based on the method of large-scale averaging and the large-scale closure problem. The latter provides a precise method of discussing the crossflow phenomena, and it illustrates exactly how the crossflow influences the theoretical prediction of the large-scale permeability tensor. The theoretical analysis was restricted to the quasi-static theory of Quintard and Whitaker (1988), however, the dynamic effects described in Part I (Quintard and Whitaker 1990a) are discussed in terms of their influence on the crossflow.Roman Letters A interfacial area between the -region and the -region contained within V, m² - a vector that maps onto , m - b vector that maps onto , m - b vector that maps onto , m - B second order tensor that maps onto , m² - C second order tensor that maps onto , m² - E energy of the gamma emitter, keV - f fractional flow of the -phase - g gravitational vector, m/s² - h characteristic length of the large-scale averaging volume, m - H height of the stratified porous medium , m - i unit base vector in the x-direction - K local volume-averaged single-phase permeability, m² - K - {K}, large-scale spatial deviation permeability - { K} large-scale volume-averaged single-phase permeability, m² - K ^* large-scale single-phase permeability, m² - K ^** equivalent large-scale single-phase permeability, m² - K local volume-averaged -phase permeability in the -region, m² - K local volume-averaged -phase permeability in the -region, m² - K - {K } , large-scale spatial deviation for the -phase permeability, m² - K ^* large-scale permeability for the -phase, m² - l thickness of the porous medium, m - l characteristic length for the -region, m - l characteristic length for the -region, m - L length of the experimental porous medium, m - characteristic length for large-scale averaged quantities, m - n outward unit normal vector for the -region - n outward unit normal vector for the -region - n unit normal vector pointing from the -region toward the -region (n = - n ) - N number of photons - p pressure in the -phase, N/m² - p ₀ reference pressure in the -phase, N/m² - local volume-averaged intrinsic phase average pressure in the -phase, N/m² - large-scale volume-averaged pressure of the -phase, N/m² - large-scale intrinsic phase average pressure in the capillary region of the -phase, N/m² - - , large-scale spatial deviation for the -phase pressure, N/m² - p_c , capillary pressure, N/m² - p _c capillary pressure in the -region, N/m² - p capillary pressure in the -region, N/m² - {p _c } ^c large-scale capillary pressure, N/m² - q -phase velocity at the entrance of the porous medium, m/s - q -phase velocity at the entrance of the porous medium, m/s - S_wi irreducible water saturation - S /, local volume-averaged saturation for the -phase - S _i initial saturation for the -phase - S _r residual saturation for the -phase - S ^* { }^*/}^*, large-scale average saturation for the -phase - S saturation for the -phase in the -region - S saturation for the -phase in the -region - t time, s - v -phase velocity vector, m/s - v local volume-averaged phase average velocity for the -phase, m/s - {v } large-scale averaged velocity for the -phase, m/s - v local volume-averaged phase average velocity for the -phase in the -region, m/s - v local volume-averaged phase average velocity for the -phase in the -region, m/s - v -{v } , large-scale spatial deviation for the -phase velocity, m/s - v -{v } , large-scale spatial deviation for the -phase velocity in the -region, m/s - v -{v } , large-scale spatial deviation for the -phase velocity in the -region, m/s - V large-scale averaging volume, m³ - y position vector relative to the centroid of the large-scale averaging volume, m - {y}^c large-scale average of y over the capillary region, m Greek Letters local porosity - local porosity in the -region - local porosity in the -region - local volume fraction for the -phase - local volume fraction for the -phase in the -region - local volume fraction for the -phase in the -region - {}^* { }^*+{ }^*, large-scale spatial average volume fraction - { }^* large-scale spatial average volume fraction for the -phase - mass density of the -phase, kg/m³ - mass density of the -phase, kg/m³ - viscosity of the -phase, N s/m² - viscosity of the -phase, Ns/m² - V /V , volume fraction of the -region ( + =1) - V /V , volume fraction of the -region ( + =1) - attenuation coefficient to gamma-rays, m^-1 - -      

