全文获取类型
收费全文 | 29篇 |
免费 | 0篇 |
国内免费 | 736篇 |
专业分类
化学 | 743篇 |
数学 | 4篇 |
物理学 | 18篇 |
出版年
2013年 | 17篇 |
2012年 | 3篇 |
2007年 | 2篇 |
2005年 | 1篇 |
2004年 | 5篇 |
2003年 | 17篇 |
2002年 | 11篇 |
2001年 | 40篇 |
2000年 | 23篇 |
1999年 | 21篇 |
1998年 | 9篇 |
1997年 | 45篇 |
1996年 | 39篇 |
1995年 | 46篇 |
1994年 | 32篇 |
1993年 | 34篇 |
1992年 | 35篇 |
1991年 | 54篇 |
1990年 | 49篇 |
1989年 | 61篇 |
1988年 | 35篇 |
1987年 | 63篇 |
1986年 | 33篇 |
1985年 | 39篇 |
1984年 | 32篇 |
1983年 | 19篇 |
排序方式: 共有765条查询结果,搜索用时 46 毫秒
1.
2.
《Composite Interfaces》2013,20(1):75-94
Interfacial debonding behavior is studied for unidirectional fiber reinforced composites from both experimental and analytical viewpoints. A new type of two-dimensional unidirectional model composite is prepared using 10 boron fibers and transparent epoxy resin with two levels of interfacial strength. In situ observation of the internal mesoscopic fracture process is carried out using the single edge notched specimen under static loading. The matrix crack propagation, the interfacial debonding growth and the interaction between them are directly observed in detail. As a result, the interfacial debonding is clearly accelerated in specimens with weakly bonded fibers in comparison with those with strongly bonded fibers. Secondary, three-dimensional finite element analysis is carried out in order to reproduce the interfacial debonding behavior. The experimentally observed relation between the mesoscopic fracture process and the applied load is given as the boundary condition. We successfully evaluate the mode II interfacial debonding toughness and the effect of interfacial frictional shear stress on the apparent mode II energy release rate separately by employing the present model composite in combination with the finite element analysis. The true mode II interfacial debonding toughness for weaker interface is about 0.4 times as high as that for a stronger interface. The effect of the interfacial frictional shear stress on the apparent mode II energy release rate for the weak interface is about 0.07 times as high as that for the strong interface. The interfacial frictional shear stress and the coefficient of friction for weak interface are calculated as 0.25 and 0.4 times as high as those for strong interface, respectively. 相似文献
3.
《Composite Interfaces》2013,20(6):629-650
Using thermogravimetric analysis (TGA), the thermal behavior of sisal fibers and sisal/polyester composites, fabricated by resin transfer molding (RTM), has been followed. Chemical treatments have been found to increase the thermal stability, which has been attributed to the resultant physical and chemical changes. Scanning electron microscopy (SEM) and infrared (FT-IR) studies were also performed to study the structural changes and morphology in the sisal fiber during the treatment. The kinetic studies of thermal degradation of untreated and treated sisal fibers have been performed using Broido method. In the composites, as the fiber content increases, the thermal stability of the matrix decreases. The treated fiber reinforced composites have been found to be thermally more stable than the untreated derivatives. The increased thermal stability and reduced moisture behavior of treated composites have been correlated with fiber/matrix adhesion. 相似文献
4.
