Measurement of interdiffusion in polymeric materials by applying Raman spectroscopy

Raman spectroscopy was evaluated regarding its specific value in terms of detection of interdiffusion in two-component injection molded parts. Two-component injection molded parts made of four material combinations chosen from polypropylene, styrene based thermoplastic elastomer, polycarbonate, polystyrene and polymethyl methacrylate produced by varying melt temperatures of the second component T_M2 were investigated.In principle, Raman spectroscopy was found to be a powerful tool to detect interdiffusion. However, some restrictions arise. These include spatial resolution limit and detection limit. Interdiffusion lengths ranging from below 1 μm–3 μm were determined. Either an increase, a decrease or no change of the interdiffusion length for increasing T_M2 was detected. The interdiffusion lengths were compared with the stress and elongation at break obtained by tensile tests. No distinct correlation of interdiffusion length and the mechanical properties was found. However, a high T_M2 provoked an increase in the stress and elongation at break.     

Adhesion and friction of an elastic half-space in contact with a slightly wavy rigid surface

The paper deals with the estimation of the pressure distribution, the shape of contact and the friction force at the interface of a flat soft elastic solid moving on a rigid half-space with a slightly wavy surface. In this case an unsymmetrical contact is considered and justified with the adhesion hysteresis. For soft solids as rubber and polymers the friction originates mainly from two different contributions: the internal friction due to the viscoelastic properties of the bulk and the adhesive processes at the interface of the two solids. In the paper the authors focus on the latter contribution to friction. It is known, indeed, that for soft solids, as rubber, the adhesion hysteresis is, at least qualitatively, related to friction: the larger the adhesion hysteresis the larger the friction. Several mechanisms may govern the adhesion hysteresis, such as the interdigitation process between the polymer chains, the local small-scale viscoelasticity or the local elastic instabilities. In the paper the authors propose a model to link, from the continuum mechanics point of view, the friction to the adhesion hysteresis. A simple one-length scale roughness model is considered having a sinusoidal profile. For partial contact conditions the detached zone is taken to be a mode I propagating crack. Due to the adhesion hysteresis, the crack is affected by two different values of the strain energy release rate at the advancing and receding edges respectively. As a result, an unsymmetrical contact and a friction force arise. Additionally, the stability of the equilibrium configurations is discussed and the adherence force for jumping out of contact and the critical load for snapping into full contact are estimated.     

Improving copper plating adhesion on glass using laser machining techniques and areal surface texture parameters

Glass is a promising substitute substrate material being evaluated for electronic packaging technology. Improving the electroless copper plated layer adhesion of the glass is one of the most important considerations for development of the technology. An excimer laser (248 nm) was used for structured texturing of glass surfaces (to improve adhesion) by changing mask dimensions, laser operating parameters and overlapping pitch spacing, and therefore producing a range of micro-scale features. Electroless plated copper adhesion strength was assessed using quantitative scratch testing, demonstrating that micro-patterned structures can significantly improve copper/glass adhesion. New ISO 25178 Part 2 areal surface texture parameters were used to characterise the surface roughness of ablated glass surfaces, and correlated to the scratch testing results. Highly correlated parameters were identified that could be used as predictive surface design tools, directly linking surface topography to adhesion performance, without the need for destructive adhesion quantification via scratch testing.     

The effects of shear on delamination in layered materials

The effect of transverse shear on delamination in layered, isotropic, linear-elastic materials has been determined. In contrast to the effects of an axial load or a bending moment on the energy-release rate for delamination, the effects of shear depend on the details of the deformation in the crack-tip region. It therefore does not appear to be possible to deduce rigorous expressions for the shear component of the energy-release rate based on steady-state energy arguments or on any type of modified beam theory. The expressions for the shear component of the energy-release rate presented in this work have been obtained using finite-element approaches. By combining these results with earlier expressions for the bending-moment and axial-force components of the energy-release rates, the framework for analyzing delamination in this type of geometry has been extended to the completely general case of any arbitrary loading. The relationship between the effects of shear and other fracture phenomena such as crack-tip rotations, elastic foundations and cohesive zones are discussed in the final sections of this paper.     

Adhesion of viscoelastic bodies

The influence of surface energy on the contact between viscoelastic bodies is investigated. An equation is derived for its effect upon the contact zone after reaching the equilibrium position. As an example of an application, the adhesion of a viscoelastic standard solid, which may be considered as a model of the mechanical properties of living cells, is described.     