On the closure problem for Darcy's law

In a previous derivation of Darcy's law, the closure problem was presented in terms of an integro-differential equation for a second-order tensor. In this paper, we show that the closure problem can be transformed to a set of Stokes-like equations and we compare solutions of these equations with experimental data. The computational advantages of the transformed closure problem are considerable.Roman Letters A interfacial area of the- interface contained within the macroscopic system, m² - A _e area of entrances and exits for the-phase contained within the macroscopic system, m² - A interfacial area of the- interface contained within the averaging volume, m² - A _e area of entrances and exits for the-phase contained within the averaging volume, m² - B second-order tensor used to respresent the velocity deviation - b vector used to represent the pressure deviation, m^–1 - C second-order tensor related to the permeability tensor, m^–2 - D second-order tensor used to represent the velocity deviation, m² - d vector used to represent the pressure deviation, m - g gravity vector, m/s² - I unit tensor - K C ^–1,–D, Darcy's law permeability tensor, m² - L characteristic length scale for volume averaged quantities, m - characteristic length scale for the-phase, m - l _i i=1, 2, 3, lattice vectors, m - n unit normal vector pointing from the-phase toward the-phase - n _e outwardly directed unit normal vector at the entrances and exits of the-phase - p pressure in the-phase, N/m ² - p intrinsic phase average pressure, N/m² - p –p , spatial deviation of the pressure in the-phase, N/m² - r position vector locating points in the-phase, m - r ₀ radius of the averaging volume, m - t time, s - v velocity vector in the-phase, m/s - v intrinsic phase average velocity in the-phase, m/s - v phase average or Darcy velocity in the \-phase, m/s - v –v , spatial deviation of the velocity in the-phase m/s - V averaging volume, m³ - V volume of the-phase contained in the averaging volume, m³ Greek Letters V /V volume fraction of the-phase - mass density of the-phase, kg/m³ - viscosity of the-phase, Nt/m²     

Viscoelastic swirling flow with free surface in cylindrical chambers

The flow of a viscoelastic liquid driven by the steadily rotating bottom cover of a cylindrical cup is investigated. The flow field and the shape of the free surface are determined at the lowest significant orders of the regular domain perturbation in terms of the angular velocity of the bottom cap. The meridional field superposed on a primary azimuthal field shows a structure of multiple cells. The velocity field and the shape of the free surface are strongly effected by the cylinder aspect ratio and the elasticity of the liquid. The use of this flow configuration as a free surface rheometer to determine the first two Rivlin-Ericksen constants is shown to be promising.Nomenclature R, ,Z Coordinates in the physical domain D - , , Coordinates in the rest stateD ₀ - r, ,z Dimensionless coordinates in the rest stateD ₀ - Angular velocity - Zero shear viscosity - Surface tension coefficient - Density - Dimensionless surface tension parameter - ₁, ₂ The first two Rivlin-Ericksen constants - Stream function - Dimensionless second order meridional stream function - ^* Dimensionless second normal stress function - 2 Dimensionless sum of the first and second normal stress functions - N ₁,N ₂ The first and second normal stress functions - n Unit normal vector - D Stretching tensor - A _n nth order Rivlin-Ericksen tensor - S Extra-stress - u Velocity field - U Dimensionless second order meridional velocity field - V Dimensionless first order azimuthal velocity field - p Pressure - Modified pressure field - P Dimensionless second order pressure field - J Mean curvature - a Cylinder radius - d Liquid depth at rest - D Dimensionless liquid depth at rest - h Free surface height - H Dimensionless free surface height at the second order     