《Composite Interfaces》2013,20(4):319-336
Not all steel fiber reinforced concrete composites are equally effective in enhancing structural performance. Their mechanical behaviour strongly depends upon the reinforcement morphology as well as the properties of the interface lying between steel reinforcement and concrete matrix. Using bone-shaped short (BSS) steel fibers, instead of conventional straight short (CSS) steel fibers, to reinforce concrete has demonstrated their potential in improving toughness, ductility and energy absorbing capacity under impact significantly and simultaneously. Accomplishing a strong steel–concrete interface leads to a slight increase in composite strength but simultaneously to a significant decrease in its toughness. Due to the sensitivity of steel reinforced concrete performance on these complex geometric and material parameters, the development of a numerical tool capable of simulating accurately the composite mechanical behaviour and thus leading to optimized design solutions is desirable. The physical problem of the present work involves a typical concrete composite uniformly reinforced with steel fibers subjected to tensional loading. A micromechanical non-linear finite element formulation is utilized in order to predict the load transfer characteristics and the failure process. A linear material behaviour is assumed for the steel component; a non-linear multi-crack material response is used to describe concrete while a mix-mode bilinear behaviour is utilized for the interface providing separation of primary material phases. Numerical results are presented in terms of the global design parameters. The influence of the fiber end shape, the interface strength and the fiber volume fraction on the composite strength and toughness is addressed and consequently optimized design preferences arise. 相似文献
5.
1,1'-(六甲基三硅撑)双环戊二烯基二(对氯苯氧基)钛的合成及晶体结构 总被引:1,自引:0,他引:1
以1,3-二氯六甲基三硅烷相继与环戊二烯基钠、正丁基锂和四氯化钛作用合成了1,1'-(六甲基三硅撑)双环戊二烯基二氯化钛(1),1在氨基钠的存在下与对氯苯酚作用制得题目化合物(2)。通过元素分析、^1HNMR和MS鉴定了1与2的结构,并对2进行X射线结构分析确证了其结构。2的晶体属单斜晶系的P21/c空间群。晶胞参数:a=1.0746(3),b=2.4865(7),c=1.2568(2)nm; β=113.42(2)°;V=3.08137nm^3;Z=4,D0=1.305g·cm^-3。化合物中三个硅原子的桥链发生明显扭曲。通过氧原子中心原钛与苯环发生共轭,使整个分子形成共轭体系。 相似文献
6.
荧光黄的示波极谱特性研究及其在催化反应-示波极谱分析中的应用 总被引:2,自引:0,他引:2
在pH4.9HOAc-NaOAc缓冲溶液中, 荧光黄于-0.50V(vs.SCE)产生一灵敏的单扫描示波极谱波。在100℃弱碱性介质中, 铱(IV)对KIO~4氧化荧光黄这一反应具有强烈催化作用。本文研究了荧光黄的示波极谱行为及利用该催化反应测定痕量铱的各种影响因素,拟定了铱的催化反应-示波极谱分析新方法, 它们的检出限和测定范围分别为0.04ng/mL和0.08-8.0ng/mL。 相似文献
7.
8.
Min-qiangYu Zhi-pingZhou De-yueYan 《高分子科学》2004,(2):155-167
This work deals with the kinetics of co-condensation polymerization of AB2 and AB monomers, giving expressions of the two-dimensional molecular weight distribution function and the number/weight average molecular weights of the resulting copolymers. The two-dimensional molecular weight distribution depends on two indices, n and l, which are the respective numbers of AB2 and AB units in a copolymer species. The evolution of the two-dimensional weight and z distributions during the co-condensation polymerization has been evaluated systematically. Finally, the two-dimensional distribution was transformed into a one-dimensional molecular weight distribution with only one variable (the molecular weight of the products instead of the degree of polymerization). The calculated results show that the highly branched copolymer has a very broad molecular weight distribution when the co-condensation polymerization approaches completion. 相似文献
9.
10.
用X射线单晶衍射法测定了反-1,2-双[2'-(5'-苯基恶唑基)]乙烯(POEOP)的晶体结构,POEOP晶体属单斜晶系, 空间群为P2~1/C, a=0.8268(2), b=0.5977(2), c=1.6292(3)nm;β=100.55(2)°; v=0.7915nm~3; Z=2; d~x=1.319g/cm~3。POEOP分子具有中心对称性,它的两个苯环和两个恶唑环是彼此平行的, 但整个分子却稍有些扭曲成螺旋浆式构型。键长数据表明POEOP分子中苯环与恶唑环以及恶唑环与C'=C双键间均有很大程度共轭。 相似文献