The contribution of internal degrees of freedom to the non-Newtonian rheology of model polymer fluids

We report non-equilibrium molecular dynamics simulations of rigid and non-rigid dumbbell fluids to determine the contribution of internal degrees of freedom to strain-rate-dependent shear viscosity. The model adopted for non-rigid molecules is a modification of the finitely extensible nonlinear elastic (FENE) dumbbell commonly used in kinetic theories of polymer solutions. We consider model polymer melts — that is, fluids composed of rigid dumbbells and of FENE dumbbells. We report the steady-state stress tensor and the transient stress response to an applied Couerte strain field for several strain rates. We find that the rheological properties of the rigid and FENE dumbbells are qualitatively and quantitatively similar. (The only exception to this is the zero strain rate shear viscosity.) Except at high strain rates, the average conformation of the FENE dumbbells in a Couette strain field is found to be very similar to that of FENE dumbbells in the absence of strain. The theological properties of the two dumbbell fluids are compared to those of a corresponding fluid of spheres which is shown to be the most non-Newtonian of the three fluids considered.Symbol Definition b dimensionless time constant relating vibration to other forms of motion - F force on center of mass of dumbbell - F _i force on bead i of dumbbell - F force between center of masses of dumbbells and - F _ij force between beads i and j - h vector connecting bead to center of mass of dumbbell - H dimensionless spring constant for dumbbells, in units of / ² - I moment of inertia of dumbbell - J general current induced by applied field - k _B Boltzmann's constant - L angular momentum - m mass of bead, (= m/2) - M mass of dumbbell, g - N number of dumbbells in simulation cell - P translational momentum of center of mass of dumbbell - P pressure tensor - P _xy xy component of pressure tensor - Q separation of beads in dumbbell - Q _eq equilibrium extension of FENE dumbbell and fixed extension of rigid dumbbell - Q ₀ maximum extension of dumbbell - r _ij vector connecting beads i and j - r position vector of center of mass dumbbell - R vector connecting centers of mass of two dumbbells - t time - t ^* dimensionless time, in units of m/ - T ^* dimensionless temperature, in units of /k - u potential energy - u velocity vector of flow field - u _x x component of velocity vector - V volume of simulation cell - X general applied field - strain rate, s^–1 - ^* dimensionless shear rate, in units of /m ² - general transport property - Lennard-Jones potential well depth - friction factor for Gaussian thermostat - shear viscosity, g/cms - ^* dimensionless shear viscosity, in units of m/ ² - ^* dimensionless number density, in units of ^–3 - Lennard-Jones separation of minimum energy - relaxation time of a fluid - angular velocity of dumbbell - orientation angle of dumbbell      

The theory of a vibrating-rod viscometer

The paper presents a complete theory for a viscometer based upon the principle of a circular-section rod, immersed in a fluid, performing transverse oscillations perpendicular to its axis. The theory is established as a result of a detailed analysis of the fluid flow around the rod and is subject to a number of criteria which subsequently constrain the design of an instrument. Using water as an example it is shown that a practical instrument can be designed so as to enable viscosity measurement with an accuracy of ±0.1%, although it is noted that many earlier instruments failed to satisfy one or more of the newly-established constraints.Nomenclature A, D constants in equation (46) - A _m , B _m , C _m , D _m constants in equations (50) and (51) - A _j , B _j constants in equation (14) - a _j ⁺ , a _j ^– wavenumbers given by equation (15) - C _f drag coefficient defined in equation (53) - c speed of sound - D _b drag force of fluid b - D ₀ coefficient of internal damping - E extensional modulus - f(z) initial deformation of rod - f(), F _m () functions of defined in equation (41) - F force in the rod - force per unit length near t=0 - F dimensionless force per unit length near t=0 - g _m amplitude of transient force - G modulus of rigidity - h, h* functions defined by equations (71) and (72) - H functions defined by equation (69) and (70) - I second moment of area - I _0,1, J _0,1, K _0,1 modified Bessel functions - k, k functions defined in equations (2) - L half-length of oscillator - Ma Mach number - m _b added mass per unit length of fluid b - m _s mass per unit length of solid - n _j eigenvalue defined in equations (15) and (16) - R radius of rod - R _c radius of container - r radial coordinate - T tension - T _visc temperature rise due to heat generation by viscous dissipation - t time - v _r , v radial and angular velocity components - y lateral displacement - y ₀ initial lateral displacement - y ₁, y ₂ successive maximum lateral displacement - z axial coordinate - dimensionless tension - dimensionless mass of fluid - dimensionless drag of fluid - amplification factor - logarithmic decrement in a fluid - _a , _b logarithmic decrement in fluids a and b - ₀ logarithmic decrement in vacuo - _j logarithmic decrement in mode j in a fluid - spatial resolution of amplitude - _v voltage resolution - r, , , _s, , increments in R, , , _s , , - dimensionless amplitude of oscillation - dimensionless axial coordinate - angular coordinate - _f thermal conductivity of fluid - viscosity of fluid - viscosity of fluid calculated on assumption that * - _a , _b viscosity of fluids a and b - _m constants in equation (10) - dimensionless displacement - _j j the component of - density of fluid - _a , _b density of fluids a and b - _s density of tube or rod material - dimensionless radial coordinate - * dimensionless radius of container - dimensionless times - spatial component of defined in equation (11) - _j , _tm jth, mth component of - dimensionless streamfunction - ⁰, ¹ components of in series expansion in powers of - streamfunction - dimensionless frequency (based on ) - angular frequency - ₀ angular frequency in absence of fluid and internal damping - _j angular frequency in mode j in a fluid - _a , _b frequencies in fluids a and b     