The rheology of polymeric liquid crystals

The molecular theory of Doi has been used as a framework to characterize the rheological behavior of polymeric liquid crystals at the low deformation rates for which it was derived, and an appropriate extension for high deformation rates is presented. The essential physics behind the Doi formulation has, however, been retained in its entirety. The resulting four-parameter equation enables prediction of the shearing behavior at low and high deformation rates, of the stress in extensional flows, of the isotropic-anisotropic phase transition and of the molecular orientation. Extensional data over nearly three decades of elongation rate (10^–2–10¹) and shearing data over six decades of shear rate (10^–2–10⁴) have been correlated using this analysis. Experimental data are presented for both homogeneous and inhomogeneous shearing stress fields. For the latter, a 20-fold range of capillary tube diameters has been employed and no effects of system geometry or the inhomogeneity of the flow-field are observed. Such an independence of the rheological properties from these effects does not occur for low molecular weight liquid crystals and this is, perhaps, the first time this has been reported for polymeric lyotropic liquid crystals; the physical basis for this major difference is discussed briefly. A Semi-empirical constant in eq. (18), N/m² - c rod concentration, rods/m³ - c ^* critical rod concentration at which the isotropic phase becomes unstable, rods/m³ - C interaction potential in the Doi theory defined in eq. (3) - d rod diameter, m - D semi-empirical constant in eq. (19), s^–1 - D _r lumped rotational diffusivity defined in eq. (4), s^–1 - rotational diffusivity of rods in a concentrated (liquid crystalline) system, s^–1 - D _ro rotational diffusivity of a dilute solution of rods, s^–1 - f distribution function defining rod orientation - F tensorial term in the Doi theory defined in eq. (7) (or eq. (19)), s^–1 - G tensorial term in the Doi theory defined in eq. (8) - K _B Boltzmann constant, 1.38 × 10^–23 J/K-molecule - L rod length, m - S scalar order parameter - S tensor order parameter defined in eq. (5) - t time, s - T absolute temperature, K - u unit vector describing the orientation of an individual rod - rate of change ofu due to macroscopic flow, s^–1 - v fluid velocity vector, m/s - v velocity gradient tensor defined in eq. (9), s^–1 - V mean field (aligning) potential defined in eq. (2) - x coordinate direction, m - Kronecker delta (= 0 if = 1 if = ) - _r ratio of viscosity of suspension to that of the solvent at the same shear stress - _s solvent viscosity, Pa · s - ^* viscosity at the critical concentrationc ^*, Pa · s - v ₁, v₂ numerical factors in eqs. (3) and (4), respectively - deviatoric stress tensor, N/m² - volume fraction of rods - ⁰ constant in eq. (16) - ^* volume fraction of rods at the critical concentrationc ^* - average over the distribution functionf(u, t) (= d ²u f(u, t)) - gradient operator - d ²u integral over the surface of the sphere (|u| = 1)     

Transport in ordered and disordered porous media V: Geometrical results for two-dimensional systems

In this paper we continue the geometrical studies of computer generated two-phase systems that were presented in Part IV. In order to reduce the computational time associated with the previous three-dimensional studies, the calculations presented in this work are restricted to two dimensions. This allows us to explore more thoroughly the influence of the size of the averaging volume and to learn something about the use of anon-representative region in the determination of averaged quantities.

Nomenclature

Roman Letters A interfacial area of the– interface associated with the local closure problem, m² - a _i i=1, 2, gaussian probability distribution used to locate the position of particles - l unit tensor - characteristic length for the-phase particles, m - ⁰ reference characteristic length for the-phase particles, m - characteristic length for the-phase, m - _i i=1,2,3 lattice vectors, m - m convolution product weighting function - m _V special convolution product weighting function associated with a unit cell - n _i i=1, 2 integers used to locate the position of particles - n unit normal vector pointing from the-phase toward the-phase - r _p position vector locating the centroid of a particle, m - r gaussian probability distribution used to determine the size of a particle, m - r ₀ characteristic length of an averaging region, m - V averaging volume, m³ - V volume of the-phase contained in the averaging volume,V, m³ - x position of the centroid of an averaging area, m - x ₀ reference position of the centroid of an averaging area, m - y position vector locating points in the-phase relative to the centroid, m Greek Letters V /V, volume average porosity - _{a i} standard deviation ofa _i - _r standard deviation ofr - intrinsic phase average of      

