Generalized self-consistent estimation of the apparent isotropic elastic moduli and minimum representative volume element size of heterogeneous media

Under investigation is a heterogeneous material consisting of an elastic homogeneous isotropic matrix in which layered elastic isotropic inclusions or pores are embedded. The generalized self-consistent model (GSCM) is extended so as to be capable of estimating the apparent elastic properties of a finite-size specimen smaller than a representative volume element (RVE). The kinematical or static apparent shear modulus is determined as a root of a cubic polynomial equation instead of a quadratic polynomial equation as in the classical GSCM of Christensen and Lo [Christensen, R.M., Lo, K.H., 1979. Solutions for effective shear properties in three phase sphere and cylinder models. J. Mech. Phys. Solids 27, 315–330]. It turns out that the extended GSCM establishes a link between the composite sphere assemblage model (CSAM) of Hashin [Hashin, Z., 1962. The elastic moduli of heterogeneous materials. J. Appl. Mech. 29, 143–150] and the classical GSCM. Demanding that the normalized distance between the kinematical and static apparent moduli of a finite-size specimen be smaller than a certain tolerance, the minimum RVE size is estimated in a closed form.     

A generalized self-consistent Mori-Tanaka model for predicting the effective moduli of the coated inclusion based composite materials

The weak point of the generalized self-consistent method (GSCM) is that its solution for the effective shear moduli involves determining the complicated displacement and strain fields in constitutents. Furthermore, the effective moduli estimated by GSCM cannot be expressed in an explicit form. Instead of following the procedure of GSCM, in this paper a generalized self-consistent Mori-Tanaka method (GSCMTM) is developed by means of Hill's interface condition and the assumption that the strain in the inclusion is uniform. A comparison with the existing theoretical and experimental results shows that the present GSCMTM is sufficiently accurate to predict the effective moduli of the coated inclusion-based composite materials. Moreover, it is interesting to find that the application of Hill's interface condition in volumetric domain is equivalent to the Mori-Tanaka average field approximation. This project was supported by the National Natural Science Foundation of China and China Postdoctoral Science Foundation.     

An explicit expression of the effective moduli for composite materials filled with coated inclusions

The obvious shortcoming of the generalized self-consistent method (GSCM) is that the effective shear modulus of composite materials estimated by the method can not be expressed in an explicit form. This is inconvenient in engineering applications. In order to overcome that shortcoming of GSCM, a reformation of GSCM is made and a new micromechanical scheme is suggested in this paper. By means of this new scheme, both the effective bulk and shear moduli of an inclusion-matrix composite material can be obtained and be expressed in simple explicit forms. A comparison with the existing models and the rigorous Hashin-Shtrikman bounds demonstrates that the present scheme is accurate. By a two-step homogenization technique from the present new scheme, the effective moduli of the composite materials with coated spherical inclusions are obtained and can also be expressed in an explicit form. The comparison with the existing theoretical and experimental results shows that the present solutions are satisfactory. Moreover, a quantitative comparison of GSCM and the Mori-Tanaka method (MTM) is made based on a unified scheme. The project supported by the National Natural Science Foundation of China under the Contract NO. 19632030 and 19572008, and China Postdoctoral Science Foundation     

Rigorous bounds on the effective moduli of composites and inhomogeneous bodies with negative-stiffness phases

We review the theoretical bounds on the effective properties of linear elastic inhomogeneous solids (including composite materials) in the presence of constituents having non-positive-definite elastic moduli (so-called negative-stiffness phases). Using arguments of Hill and Koiter, we show that for statically stable bodies the classical displacement-based variational principles for Dirichlet and Neumann boundary problems hold but that the dual variational principle for traction boundary problems does not apply. We illustrate our findings by the example of a coated spherical inclusion whose stability conditions are obtained from the variational principles. We further show that the classical Voigt upper bound on the linear elastic moduli in multi-phase inhomogeneous bodies and composites applies and that it imposes a stability condition: overall stability requires that the effective moduli do not surpass the Voigt upper bound. This particularly implies that, while the geometric constraints among constituents in a composite can stabilize negative-stiffness phases, the stabilization is insufficient to allow for extreme overall static elastic moduli (exceeding those of the constituents). Stronger bounds on the effective elastic moduli of isotropic composites can be obtained from the Hashin–Shtrikman variational inequalities, which are also shown to hold in the presence of negative stiffness.     