Free convection from a vertical plate with concentrated and distributed thermal sources

An analysis is developed for the laminar free convection from a vertical plate with uniformly distributed wall heat flux and a concentrated line thermal source embedded at the leading edge. We introduce a parameter=(1 +Q _L/Q_w)^–1=(1 + Ra_L/Ra_w)^–1 to describe the relative strength of the two thermal sources; and propose a unified buoyancy parameter=( Ra_L+ Ra_w)^1/5 with=1/(1 +Pr ^–1) to properly scale the dependent and independent variables. The variables are so defined that the resulting nonsimilar boundary-layer equations can describe exactly the buoyancy-induced flow from the dual sources with any relative strength to fluids of any Prandtl number from very small values to infinity. These nonsimilar equations are readily reducible to the self-similar equations of an adiabatic wall plume for=0, and to those of free convection from uniform flux plate for=1. Rigorous finite-difference solutions for fluids of Pr from 0.001 to are obtained over the entire range of from 0 to 1. The effects of both relative source strength and Prandtl number on the velocity profiles, temperature profiles, and the variations of wall temperature, are clearly illustrated.

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Freie Konvektion an einer vertikalen Platte mit einer konzentrierten und einer gleichmäßig verteilten Wärmequelle

Zusammenfassung Für die freie Konvektion an einer vertikalen Platte mit einer gleichmäßig verteilten Wandwärmestromdichte und einer in der Vorderkante eingebetteten linienförmigen Wärmequelle wird eine Berechnungsmethode entwickelt. Zur Beschreibung der relativen Stärke der beiden Wärmequellen führen wir einen Parameter=(1 + Q_L/Q_w)^–1=(1 + Ra_L/Ra_w)^–1 ein und schlagen einen vereinheitlichten Auftriebsparameter=( Ra _L+ Ra _w)^1/5 mit=1/(1 +Pr ^–1 für die Skalierung der abhängigen und unabhängigen Variablen vor. Die Variablen werden so definiert, daß mit den sich ergebenden unabhängigen Grenzschichtgleichungen die von den beiden Wärmequellen beliebiger Stärke verursachte Auftriebsströmung von Fluiden beliebiger Prandtl-Zahl genau beschrieben werden kann. Diese unabhängigen Gleichungen können ohne weiteres auf die selbstähnlichen Gleichungen für den Fall einer lokalen Wärmezufuhr an einer sonst adiabatischen Wand für=0 und jenen der freien konvektion an einer Platte mit einheitlichem Wärmestrom für=1 zurückgeführt werden. Für Fluide mit der Prandtl-Zahl zwischen 0,001 und Unendlich werden nach der strengen finite Differenzen-Methode Lösungen im Bereich von zwischen 0 und 1 erhalten. Der jeweilige Einfluß der relativen Quellenstärke und der Prandtl-Zahl auf die Geschwindigkeits- und Temperaturprofile sowie die Veränderung der Wandtemperatur werden deutlich dargestellt.

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Nomenclature C _f friction coefficient - C _p specific heat - f reduced stream function - g gravitational acceleration - k thermal conductivity - L width of the plate - Nu local Nusselt number - Pr Prandtl number - q _w wall heat flux - Q _L heat generated by the line source - Q _w heat released by the uniform-flux wall from 0 tox, q _w Lx - Ra _L local Rayleigh number, g T _L ^* x ³/( ) - Ra _w local Rayleigh number,g T _w ^* w ³/( ) - T fluid temperature - T temperature of ambient fluid - T _L ^* characteristic temperature of the line source,Q _{L/(C p} L) - T _w ^* characteristic temperature of the uniform flux wall, =q _w x/k=Q _w /(C _p L) - u velocity component in then-direction - U₀ dimensionless velocity,u/(/x) Ra _L ^2/5 - U ₁ dimensionless velocity,u/(/x) Ra _w ^2/5 - velocity component in they-direction - x coordinate parallel to the plate - y coordinate normal to the plate - thermal diffusivity - thermal expansion coefficient - pseudo-similarity variable,(y/x) - dimensionless temperature, (T–T )/(T _L ^* +T _w ^* ) - ₀ dimensionless temperature, (Ra_l)^1/5 (T–T )/T _L ^* - ₁ dimensionless temperature, (Ra_w)Ra_w)^1/5 (T–T )/T _w ^* - (Ra _L+Ra_w)^1/5 - kinematic viscosity - (1 +Ra _L/Ra_w)^–1=(1 +T _L ^* /T _w ^* )^–1=(1 + Q_L/Q_w)^–1 - density - Pr/(1 +Pr) - _w wall shear stress - stream function     