Stability transitions for periodic orbits in hamiltonian systems

The paper considers one-parameter families of periodic solutions of real analytic Hamiltonian systems with two degrees of freedom, the parameter being the energy h. Conditions are given which guarantee that this family will undergo infinitely many changes in stability status as h tends to some finite value h ₀. First considered is the case of a critical point (with eigenvalues ±, ±i, and >0) of the Hamiltonian at energy h ₀ with the property that the family limits to a homoclinic orbit asymptotic to this point. Some generalizations of this case are given, and applications are made to examples such as the Hénon-Heiles Hamiltonian. We obtain an infinite sequence of distinct energy intervals converging to h ₀ on which the periodic orbits are elliptic. Requirements for the elliptic stability of the orbits are then given. The additional conditions for an infinite sequence of distinct energy intervals converging to h ₀, on which the orbits are hyperbolic, involve the coexistence problem for an associated Hill's equation that appears when the relevant Poincaré maps along the orbits are computed in coordinates. The results are compared to the case where the critical point has eigenvalues (±±i), and >0, investigated by Henrard and Devaney.     

Fatigue crack propagaion under mixed mode loading

Mixed model fatigue crack propagation is analyzed in this paper, using a centre cracked plate geometry, loaded under un-iaxial cyclic tension. Based on maximum principal stress criterion, a modified Paris expression of fatigue crack growth rate is derived in terms of ΔK and crack angle β_α for an inclined crack. It is also shown that it is more convenient to express the Paris equation by means of crack length projected on the x -axis, α_x rather than the actual length, α itself. The crack trajectory due to cyclic loading is predicted, β is varied from 29° to 90°. Experimental data on Type L3 aluminium agree fairly well with predicted values when β_α exceeds 30°.     

Messung der Viskosität von Kohlendioxid und Propylen

Zusammenfassung Die Viskosität von Kohlendioxid und Propylen wurde bei Temperaturen zwischen 298 K und 473 K und Drücken zwischen 1 bar und dem zweifachen kritischen Druck mit einem Schwingscheibenviskosimeter gemessen. Dieses unterscheidet sich von den bisher bekannten Schwingscheibenviskosimetern insbesondere durch die optische Einrichtung zur Bestimmung der Winkelamplituden. Die mittleren relativen Fehler der Meßwerte sind vom thermodynamischen Zustandsbereich abhängig und liegen zwischen 0,9 % und 1,6%. Für Interpolationsrechnungen werden einfache Gleichungen angegeben.

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Measurements on the viscosity of carbon dioxide and propylene

Measurements on the viscosity of carbon dioxide and propylene are reported. The experimental investigations have been performed with an oscillating disk viscosimeter at temperatures between 298 K and 473K and pressures from 1 bar up to the twofold critical pressure of each gas. The optical system for reproducing the oscillations of the disk on a scale is modified to the yet known oscillating disk viscosimeters. With respect to the thermodynamic state of the gas an accuracy between 98,4% and 99,1% could be reached. For correlating the measured values two polynomial approximations are reported.

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Formelzeichen b mittlere Spaltbreite; - C_N,C Gerätekonstante - D Scheibenabstand - d Scheibendicke - J Trägheitsmoment - p Druck - R Scheibenradius - T Temperatur - T_kr kritische Temperatur - T_N normierte Temperatur, T_N=T/T_kr - t Zeit - Zeitverhältnis; =t/t_O - logarithmisches Dekrement - dynamische Viskosität - kinematische Viskosität - Kreisfrequenz - Dichte - _kr kritische Dichte - _N normierte Dichte; _N= /_kr Index 0 Vakuum Der Verfasser dankt Herrn Prof. Dr.-Ing. K. Stephan für die grozügige Förderung dieser Arbeit.     