Solutions for effective shear properties in three phase sphere and cylinder models

Solutions are presented for the effective shear modulus of two types of composite material models. The first type is that of a macroscopically isotropic composite medium containing spherical inclusions. The corresponding model employed is that involving three phases: the spherical inclusion, a spherical annulus of matrix material and an outer region of equivalent homogeneous material of unlimited extent. The corresponding two-dimensional, polar model is used to represent a transversely isotropic, fiber reinforced medium. In the latter case only the transverse effective shear modulus is obtained. The relative volumes of the inclusion phase to the matrix annulus phase in the three phase models are taken to be the given volume fractions of the inclusion phases in the composite materials at large. The results are found to differ from those of the well-known Kerner and Hermans formulae for the same models. The latter works are now understood to violate a continuity condition at the matrix to equivalent homogeneous medium interface. The present results are compared extensively with results from other related models. Conditions of linear elasticity are assumed.     

An exact solution for the three-phase thermo-electro-magneto-elastic cylinder model and its application to piezoelectric–magnetic fiber composites

A three-phase cylindrical model for analyzing fiber composite subject to in-plane mechanical load under the coupling effects of multiple physical fields (thermo, electric, magnetic and elastic) is presented. By introducing an eigenstrain corresponding to the thermo-electro-magnetic-elastic effect, the complex multi-field coupling problem can be reduced to a formal in-plane elasticity problem for which an exact closed form solution is available. The present three-phase model can be applied to fiber/interphase/matrix composites, such that a lot of interesting thermo-electro-magnetism and stress coupling phenomena induced by the interphase layer are revealed. The present model can also be applied to fiber/matrix composites, in terms of which a generalized self-consistent method (GSCM) is developed for predicting the effective properties of piezoelectric–magnetic fiber reinforced composites. The effective piezoelectric, piezomagnetic, thermoelectric and magnetoelectric moduli can be expressed in compact explicit formulae for direct references and applications. A comparison of the predictions by the GSCM with available experimental data is presented, and interesting magnification effects and peculiar product properties are discussed. As a theoretical basis for the GSCM, the equivalence of the three sets of different average field equations in predicting the effective properties are proved, and this fact provides a strong evidence of mathematical rigor and physical realism in the formulation.     

Material instability-induced extreme damping in composites: A computational study

We investigate the effective viscoelastic performance of particle-reinforced composite materials whose particulate phase undergoes a material instability resulting in temporarily non-positive-definite elastic moduli. Recent experiments have shown that phase transitions in geometrically-constrained composite phases (such as in particles embedded in a stiff matrix) can lead to stable non-positive-definite elastic moduli, and they hinted at strong damping increases that can be achieved from such metastable composite phases. All previous theoretical efforts to explain such phenomena have used simplistic one-dimensional models or they were based on composite bounds and specific two-phase solids. Here, we study particle–matrix composites with periodic randomized particle dispersion. A finite element discretization is used in combination with a sophisticated nonlinear solver in order to perform the numerous calculations in a feasible amount of computing time. Our computational analysis shows that stable non-positive-definite inclusion moduli can indeed lead to extreme damping increases (i.e. greatly exceeding the intrinsic damping of each composite phase) and that such extreme damping arises from a shift in microstructural mechanisms.     