Zur Variationsformulierung nichtlinearer Randwertprobleme

Übersicht Es werden verschiedene Bedingungen aufgestellt, die es erlauben, die durch die beiden (Systeme von) nichtlinearen DifferentialgleichungenA (u, ) = q, B (u, ) = und Randbedingungen zusammen mit den nichtlinearen algebraischen Relationenq = C(u, ), = D(u, ) beschriebene Aufgabe durch äquivalente Variationsprobleme zu ersetzen. Dabei zeigt sich ein enger Zusammenhang mit den in der Festkörpermechanik wohlbekannten Prinzipien der virtuellen Verschiebungen und der virtuellen Kräfte. Die auf systematischem Weg konstruierten Variationsfunktionale enthalten viele in der Physik bekannte Funktionale als Sonderfälle, insbesondere jene, die in der Elastomechanik nach Green, Castigliano, Hellinger, Reißner, Hu und Washizu benannt werden.

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Summary In this paper there are established various conditions which allow a variational formulation of the problem described by the two (systems of) nonlinear differential equationsA(u, ) = q, B(u, ) = and boundary conditions together with the nonlinear algebraic relationsq = C(u, ), = D(u, ). Besides a close relationship is revealed to the principles of virtual displacements and virtual forces which are wellknown in solid mechanics. The systematically constructed variational functional contain many functionals in physics as special cases, mainly those of Green, Castigliano, Hellinger, Reißner, Hu and Washizu in elastomechanics.

     

Positively invariant regions for a problem in phase transitions

Positively invariant regions for the system v _t + p(W) _x = V _xx , W _t –V _x = W _xx are constructed where p < 0, w < , w > , p(w) = 0, w , > 0. Such a choice of p is motivated by the Maxwell construction for a van der Waals fluid. The method of an analysis is a modification of earlier ideas of Chueh, Conley, & Smoller [1]. The results given here provide independent L bounds on the solution (w, v).Dedicated to Professor James Serrin on the occasion of his sixtieth birthday     

Flow in porous media I: A theoretical derivation of Darcy's law

Stokes flow through a rigid porous medium is analyzed in terms of the method of volume averaging. The traditional averaging procedure leads to an equation of motion and a continuity equation expressed in terms of the volume-averaged pressure and velocity. The equation of motion contains integrals involving spatial deviations of the pressure and velocity, the Brinkman correction, and other lower-order terms. The analysis clearly indicates why the Brinkman correction should not be used to accommodate ano slip condition at an interface between a porous medium and a bounding solid surface.The presence of spatial deviations of the pressure and velocity in the volume-averaged equations of motion gives rise to aclosure problem, and representations for the spatial deviations are derived that lead to Darcy's law. The theoretical development is not restricted to either homogeneous or spatially periodic porous media; however, the problem ofabrupt changes in the structure of a porous medium is not considered.Roman Letters A interfacial area of the - interface contained within the macroscopic system, m² - A _e area of entrances and exits for the -phase contained within the macroscopic system, m² - A interfacial area of the - interface contained within the averaging volume, m² - A ^* interfacial area of the - interface contained within a unit cell, m² - Ae area of entrances and exits for the -phase contained within a unit cell, m² - B second order tensor used to represent the velocity deviation (see Equation (3.30)) - b vector used to represent the pressure deviation (see Equation (3.31)), m^–1 - d distance between two points at which the pressure is measured, m - g gravity vector, m/s² - K Darcy's law permeability tensor, m² - L characteristic length scale for volume averaged quantities, m - characteristic length scale for the -phase (see Figure 2), m - characteristic length scale for the -phase (see Figure 2), m - n unit normal vector pointing from the -phase toward the -phase (n =–n ) - n _e unit normal vector for the entrances and exits of the -phase contained within a unit cell - p pressure in the -phase, N/m² - p intrinsic phase average pressure for the -phase, N/m² - p –p , spatial deviation of the pressure in the -phase, N/m² - r ₀ radius of the averaging volume and radius of a capillary tube, m - v velocity vector for the -phase, m/s - v phase average velocity vector for the -phase, m/s - v intrinsic phase average velocity vector for the -phase, m/s - v –v , spatial deviation of the velocity vector for the -phase, m/s - V averaging volume, m³ - V volume of the -phase contained within the averaging volume, m³ Greek Letters V/V, volume fraction of the -phase - mass density of the -phase, kg/m³ - viscosity of the -phase, Nt/m² - arbitrary function used in the representation of the velocity deviation (see Equations (3.11) and (B1)), m/s - arbitrary function used in the representation of the pressure deviation (see Equations (3.12) and (B2)), s^–1     