Detachment of a rigid solid from an elastic wavy surface: Theory

The mechanics of detachment between a wavy elastic half space and a rigid solid is considered. Solutions for the axisymmetric problem of a rigid sphere and the plane strain problem of a rigid cylinder detaching from a wavy surface are developed. The interacting solids are taken to be in complete contact over a finite area initially. It is shown that the surface waviness makes the detachment process unstable, with the interface separating in alternating stable and unstable segments. Each unstable segment dissipates mechanical energy, leading to an increase in the total work of separation compared to that of a flat surface. Further, waviness causes the maximum separation force or the pull-off force to increase during detachment, resulting in an apparent toughening of the interface. This mechanism provides an alternative explanation to the experimental observations in the literature that roughness can sometimes lead to increase in pull-off force. It also illustrates the role of roughness in the attachment capability of several insect feet possessing soft pads. The basic solution presented here can be used to analyze the detachment of surfaces with multiple scale roughness as well. The solution also suggests strategies to improve reversible adhesion of a soft material by designing optimal surface topographies.     

Synthese de Nouveaux Derives Phosphones a Chaine Perfluoree et Leurs Proprietes Adhesives Sur Acier

Ce mémoire décrit la synthèse de phosphonates comportant une chaîne perfluorée. Ces composés sont obtenus par la télomérisation d'allylphosphonates de dialkyle en présence d'un agent de transfert fluoré de type mercaptan. Ensuite, nous employons deux méthodes de déalkylation menant sélectivement soit au monoacide soit au diacide phosphonique. Tous ces produits comprenant une extrémité de chaîne phosphonée, sous forme acide ou ester, ont été caractérisés et leur adhésion respective sur des plaques d'acier est étudiée. Ces tests montrent que le monoacide phosphonique est un excellent promoteur d'adhésion et qu'il est aussi efficace que le diacide. This article describes the synthesis of phosphonic derivatives bearing a perfluorinated chain. These compounds have been synthetized by telomerization of dialkyl allylphosphonate with a fluorinated transfer agent type mercaptan. Then two methods of dealkylation leading selectively were used to mono or to diacid phosphonic moieties. All the products bearing phosphonic end-groups, more or less acidic, have been characterized and their own adhesion on steel plates is studied. These tests show that phosphonic monoacid is an excellent adhesion promoter on steel, as efficient as the diacid compound.     

TiO2/activated carbon fibers photocatalyst: Effects of coating procedures on the microstructure, adhesion property, and photocatalytic ability

In order to more easily separate TiO₂ photocatalyst from the treated wastewater, TiO₂ film was immobilized on the surface of activated carbon fibers (ACFs) by employing two kinds of coating procedures, dip-coating, and hydrothermal treatment. The effects of coating procedures on microstructure of TiO₂-coated ACFs (TiO₂/ACFs), such as morphology, porous property, crystal structure, and light absorption characteristics were investigated in detail. The adhesion property between TiO₂ film and ACFs was evaluated by ultrasonic vibration, and the photocatalytic activity of TiO₂/ACFs was tested by the photocatalytic decoloration of methylene blue solution. The results show that hydrothermal treatment presented many advantages to obtain high-performance TiO₂/ACFs photocatalyst in comparison with dip-coating. Hydrothermal treatment could improve the binding property between TiO₂ films and ACFs, which endowed the as-obtained TiO₂/ACFs photocatalyst with improved reusable performance, and TiO₂/ACFs synthesized by hydrothermal treatment presented higher photocatalytic activity.     

骨髓基质干细胞在等离子体处理PEGDA基凝胶表面的黏附和增殖

通过低温等离子体技术对聚乙二醇双丙烯酸酯(PEGDA)/甲基丙烯酸β-羟乙酯(HEMA)共聚物水凝胶生物材料进行表面改性,以骨髓基质干细胞(BMSc)为细胞模型,考察了细胞在等离子体表面改性前后的水凝胶材料的黏附和增值行为,材料的表面性能通过 X 射线光电子能谱、接触角和扫描电镜进行表征.研究结果表明,材料表面经氩等离...     

丝网印刷法制备高催化活性对电极

对电极在染料敏化太阳能电池（DSCs）中主要起催化氧化还原反应及收集电荷的作用,铂对电极常用的制备方法为磁控溅射法,但其成本较高,制备条件苛刻. 本文通过引入低成本的表面活性剂Span-85,所制得的铂对电极的附着力、透光率和均匀性显著改善,实现了面积可控,与两步浸泡法和旋涂热解法制备的对电极在DSCs中的光电转换效率分别为7.30%,6.96%和7.03%. 紫外-可见吸收光谱、扫描电镜和附着力测试等结果表明,（1）添加表面活性剂有利于增加附着力及改善透光率和均匀性;（2）使用该法制备的Pt/FTO对电极的透光率与两步浸泡法制作的相同,且铂粒子分布更加均匀. 电化学阻抗图谱、塔菲尔极化曲线和循环伏安曲线结果表明,丝网印刷方法制备的Pt/FTO对电极具有更加优异的催化性能,且该法更有利于降低其生产成本和大规模生产.