The effective elastic moduli of columnar composites made of cylindrically anisotropic phases with rough interfaces

The present work aims to determine the effective elastic moduli of a composite having a columnar microstructure and made of two cylindrically anisotropic phases perfectly bonded at their interface oscillating quickly and periodically along the circular circumferential direction. To achieve this objective, a two-scale homogenization method is elaborated. First, the micro-to-meso upscaling is carried out by applying an asymptotic analysis, and the zone in which the interface oscillates is correspondingly homogenized as an equivalent interphase whose elastic properties are analytically and exactly determined. Second, the meso-to-macro upscaling is accomplished by using the composite cylinder assemblage model, and closed-form solutions are derived for the effective elastic moduli of the composite. Two important cases in which rough interfaces exhibit comb and saw-tooth profiles are studied in detail. The analytical results given by the two-scale homogenization procedure are shown to agree well with the numerical ones provided by the finite element method and to verify the universal relations existing between the effective elastic moduli of a two-phase columnar composite.     

Effective pressure-sensitive elastoplastic behavior of particle-reinforced composites and porous media under isotropic loading

The composite under investigation consists of an elastoplastic matrix reinforced by elastic particles or weakened by pores. The material forming the matrix is pressure-sensitive. The Drucker–Prager yield criterion and a one-parameter non-associated flow rule are employed to formulate the yield behavior of the matrix. The objective of this work is to estimate the effective elastoplastic behavior of the composite under isotropic tensile and compressive loadings. To achieve this objective, the composite sphere assemblage model of Hashin [Z. Hashin, The elastic moduli of heterogeneous materials, ASME J. Appl. Mech. 29 (1962) 143–150] is used. Exact solutions are thus derived as estimations for the effective secant and tangent bulk moduli of the composite. The effects of the loading modes and phase properties on the effective elastoplastic behavior of the composite are analytically and numerically evaluated.     

Effective elastic properties of matrix composites with transversely-isotropic phases

The present work addresses the problem of calculation of the macroscopic effective elastic properties of composites containing transversely isotropic phases. As a first step, the contribution of a single inhomogeneity to the effective elastic properties is quantified. Relevant stiffness and compliance contribution tensors are derived for spheroidal inhomogeneities. The limiting cases of spherical, penny-shaped and cylindrical shapes are discussed in detail. The property contribution tensors are used to derive the effective elastic moduli of composite materials formed by transversely isotropic phases in two approximations: non-interaction approximation and effective field method. The results are compared with elastic moduli of quasi-random composites.     

On the thermostatics of composite materials

The problem of determining overall thermoelastic moduli of some solid composites is discussed. The phases may be arbitrarily anisotropic. One phase is required to be a matrix and the remainder are required to be aligned ellipsoidal inclusions. The volume concentrations are arbitrary. Some exact results are obtained for a binary composite. In the general case the self-consistent method is used to estimate the overall moduli. The general results are shown to reduce to those known for an isotropic dispersion of spheres.     

功能梯度界面相对周期分布纤维增强复合材料反平面剪切的影响

基于复变函数理论和边界配点法,探索了功能梯度界面相在周期均匀分布纤维增强复合材料反平面剪切问题中所起的作用。由于纤维在复合材料基体中的周期分布是均匀的,将其简化成含一功能梯度界面相夹杂的方形单胞。采用分层均匀化方法,将功能梯度界面相离散成K层界面层。当K足够大时,每个界面层可视为匀质材料,同时计算得到的复合材料宏观性能趋于定值。根据单胞内的基体、界面相和夹杂的几何外形特点,分别给出复势函数的级数形式,这些复势函数在各组分的相邻界面应满足连续性条件,在单胞的外边界应满足周期性边界条件和远场加载条件,从而确定复势函数中的待定系数,进而根据平均场理论确定复合材料有效模量。主要探讨了夹杂体积分数、各组分模量、功能梯度界面相的模量渐变形式等因素对纤维增强复合材料性能的影响。结果表明：不管基体模量相对于夹杂模量是大还是小,都有对应的界面相模量渐变形式可使夹杂周围的等效应力集中系数减小;另外还发现仅当夹杂模量较大时,功能梯度界面相模量的变化方式对复合材料有效模量产生不可忽视的影响。     