Heat transfer from laminar flow in ducts with elliptic cross-section

Summary The cooling of a hot fluid in laminar Newtonian flow through cooled elliptic tubes has been calculated theoretically. Numerical data have been computed for the two values 1.25 and 4 of the axial ratio of the elliptic cross-section . For =1.25 the influence of non-zero thermal resistance between outmost fluid layer and isothermal surroundings has also been investigated. Special attention has been given to the distribution of heat flux around the perimeter; when increases the flux varies more with the position at the circumference. This positional dependence becomes less pronounced, however, as the (position-independent) thermal resistance of the wall increases.Flattening of the conduit, while maintaining its cross-sectional area constant, improves the cooling. Comparison with rectangular pipes shows that this improvement is not as marked with elliptic as with rectangular pipes.Nomenclature A _k =A _{m, n} coefficients of expansion (6) - a, b half-axes of ellipse, b<a - a _p =a _{r, s} coefficients of representation (V) - D hydraulic diameter, = 4S/P; S = cross-sectional area, P = perimeter - D _e equivalent diameter, according to (13) - n coordinate (outward) normal to the tube wall - T temperature of fluid - T _i temperature of fluid at the inlet - T _s temperature of surroundings - v ₀ mean velocity of fluid - v _z longitudinal velocity of fluid - x, y carthesian coordinates coinciding with axes of ellipse - z coordinate in flow direction - , dimensionless half-axes of ellipse, =a/D and =b/D - _t heat transfer coefficient from fluid at bulk temperature to surroundings; equation (11) - _w heat transfer coefficient at the wall; equation (3) - axial ratio of ellipse, = a/b = / - , , , dimensionless coordinates; =x/D, =y/D, =z/D, =n/D - dimensionless temperature, = (T–T _s)/(T _i–T _s) - ₀ cup-mixing mean value of ; equation (10) - thermal conductivity of fluid - _m,n = _k eigenvalue - c volumetric heat capacity of fluid - _{m, n} = _k = _k eigenfunction; equations (6) and (I) - Nu total Nusselt number, = _t D/ - Nusselt number at large distance from the inlet - Nu _w wall Nusselt number, = _w D/, based on _w - Pé Péclet number, = ₀ Dc/     

Parameter determination for thermodynamical models of the pseudoelastic behaviour of shape memory alloy by resistivity measurements and infrared thermography

Two thermodynamical models of pseudoelastic behaviour of shape memory alloys have been formulated. The first corresponds to the ideal reversible case. The second takes into account the hysteresis loop characteristic of this shape memory alloys.Two totally independent techniques are used during a loading-unloading tensile test to determine the whole set of model parameters, namely resistivity and infrared thermography measurements. In the ideal case, there is no difficulty in identifying parameters.Infrared thermography measurements are well adapted for observing the phase transformation thermal effects.Notations 1 austenite 2 martensite - ₍₎ Macroscopic infinitesimal strain tensor of phase - ₍₂₎ ^f Traceless strain tensor associated with the formation of martensite phase - Macroscopic infiniesimal strain tensor - Macroscopic infinitesimal strain tensor deviator - _f Trace - Equivalent strain - ^pe Macroscopic pseudoelastic strain tensor - x Distortion due to parent (austenite =1)product (martensite =2) phase transformation (traceless symmetric second order tensor) - M Total mass of a system - M() Total mass of phase - V Total volume of a system - V() Total volume of phase - z=M(2)/M Weight fraction of martensite - 1-z=M(1)/M Weight fraction of austenite - u ₀ ^* () Specific internal energy of phase (=1,2) - s ₀ ^* () Specific internal entropy of phase - Specific configurational energy - Specific configurational entropy - ₀ ^f (T) Driving force for temperature-induced martensitic transformation at stress free state ( ₀ ^f T) = T ^*–Ts ^*) - Kirchhoff stress tensor - Kirchhoff stress tensor deviator - Equivalent stress - Cauchy stress tensor - Mass density - K Bulk moduli (K ₀=K) - L Elastic moduli tensor (order 4) - E Young modulus - Energetic shear (₀ = ) - Poisson coefficient - M _s ^o (M _F ^o ) Martensite start (finish) temperature at stress free state - A _s ^o (A _F ^o ) Austenite start (finish) temperature at stress free state - C _v Specific heat at constant volume - k Conductivity - Pseudoelastic strain obtained in tensile test after complete phase transformation (AM) (unidimensional test) - ₀ Thermal expansion tensor - r Resistivity - 1MPa 10⁶ N/m ² - ⁽⁾ Specific free energy of phase - _n Specific free energy at non equilibrium (R model) - _n ^eq Specific free energy at equilibrium (R model) - _n ^v Volumic part of ^eq - Specific free energy at non equilibrium (R _L model) - _conf Specific coherency energy (R _L model) - _c Specific free energy at constrained equilibria (R _L model) - _it (T) Coherency term (R _L model)     

Representation of the rheological properties of polymer melts in terms of complex fluidity

In dynamic rheological experiments melt behavior is usually expressed in terms of complex viscosity ^* () or complex modulusG ^* (). In contrast, we attempted to use the complex fluidity ^* () = 1/µ ^* () to represent this behavior. The main interest is to simplify the complex-plane diagram and to simplify the determination of fundamental parameters such as the Newtonian viscosity or the parameter of relaxation-time distribution when a Cole-Cole type distribution can be applied. ^* () complex shear viscosity - () real part of the complex viscosity - () imaginary part of the complex viscosity - G ^* () complex shear modulus - G() storage modulus in shear - G() loss modulus in shear - J ^* () complex shear compliance - J() storage compliance in shear - J() loss compliance in shear - shear strain - rate of strain - angular frequency (rad/s) - shear stress - loss angle - ^* () complex shear fluidity - () real part of the complex fluidity - () imaginary part of the complex fluidity - ₀ zero-viscosity - ₀ average relaxation time - h parameter of relaxation-time distribution     

Effects of MHD free convection and mass transfer on the flow past an oscillating infinite coaxial vertical circular cylinder

The effects of MHD free convection and mass transfer are taken into account on the flow past oscillating infinite coaxial vertical circular cylinder. The analytical expressions for velocity, temperature and concentration of the fluid are obtained by using perturbation technique.

