| 2-氨基-3-氰基-4-芳基-6-二茂铁基吡啶的合成 |
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| 引用本文： | 孙晶,张丽丽,柳冬梅,高卉,颜朝国.2-氨基-3-氰基-4-芳基-6-二茂铁基吡啶的合成[J].有机化学,2008,28(9):1616-1619. |
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| 作者姓名： | 孙晶 张丽丽 柳冬梅 高卉 颜朝国 |
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| 作者单位： | 扬州大学化学化工学院,扬州,225002 |
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| 摘 要： | 以乙酰二茂铁、芳香醛、丙二腈为原料, 在乙酸铵存在下以乙醇为溶剂, 采用一锅煮的方法合成了8个2-氨基-3-氰基-4-芳基-6-二茂铁基吡啶化合物, 产率中等. 并通过X射线衍射分析确证产物4e的结构.
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| 关 键 词： | 多组分反应 一锅煮反应 二茂铁 丙二腈 芳香醛 吡啶 |
| 收稿时间： | 2008-1-22 |
| 修稿时间： | 2008-3-7 |
One-Pot Synthesis of 2-Amino-3-cyano-4-[(un)substituted phenyl]-6-ferrocenylpyridines |
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| SUN, Jing,ZHANG, Li-Li,LIU, Dong-Mei,GAO, Hui,YAN, Chao-Guo.One-Pot Synthesis of 2-Amino-3-cyano-4-[(un)substituted phenyl]-6-ferrocenylpyridines[J].Chinese Journal of Organic Chemistry,2008,28(9):1616-1619. |
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| Authors: | SUN Jing ZHANG Li-Li LIU Dong-Mei GAO Hui YAN Chao-Guo |
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| Institution: | (College of Chemistry & Chemical Engineering, Yangzhou University, Yangzhou 225002) |
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| Abstract: | One-pot multicomponent reactions of acetylferrocene, (un)substituted benzaldehyde and malononitrile in refluxing ethanol with ammonium acetate as a catalyst gave 2-amino-3-cyano-4- (un)substituted phenyl]-6-ferrocenylpyridines in moderate yields. Eight ferrocenyl pyridine derivatives were prepared efficiently and one single crystal structure of 4e was determined. |
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| Keywords: | multicomponent reaction one-pot reaction ferrocene malononitrile benzaldehyde pyridine |
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