Binary mixtures of cyclohexanone, 2-butanone, 1,4-dioxane and 1,2-dimethoxyethane

Densities and sound velocities of binary mixtures of cyclohexanone, 2-butanone, 1,4-dioxane and 1,2-dimethoxyethane were measured at 298.15 K and also the densities at 303.15 K. Excess volumes were determined from densities. Isentropic compressibilities were determined from densities and sound velocities, and excess thermal expansion factors were determined from excess volumes of two temperatures. Excess isothermal compressibilities and excess isochoric heat capacities were then estimated using excess isobaric heat capacities previously reported. Excess volumes and excess isentropic and isothermal compressibilities were negative except for cyclohexanone+1,4-dioxane system. This revised version was published online in August 2006 with corrections to the Cover Date.     

等容条件下H2O-CO2-CH4混合流体的高温拉曼光谱就位分析

 以合成包裹体作为腔体，用显微激光拉曼探针就位分析了H₂O-CO₂-CH₄混合流体的高温特性。研究结果表明，在高温下，CH₄和CO₂相互之间对各自拉曼光谱的影响不大，水分子对它们的拉曼峰有比较大的影响。在等容条件下，流体均一前，随着温度的升高，水分子的氢键几乎呈线性减少，均一为气相的流体，水分子伸缩振动拉曼峰的变化与一般气体变化相似；随着温度升高，体系压力的增加，最大峰频率呈很微小的降低趋势。均一为液相的流体中的水分子，在均一温度时，氢键变化发生了转折，均一后流体中水分子的氢键受温度的影响比均一前明显要小，在测量的最高温度520 ℃，水分子存在着一定的氢键作用。一直到拉曼光谱测量的最高温度580 ℃还未均一的流体，液相中水分子存在比较强的氢键作用。     

Analysis of a system related to a model for phase transitions in dissipative isochoric thermoviscoelastic materials

We analyze a highly nonlinear system of partial differential equations related to a model solidification and/or melting of thermoviscoelastic isochoric materials with the possibility of motion of the material during the process. This system consists of an internal energy balance equation governing the evolution of temperature, coupled with an evolution equation for a phase field whose values describe the state of material and a balance equation for the linear moments governing the material displacements. For this system, under suitable dissipation conditions, we prove global existence and uniqueness of weak solutions. Copyright © 2016 John Wiley & Sons, Ltd.     

Hydrogels with Dual Thermoresponsive Mechanical Performance

Dual thermoresponsive chemical hydrogels, combining poly(N‐isopropylacrylamide) side‐chains within a poly(N‐acryloylglycinamide) network, are designed following a simple and versatile procedure. These hydrogels exhibit two phase transitions both at low (upper critical solution temperature) and high (lower critical solution temperature) temperatures, thereby modifying their swelling, rheological, and mechanical properties. These novel thermo‐schizophrenic hydrogels pave the way for the development of thermotoughening wet materials in a broad range of temperatures.     

Thermophysical properties of 1-hexanol over the temperature range from 303 K to 503 K and at pressures from the saturation line to 400 MPa

Isobaric thermal expansivities, _P(T,p), of 1-hexanol have been measured in a pressure-controlled scanning calorimeter from just above the saturation vapour pressure to 400 Mpa at temperatures from 302.6 K to 503.15 K. The specific volume isotherm, v(T_R,p), at T_R=302.6 K has been derived from measurements of isothermal compressibilities up to 400 MPa and from the specific density at atmospheric pressure. Specific volumes, isothermal compressibilities, thermal pressure coefficients, and isobaric and isochoric heat capacities for the whole pressure and temperature range are derived from these data and from literature data on the saturation vapour pressures and on the isobaric heat capacities at atmospheric or saturation vapour pressure.     

压缩氘氚球的热核燃烧特性研究

本文利用LARED-S程序模拟了等密度和等压力条件下压缩氘氚球的热核反应燃烧过程.对于等密度模型,模拟了两个具体算例,与国外计算结果进行了比较,验证了程序的可靠性.对于等压力模型,利用数值模拟给出了热核反应燃烧与压缩氘氚球初始状态之间的关系曲线,分析发现,氘氚装量、压力和主燃料密度的增加有利于提高热核反应放能和燃耗,中心热斑的温度和面密度分别达到70—80 MK和3—4 kg·m^-2时热核反应才有显著的放能,提高主燃料密度,可以适当放宽对中心热斑的点火要求.最后对实际点火靶进行了数值模拟并且与等压力模拟计算结果进行了比较分析. 关键词： 压缩氘氚球 等密度模型 等压力模型 热核反应聚变     

爆轰等容终点的四组理论解

用Hamilton原理描述爆轰产物粒子运动并最终耗散为热的过程,证明爆轰过程反应区有四组理论解可以达到等容终点,即反应区的多变量解、等温过程解、等压过程解、等容过程解;修正了经典的ZND模型由于忽略输运效应而认为爆轰过程不可能达到等容终点的结论。本文结果与实验结果较为一致。     

Thermodynamic Properties of Aqueous Solution of 2-Isopropoxyethanol at 25°C

Excess enthalpy, excess isobaric heat capacity, density, and speed of sound for aqueous 2-isopropoxyethanol solutions were measured at 25°C. The density was also measured at 20°C. The excess enthalpy was –800 J-mol^–1 at the minimum (mole fraction alcohol, x = 0.2), showing that the hydrogen bonds formed between unlike molecules are stronger than those in both pure liquid states. The excess volume also was large and negative, more than –1.2 cm³-mol^–1 at the minimum (x = 0.35). Excess isentropic and isothermal compressibilities are extremely negative. These results suggest that breaking the hydrogen bond network in water and forming the stronger hydrogen bonds between unlike molecules reduces the volume of the solution and makes the solution less compressible. The excess isobaric heat capacity is positive and large, up to 10 J-K^–1-mol^–1 and shows anomalous behavior in the neighborhood of x = 0.15.     

压缩氘氚球的热核燃烧特性研究

本文利用LARED-S程序模拟了等密度和等压力条件下压缩氘氚球的热核反应燃烧过程.对于等密度模型,模拟了两个具体算例,与国外计算结果进行了比较,验证了程序的可靠性.对于等压力模型,利用数值模拟给出了热核反应燃烧与压缩氘氚球初始状态之间的关系曲线,分析发现,氘氚装量、压力和主燃料密度的增加有利于提高热核反应放能和燃耗,中心热斑的温度和面密度分别达到70—80 MK和3—4 kg·m^-2时热核反应才有显著的放能,提高主燃料密度,可以适当放宽对中心热斑的点火要求.最后对实际点火靶进行了数值模拟并且与等压力模拟计算结果进行了比较分析.