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Einwirkungen von freier MHD-Konvektion und Stoffübertragung auf eine Strömung nach einem schwingenden unendlichen koaxialen vertikalen Zylinder

Zusammenfassung Die Einwirkungen der freien MHD-Konvektion und Stoffübertragung auf eine Strömung nach einem schwingenden, unendlichen, koaxialen, vertikalen Zylinder wurden untersucht. Die analytischen Ausdrücke der Geschwindigkeit, Temperatur und Fluidkonzentration sind durch die Perturbationstechnik erhalten worden.

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Nomenclature C _p Specific heat at constant temperature - C the species concentration near the circular cylinder - C _w the species concentration of the circular cylinder - C the species concentration of the fluid at infinite - * dimensionless species concentration - D chemical molecular diffusivity - g acceleration due to gravity - Gr Grashof number - Gm modified Grashof number - K thermal conductivity - Pr Prandtl number - r _a ,r _b radius of inner and outer cylinder - a, b dimensionless inner and outer radius - r,r coordinate and dimensionless coordinate normal to the circular cylinder - Sc Schmidt number - t time - t dimensionless time - T temperature of the fluid near the circular cylinder - T _w temperature of the circular cylinder - T temperature of the fluid at infinite - u velocity of the fluid - u dimensionless velocity of the fluid - U ₀ reference velocity - z,z coordinate and dimensionless coordinate along the circular cylinder - coefficient of volume expansion - * coefficient of thermal expansion with concentration - dimensionless temperature - H ₀ magnetic field intensity - coefficient of viscosity - _e permeability (magnetic) - kinematic viscosity - electric conductivity - density - M Hartmann number - dimensionless skin-friction - frequency - dimensionless frequency     

Transport in ordered and disordered porous media V: Geometrical results for two-dimensional systems

In this paper we continue the geometrical studies of computer generated two-phase systems that were presented in Part IV. In order to reduce the computational time associated with the previous three-dimensional studies, the calculations presented in this work are restricted to two dimensions. This allows us to explore more thoroughly the influence of the size of the averaging volume and to learn something about the use of anon-representative region in the determination of averaged quantities.

Nomenclature

Roman Letters A interfacial area of the– interface associated with the local closure problem, m² - a _i i=1, 2, gaussian probability distribution used to locate the position of particles - l unit tensor - characteristic length for the-phase particles, m - ⁰ reference characteristic length for the-phase particles, m - characteristic length for the-phase, m - _i i=1,2,3 lattice vectors, m - m convolution product weighting function - m _V special convolution product weighting function associated with a unit cell - n _i i=1, 2 integers used to locate the position of particles - n unit normal vector pointing from the-phase toward the-phase - r _p position vector locating the centroid of a particle, m - r gaussian probability distribution used to determine the size of a particle, m - r ₀ characteristic length of an averaging region, m - V averaging volume, m³ - V volume of the-phase contained in the averaging volume,V, m³ - x position of the centroid of an averaging area, m - x ₀ reference position of the centroid of an averaging area, m - y position vector locating points in the-phase relative to the centroid, m Greek Letters V /V, volume average porosity - _{a i} standard deviation ofa _i - _r standard deviation ofr - intrinsic phase average of      

Analytical evaluation of stress-strain test data

An analytical model for deducing the actual stress-strain properties from laboratory test results is discussed. As an illustration, an elastic bilinear material is used for unconfined cylindrical compression test conditions, as simulated with a finite element analysis. The results obtained are applicable for assisting in evaluating measured strength and stiffness properties of some clay soils, concrete test cylinders, concrete cores, and rock cores.The quantitative results of this study can be used for interpreting measured stress-strain data for unconfined compression test conditions. The error in measured results is shown to be influenced by Poisson's ratio, length-to-diameter ratio of the specimen, end condition, and ratio of inelastic modulus to initial elastic modulus. Curves for adjusting the measured results to the theoretical results are presented.Nomenclature D specimen diameter - E _i initial elastic stiffness modulus - E _y elastic stiffness modulus beyond the yield stress, plastic or inelastic modulus - L specimen length - axial strain - _av average strain - _g gage length strain - _y yield strain - Poisson's ratio - compressive stress - _av average stress - _t theoretical compressive stress - _y yield stress - _ym measured stress at the yield strain     

The dynamic performance of the Weissenberg rheogoniometer III. Large amplitude oscillatory shearing — harmonic analysis