Equivalent inclusions in micromechanics with interface energy effect

In order to apply classical micromechanics in predicting the effective properties of nanocomposites incorporating interface energy, a concept of equivalent inclusion(EI) is usually adopted. The properties of EI are obtained by embedding a single inclusion with the interface into an infinite matrix. However, whether such an EI is universal for different micromechanics-based methods is rarely discussed in the literature. In this paper, the interface energy theory is used to study the applicability of the above mentioned EI. It is found that some elastic properties of the EI are related only to the properties of the inclusion and the interface, whereas others are also related to the properties of the matrix. The former properties of the EI can be applied to both the classical Mori-Tanaka method(MTM) and the generalized self-consistent method(GSCM). However, the latter can be applied only to the MTM. Two kinds of new EIs are proposed for the GSCM and used to estimate the effective mechanical properties of nanocomposites.     

Effect of an inhomogeneous interphase zone on the bulk modulus and conductivity of a particulate composite

A model is presented of a particulate composite containing spherical inclusions, each of which are surrounded by a localized region in which the elastic moduli vary smoothly with radius. This region may represent an interphase zone in a composite, or the transition zone around an aggregate particle in concrete, for example. An exact solution is derived for the displacements and stresses around a single inclusion in an infinite matrix, subjected to a far-field hydrostatic compression, and is then used to derive an approximate expression for the effective bulk modulus of a material containing a random dispersion of these inclusions. The analogous conductivity (thermal, electrical, etc.) problem is then discussed, and it is shown that the expression for the normalized effective conductivity corresponds exactly to that for the normalized effective bulk modulus, if the Poisson ratios of both phases are set to zero.     

The effective properties of piezoelectric composite materials with transversely isotropic spherical inclusions

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On a full-strength juncture between an isotropic matrix and an orthotropic inclusion under a triaxial load

The possibility exists for the full-strength state of the juncture between an isotropic medium and an orthotropic inclusion when the phases are in ideal contact and the stresses are tensile (compressive). It is found that an ellipsoid, whose semiaxes depend heavily on the elastic characteristics of the matrix and inclusion and the parameters of external loading, is such a form. A system of transcendental equations is obtained to search for the unknown semi-axes. Previous data confirm the results obtained. Numerical investigations are performed, and interrelations are established between geometrical parameters and loading conditions and the properties of the phases for transversally isotropic and orthotropic inclusions. S. P. Timoshenko Institute of Mechanics, National Academy of Sciences of Ukraine, Kiev. Translated from Prikladnaya Mekhanika Vol. 36, No. 1, pp. 95–102, January, 2000     

Micromechanics predictions of the effective moduli of magnetoelectroelastic composite materials

In this paper, the self-consistent, generalized Mori–Tanaka and dilute micromechanics theories are extended to study the coupled magnetoelectroelastic composite materials. The heterogeneous inclusion problem of magnetoelectroelastic behavior is formulated in terms of five interaction tensors related to the Green's functions for an infinite three-dimensional transversely isotropic magnetoelectroelastic solid. These tensors are then used to predict the effective moduli of the magnetoelectroelastic solid based on the self-consistent, Mori–Tanaka and the dilute approaches. Numerical results are obtained for various types of inclusions. These results are employed to study the effects of the inclusion properties, such as moduli, volume fractions, shapes, etc., on the effective moduli of magnetoelectroelastic composites, in particular, the related magnetic properties. The results obtained using the self-consistent model, the generalized Mori–Tanaka's model and the dilute approach are compared with the existing experimental and theoretical results.     