The chaotic response of a fluttering panel: The influence of maneuvering

The influence of maneuvering on the chaotic response of a fluttering buckled plate on an aircraft has been studied. The governing equations, derived using Lagrangian mechanics, include geometric non-linearities associated with the occurrence of tensile stresses, as well as coupling between the angular velocity of the maneuver and the elastic degrees of freedom. Numerical simulation for periodic and chaotic responses are conducted in order to analyze the influence of the pull-up maneuver on the dynamic behavior of the panel. Long-time histories phase-plane plots, and power spectra of the responses are presented. As the maneuver (load factor) increases, the system exhibits complicated dynamic behavior including a direct and inverse cascade of subharmonic bifurcations, intermittency, and chaos. Beside these classical routes of transition from a periodic state to chaos, our calculations suggest amplitude modulation as a possible new mode of transition to chaos. Consequently this research contributes to the understanding of the mechanisms through which the transition between periodic and strange attractors occurs in, dissipative mechanical systems. In the case of a prescribed time dependent maneuver, a remarkable transition between the different types of limit cycles is presented.Nomenclature a plate length - a _r u _r /h - D plate bending stiffness - E modulus of elasticity - g acceleration due to gravity - h plate thickness - j₁,j₂,j₃ base vectors of the body frame of reference - K spring constant - M Mach number - n 1 + ₀/g - N ₁ applied in-plane force - p–p aerodynamic pressure - P pa ⁴/Dh - q ₀/2 - Q _r generalized Lagrangian forces - R rotation matrix - R ₄ N, a ²/D - t time - kinetic energy - u plate deflection - u displacement of the structure - u _r modal amplitude - v₀ velocity - x coordinates in the inertial frame of reference - z coordinates in the body frame of reference - Ka/(Ka+Eh) - - elastic energy - 2qa ³/D - a/_mh - Poisson's ratio - material coordinates - air density - _m plate density - - _r prescribed functions - _r sin(r z/a) - angular velocity - a/v₀ - skew-symmetric matrix form of the angular velocity     

Dielectric properties of the composite system polyurethane — sodium chloride

Summary The dielectric properties of the composite system polyurethane-sodium chloride have been measured at frequencies between 10^–4 Hz and 3 · 10⁵ Hz in the temperature range from –150 °C up to +90 dgC. Three dielectric loss mechanisms have been found; they are indicated by ₁, ₂ and. The activation energy of the ₁-transition is 35 kcal/mole, that of the-transition 6.7 kcal/mole. The ₂-loss peak was only observed at frequencies of 10³ Hz and higher, forming one broad peak with the ₁-loss peak at lower frequencies. In the composite materials, the- and ₂-loss peaks measured at fixed frequencies were found at the same temperature. The ₂-loss peak, however, was shifted to a lower temperature, due to the sodium chloride filler. Comparison of experimental data of and tan with theoretical predictions concerning the dielectric properties of composite systems showed only partial agreement. The difference mainly consisted in. the temperature shift in the tan-peak of the ₁-transition.

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Zusammenfassung Die dielektrischen Eigenschaften des Verbundssystems Kochsalz-Polyurethankautschuk wurden im Frequenzgebiet zwischen 10^–4 Hz und 3.10⁵ Hz und im Temperaturbereich von –150 °C bis +90 °C gemessen. Es wurden drei dielektrische Verlustmaxima gefunden, die mit ₁, ₂ und angedeutet werden. Die Aktivierungsenergie des ₁-Überganges beträgt 35 kcal/Mol, die des-Überganges 6.7 kcal/Mol. Das ₂-Maximum konnte nur bei Frequenzen höher als 10³Hz vom ₁-Maximum gesondert erfaßt werden. Die Lage der ₂- und-Maxima war vom Füllgrad unabhängig. Das ₁-Maximum verschiebt sich mit steigendem Füllgrad zu niedrigeren Temperaturen. Die gemessenen Werte von und tan stimmen nur teilweise mit den Aussagen einer Theorie der dielektrischen Eigenschaften von Mischkörpern überein.

     

The problems of nonlinear bending for orthotropic rectangular plate with four clamped edges

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Saint-Venant's principle in nonlinear plane elasticity with sufficiently small strains

A homogeneous, isotropic cylinder in an equilibrium state of plane strain, whose cross-section is a rectangle R : [0 < y ₁ < 2L; 0 < y ₂ < h] with h/L 1, is considered. There are no body forces and the long sides are stress free. At y ₁ = 0 and y ₁ = 2L, there are arbitrary loadings, each statically equivalent to a uniformly distributed tensile or compressive stress c. Within the theory of nonlinear elasticity and with the strains and strain gradients assumed to be sufficiently small (but with no such assumptions on the displacement gradients), it is proved that if (,=1,2) represents the Cauchy stress tensor and the Kronecker delta, then |–c₁₁| decays exponentially to zero in R with distance from the nearer end, and the decay constant depends only upon the material but is independent of L.