The harmonic content of the nonlinear dynamic behaviour of 1% polyacrylamide in 50% glycerol/water was studied using a standard Model R 18 Weissenberg Rheogoniometer. The Fourier analysis of the Oscillation Input and Torsion Head motions was performed using a Digital Transfer Function Analyser.In the absence of fluid inertia effects and when the amplitude of the (fundamental) Oscillation Input motion _I is much greater than the amplitudes of the Fourier components of the Torsion Head motion _Tn empirical nonlinear dynamic rheological propertiesG _n (, ⁰),G _n (, ⁰) and/or _n (, ⁰), _n (, ⁰) may be evaluated without a-priori-knowledge of a rheological constitutive equation. A detailed derivation of the basic equations involved is presented.Cone and plate data for the third harmonic storage modulus (dynamic rigidity)G ₃ (, ⁰), loss modulusG ₃ (, ⁰) and loss angle ₃ (, ⁰) are presented for the frequency range 3.14 × 10^–2 1.25 × 10² rad/s at two strain amplitudes, _CP ⁰ = 2.27 and 4.03. Composite cone and plate and parallel plates data for both the third and fifth harmonic dynamic viscosities ₃ (, ⁰), _S (, ⁰) and dynamic rigiditiesG ₃ (, ⁰),G ₅ (, ⁰) are presented for strain amplitudes in the ranges 1.10 _CP ⁰ 4.03 and 1.80 _PP ⁰ 36 for a single frequency, = 3.14 × 10^–1 rad/s. Good agreement was obtained between the results from both geometries and the absence of significant fluid inertia effects was confirmed by the superposition of the data for different gap widths.     

Free convection heat transfer from an isothermal plate with arbitrary inclination

This paper presents a new formulation for the laminar free convection from an arbitrarily inclined isothermal plate to fluids of any Prandtl number between 0.001 and infinity. A novel inclination parameter is proposed such that all cases of the horizontal, inclined and vertical plates can be described by a single set of transformed equations. Moreover, the self-similar equations for the limiting cases of the horizontal and vertical plates are recovered from the transformed equations by setting=0 and=1, respectively. Heated upward-facing plates with positive and negative inclination angles are investigated. A very accurate correlation equation of the local Nusselt number is developed for arbitrary inclination angle and for 0.001 Pr .

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Wärmeübertragung bei freier Konvektion an einer isothermen Platte mit beliebiger Neigung

Zusammenfasssung Diese Untersuchung stellt eine neue Formulierung der laminaren freien Konvektion von Flüssigkeiten mit einer Prandtl-Zahl zwischen 0,001 und unendlich an einer beliebig schräggestellten isothermen Platte dar. Ein neuer Neigungsparameter wird eingeführt, so daß alle Fälle der horizontalen, geneigten oder vertikalen Platte von einem einzigen Satz transformierter Gleichungen beschrieben werden können. Die unabhängigen Gleichungen für die beiden Fälle der horizontalen and vertikalen Platte wurden für=0 und=1 aus den transformierten Gleichungen wieder abgeleitet. Es wurden erwärmte aufwärtsgerichtete Platten mit positiven und negativen Neigungswinkeln untersucht. Eine sehr genaue Gleichung wurde für die lokale Nusselt-Zahl bei beliebigen Neigungswinkeln und für 0,001 Pr entwickelt.

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Nomenclature C _p specific heat - f reduced stream function - g gravitational acceleration - Gr local Grashof number,g(T _w –T _w ) x³/v² - h local heat transfer coefficient - k thermal conductivity - n constant exponent - Nu local Nusselt number,hx/k - p pressure - Pr Prandtl number, v/ - Ra local Rayleigh number,g(T _w –T )J x³/v - T fluid temperature - T _w wall temperature - T temperature of ambient fluid - u velocity component in x-direction - v velocity component in y-direction - x coordinate parallel to the plate - y coordinate normal to the plate Greek symbols thermal diffusivity - thermal expansion coefficient - (Ra¦sin¦)^1/4/( Ra cos()^1/5 - pseudo-similarity variable, (y/) - dimensionless temperature, (T–T )/(T _w–T ) - ( Ra cos)^1/5+(Rasin)^1/4 - v kinematic viscosity - 1/[1 +(Ra cos)^1/5/( Ra¦sin)^1/4] - density of fluid - Pr/(1+Pr) - _w wall shear stress - angle of plate inclination measured from the horizontal - stream function - dimensionless dynamic pressure     

Transport in ordered and disordered porous media I: The cellular average and the use of weighting functions