Electromechanical response of (3–0, 3–1) particulate,fibrous, and porous piezoelectric composites with anisotropic constituents: A model based on the homogenization method

An analytical framework based on the homogenization method has been developed to predict the effective electromechanical properties of periodic, particulate and porous, piezoelectric composites with anisotropic constituents. Expressions are provided for the effective moduli tensors of n-phase composites based on the respective strain and electric field concentration tensors. By taking into account the shape and distribution of the inclusion and by invoking a simple numerical procedure, solutions for the electromechanical properties of a general anisotropic inclusion in an anisotropic matrix are obtained. While analytical forms are provided for predicting the electroelastic moduli of composites with spherical and cylindrical inclusions, numerical evaluation of integrals over the composite microstructure is required in order to obtain the corresponding expressions for a general ellipsoidal particle in a piezoelectric matrix. The electroelastic moduli of piezoelectric composites predicted by the analytical model developed in the present study demonstrate excellent agreement with results obtained from three-dimensional finite-element models for several piezoelectric systems that exhibit varying degrees of elastic anisotropy.     

New exact results for the effective electric, elastic, piezoelectric and other properties of composite ellipsoid assemblages

In this paper we present a unified treatment of composite ellipsoid assemblages in the setting of uncoupled phenomena like conductivity and elasticity and coupled phenomena like thermoelectricity and piezomagnetoelectricity. The building block of this microgeometry is a confocal ellipsoidal particle consisting of a (possibly void) core and a coating. All space is filled up with such units which have different sizes but possess the same aspect ratios. The confocal ellipsoids may have the same orientation in space or may be randomly oriented. The resulting microgeometry simulates two-phase composites in which the reinforcing components are short fibers or elongated particles. Our main interest is in obtaining information of an exact nature on the effective moduli of this microgeometry whose effective tensor symmetry structure depends on the packing mode of the coated ellipsoids. This information will sometimes be complete like the full effective thermoelectric tensor of an assemblage which contains aligned ellipsoids in which the coating is isotropic and the core is arbitrarily anisotropic. In the majority of the cases however the maximum achievable exact information will be only partial and will appear in the form of certain exact relations between the effective moduli of the microgeometry. These exact relations are obtained from exact solutions for the fields in the microstructure for a certain set of loading conditions. In all the considered cases an isotropic coating can be combined with a fully arbitrary core. This covers the most important physical case of anisotropic fibers in an isotropic matrix. Allowing anisotropy in the coating requires the fulfillment of certain constraint conditions between its moduli. Even though in this case the presence of such constraint conditions may render the anisotropic coating material hypothetical, the value of the derived solutions remains since they still provide benchmark comparisons for approximate and numerical treatments. The remarkable feature of the general analysis which covers all treated uncoupled and coupled phenomena is that it is developed solely on the basis of potential solutions of the conduction problem in the same microgeometry.     

A unified model for piezocomposites with non-piezoelectric matrix and piezoelectric ellipsoidal inclusions

In this paper, the closed-form solutions of the electroelastic Eshelbys tensors of a piezoelectric ellipsoidal inclusion in an infinite non-piezoelectric matrix are obtained via the Greens function technique. Based on the generalized Budianskys energy-equivalence framework and the closed-form solutions of the electroelastic Eshelbys tensors, a unified model for multiphase piezocomposites with the non-piezoelectric matrix and piezoelectric inclusions is set up. The closed-form solutions of the effective electroelastic moduli of piezocomposites are also obtained. The unified model has a rigorous but simple form, which can describe the multiphase piezocomposites with different connectivities, such as 0–3, 1–3, 2–2, 2–3, 3–3 connectivities, etc. It can also describe the effects of non-interaction and interaction among the inclusions. As examples, the closed-form solutions of the effective electroelastic moduli are given by means of the dilute solution for the 0–3 piezocomposite with transversely isotropic piezoelectric spherical inclusions and by means of the dilute solution and the Mori–Tanakas method for the 1–3 piezocomposite with two kinds of transversely isotropic piezoelectric cylindrical inclusions. The predicted results are compared with experimental data, which shows that the theoretical curves calculated by means of the Mori–Tanakas method agree quite well with the experimental values, but the theoretical curves obtained by the dilute solution agree well with the experimental values only when the volume fraction of the ceramic inclusion is less than 0.3. The results in this paper can be used to analyze and design the multiphase piezocomposites.