In this work we consider transport in ordered and disordered porous media using singlephase flow in rigid porous mediaas an example. We defineorder anddisorder in terms of geometrical integrals that arise naturally in the method of volume averaging, and we show that dependent variables for ordered media must generally be defined in terms of thecellular average. The cellular average can be constructed by means of a weighting function, thus transport processes in both ordered and disordered media can be treated with a single theory based on weighted averages. Part I provides some basic ideas associated with ordered and disordered media, weighted averages, and the theory of distributions. In Part II a generalized averaging procedure is presented and in Part III the closure problem is developed and the theory is compared with experiment. Parts IV and V provide some geometrical results for computer generated porous media.Roman Letters A interfacial area of the- interface contained within the macroscopic region, m² - A_e area of entrances and exits for the-phase contained within the macroscopic system, m² - g gravity vector, m/s² - I unit tensor - K traditional Darcy's law permeability tensor, m² - L general characteristic length for volume averaged quantities, m - characteristic length (pore scale) for the-phase - (y) weighting function - m(–y) (y), convolution product weighting function - _v special weighting function associated with the traditional averaging volume - N unit normal vector pointing from the-phase toward the-phase - p pressure in the-phase, N/m² - p0 reference pressure in the-phase, N/m² - p traditional intrinsic volume averaged pressure, N/m² - r0 radius of a spherical averaging volume, m - r position vector, m - r position vector locating points in the-phase, m - averaging volume, m³ - V volume of the-phase contained in the averaging volume, m³ - V _cell volume of a unit cell, m³ - v velocity vector in the-phase, m/s - v traditional superficial volume averaged velocity, m/s - x position vector locating the centroid of the averaging volume or the convolution product weighting function, m - y position vector relative to the centroid, m - y position vector locating points in the-phase relative to the centroid, m Greek Letters indicator function for the-phase - Dirac distribution associated with the- interface - V/V, volume average porosity - mass density of the-phase, kg/m³ - viscosity of the-phase, Ns/m²     

Mean and turbulent velocity measurements of supersonic mixing layers

The behavior of supersonic mixing layers under three conditions has been examined by schlieren photography and laser Doppler velocimetry. In the schlieren photographs, some large-scale, repetitive patterns were observed within the mixing layer; however, these structures do not appear to dominate the mixing layer character under the present flow conditions. It was found that higher levels of secondary freestream turbulence did not increase the peak turbulence intensity observed within the mixing layer, but slightly increased the growth rate. Higher levels of freestream turbulence also reduced the axial distance required for development of the mean velocity. At higher convective Mach numbers, the mixing layer growth rate was found to be smaller than that of an incompressible mixing layer at the same velocity and freestream density ratio. The increase in convective Mach number also caused a decrease in the turbulence intensity ( _u/U).List of symbols a speed of sound - b total mixing layer thickness between U ₁ – 0.1 U and U ₂ + 0.1 U - f normalized third moment of u-velocity, f u³/(U)³ - g normalized triple product of u² , g u²/(U)³ - h normalized triple product of u ², h u ²/(U)³ - l _u axial distance for similarity in the mean velocity - l _u axial distance for similarity in the turbulence intensity - M Mach number - M _c convective Mach number (for ₁ = ₂), M _c (U ₁ – U ₂)/(a ₁ + a ₂) - P static pressure - r freestream velocity ratio, r U ₂/U ₁ - Re unit Reynolds number, Re U/ - s freestream density ratio, s ₂/₁ - T _t total temperature - u instantaneous streamwise velocity - u deviation of u-velocity, uu – U - U local mean streamwise velocity - U ₁ primary freestream velocity - U ₂ secondary freestream velocity - average of freestream velocities, (U ₁ + U ₂)/2 - U freestream velocity difference, U U ₁ – U ₂ - instantaneous transverse velocity - v deviation of -velocity, – V - V local mean transverse velocity - x streamwise coordinate - y transverse coordinate - y ₀ transverse location of the mixing layer centerline - ensemble average - ratio of specific heats - boundary layer thickness (y-location at 99.5% of free-stream velocity) - similarity coordinate, (y – y ₀)/b - compressible boundary layer momentum thickness - viscosity - density - standard deviation - dimensionless velocity, (U – U ₂)/U - 1 primary stream - 2 secondary stream A version of this paper was presented at the 11th Symposium on Turbulence, October 17–19, 1988, University of Missouri-Rolla     

Injection moulding of thermoplastics: Freezing of variable-viscosity fluids.

The injection moulding of thermoplastics involves, during mould filling, flows of hot polymer melts into mould networks, the walls of which are so cold that frozen layers form on them. An analytical study of such flows is presented here for the case when the Graetz number is small and the Nahme number is non-zero and can be large. Thus the flows are fully-developed and temperature differences due to heat generation by viscous dissipation are sufficiently large to cause significant variations in viscosity. Gz Graetz number - h half-height of channel or disc - h ^* half-height of polymer melt region in channel or disc - L length of channel or pipe - m viscosity shear-rate exponent - Na _Q Nahme number based on flowrate - Na _P Nahme number based on pressure drop - Na _PL lower critical value of Nahme number based on pressure drop - Na _PU upper critical value of Nahme number based on pressure drop - Na _P Nahme number based on pressure gradient - p pressure - P pressure drop - Q volumetric flowrate - r radial coordinate in pipe or disc - R radius of pipe - Re Reynolds number - R _i inner radius of disc - R ₀ outer radius of disc - R ^* radius of polymer melt region in pipe - T temperature - T _m melting temperature of polymer - T ₀ reference temperature - T _w wall temperature - u axial velocity in pipe or channel or radial velocity in disc - w width of channel - x axial coordinate in channel - y transverse coordinate in channel or disc - z axial coordinate in pipe - thermal conductivity of molten polymer - thermal conductivity of frozen polymer - heat capacity of molten polymer - viscosity temperature exponent - dimensionless transverse coordinate in channel or disc - ^* dimensionless half-height of polymer melt region in channel or disc - dimensionless temperature - ^* dimensionless wall temperature - µ viscosity of molten polymer - µ ₀ consistency of molten polymer - dimensionless pressure drop - dimensionless pressure gradient - density of molten polymer - dimensionless radial coordinate in pipe or disc - _i dimensionless inner radius of disc - ^* dimensionless radius of polymer melt region in pipe - dimensionless velocity     

Transient flow towards a well in an aquifer including the effect of fluid inertia

Transient propagation of weak pressure perturbations in a homogeneous, isotropic, fluid saturated aquifer has been studied. A damped wave equation for the pressure in the aquifer is derived using the macroscopic, volume averaged, mass conservation and momentum equations. The equation is applied to the case of a well in a closed aquifer and analytical solutions are obtained to two different flow cases. It is shown that the radius of influence propagates with a finite velocity. The results show that the effect of fluid inertia could be of importance where transient flow in porous media is studied.List of symbols b Thickness of the aquifer, m - c ₀ Wave velocity, m/s - k Permeability of the porous medium, m² - n Porosity of the porous medium - p( ,t) Pressure, N/m² - Q Volume flux, m³/s - r Radial coordinate, m - r _w Radius of the well, m - s Transform variable - S Storativity of the aquifer - S _d(r, t) Drawdown, m - t Time, s - T Transmissivity of the aquifer, m²/s - ( ,t) Velocity of the fluid, m/s - Coordinate vector, m - z Vertical coordinate, m - Coefficient of compressibility, m²/N - Coefficient of fluid compressibility, m²/N - Relaxation time, s - (r, t) Hydraulic potential, m - Dynamic viscosity of the fluid, Ns/m² - Dimensionless radius - Density of the fluid, Ns²/m⁴ - (, ) Dimensionless drawdown - Dimensionless time - , x Dummy variables - ₀, ₁ Auxilary functions     

On the thermodynamics of elastic-plastic materials with temperature-dependent moduli and yield stresses

Summary The subject of this article is the thermodynamics of perfect elastic-plastic materials undergoing unidimensional, but not necessarily isothermal, deformations. The first and second laws of thermodynamics are employed in a form in which only the following quantities appear: the temperature , the elastic strain _e, the plastic strain _p, the elastic modulus (gq), the yield strain (gq), the heat capacity (_e, _p,), the latent elastic heat _e(_e, _p, ), and the latent plastic heat _p(_e, _p, ). Relations among the response functions , , , _e, and _p are derived, and it is shown that a set of these relations gives a necessary and sufficient condition for compliance with the laws of thermodynamics. Some observations are made about the existence and uniqueness of energy and entropy as functions of state.Dedicated to Clifford Truesdell on the occasion of his 60th birthdayThis research was supported by the U.S. National Science Foundation.     

Power spectra of fluid velocities measured by laser Doppler velocimetry

The power spectrum and the correlation of the laser Doppler velocimeter velocity signal obtained by sampling and holding the velocity at each new Doppler burst are studied. Theory valid for low fluctuation intensity flows shows that the measured spectrum is filtered at the mean sample rate and that it contains a filtered white noise spectrum caused by the steps in the sample and hold signal. In the limit of high data density, the step noise vanishes and the sample and hold signal is statistically unbiased for any turbulence intensity.List of symbols A cross-section of the LDV measurement volume, m² - A empirical constant - B bandwidth of velocity spectrum, Hz - C concentration of particles that produce valid signals, number/m³ - d _m diameter of LDV measurement volume, m - f(₁, ₂ | u) probability density of t _i; and t _j given (t) for all t, Hz² - probability density for t _j-t_i, Hz - n (t, t) number of valid bursts in (t, t) = N + n - N (t, t) mean number of valid bursts in (t, t) - N _e mean number of particles in LDV measurement volume - valid signal arrival rate, Hz - mean valid signal arrival rate, Hz - R _uu time delayed autocorrelation of velocity, m²/s² - S _u power spectrum of velocity, m²/s²/Hz - t ₁, t ₂ times at which velocity is correlated, s - t _i, t _j arrival times of the bursts that immediately precede t ₁ and t ₂, respectively, s - t _ij t _j–t _i s - T averaging time for spectral estimator, s - T _u integral time scale of u (t), s - T Taylor's microscale for u (t), s - u velocity vector = U + u, m/s - u fluctuating component of velocity, m/s - U mean velocity, m/s - u _m sampled and held signal, m/s Greek symbols (t) noise signal, m/s - _m (t) sampled and held noise signal, m/s - bandwidth of spectral estimator window, radians/s - time between arrivals in pdf, s - Taylor's microscale of length = UT m - kinematic viscosity - ₁, ₂ arrival times in pdf, s - root mean square of noise signal, m/s - _u root mean square of u, m/s - delay time = t ₂ - t ₁ s - B duration of a Doppler burst, s - circular frequency, radians/s - _c low pass frequency of signal spectrum radians/s Other symbols ensemble average - conditional average - ^ estimate