全文获取类型
收费全文 | 462篇 |
免费 | 37篇 |
国内免费 | 48篇 |
专业分类
化学 | 182篇 |
晶体学 | 3篇 |
力学 | 68篇 |
综合类 | 4篇 |
数学 | 64篇 |
物理学 | 226篇 |
出版年
2024年 | 1篇 |
2023年 | 5篇 |
2022年 | 9篇 |
2021年 | 3篇 |
2020年 | 13篇 |
2019年 | 5篇 |
2018年 | 10篇 |
2017年 | 13篇 |
2016年 | 15篇 |
2015年 | 31篇 |
2014年 | 15篇 |
2013年 | 30篇 |
2012年 | 20篇 |
2011年 | 43篇 |
2010年 | 25篇 |
2009年 | 32篇 |
2008年 | 33篇 |
2007年 | 27篇 |
2006年 | 30篇 |
2005年 | 19篇 |
2004年 | 18篇 |
2003年 | 22篇 |
2002年 | 20篇 |
2001年 | 9篇 |
2000年 | 13篇 |
1999年 | 14篇 |
1998年 | 14篇 |
1997年 | 11篇 |
1996年 | 8篇 |
1995年 | 4篇 |
1994年 | 3篇 |
1993年 | 3篇 |
1992年 | 3篇 |
1991年 | 1篇 |
1990年 | 4篇 |
1989年 | 4篇 |
1988年 | 3篇 |
1987年 | 3篇 |
1986年 | 2篇 |
1985年 | 3篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1982年 | 2篇 |
1981年 | 1篇 |
1979年 | 1篇 |
排序方式: 共有547条查询结果,搜索用时 15 毫秒
1.
2.
壳模型计算表明,1/2+[411]出现于157Tm核的基态可能是由非轴对称形变造成的.但是新近从157Yb衰变纲图给出的157Tm低激发谱中,指认了一个建立在1/2+[411]带头上的基态转动带,并认为该带的性质是轴对称的,提取了该带的惯性参数与脱耦合参数.通过对奇ATm核1/2+[411]转动带的系统分析,强调了在157Tm核中非轴对称γ自由度效应的重要性. 相似文献
3.
We present two methods for the creation of two-particle entangled states of excitons in a coupled quantum dot system. The system contains two identical quantum dots that are coupled by an inter-dot hopping process. The manipulation of the system is succeeded by proper application of an external laser field. 相似文献
4.
Mark C. Veraar 《Proceedings of the American Mathematical Society》2007,135(5):1477-1486
In this paper we prove the equivalence of decoupling inequalities for stochastic integrals and one-sided randomized versions of the UMD property of a Banach space as introduced by Garling.
5.
Polycrystalline perovskite La0.67Ca0.33MnO3 was synthesized by a sol–gel method. Its adiabatic temperature change ΔTad induced by a magnetic field change was measured directly. At 268 K, near its Curie temperature TC, ΔTad of La0.67Ca0.33MnO3 induced by a magnetic field change of 2.02 T reaches 2.4 K. The latent heat Q and magnetic entropy change −ΔSM induced by a magnetic field change were calculated from the temperature dependence of ΔTad and zero-field heat capacity Cp. The maximum values of Q and −ΔSM in La0.67Ca0.33MnO3 induced by a magnetic field change of 2.02 T are 1.85 J g−1 and 6.9 J kg−1 K−1, respectively. The former is larger than the phase transition latent heat of heating or cooling, which is about 1.70 J g−1. 相似文献
6.
利用精密自动绝热热量计直接测定了配合物Zn(Phe)(NO3)2·H2O(s) (Phe:苯丙氨酸)在78-370 K温区的摩尔热容. 通过热容曲线的解析得到该配合物的起始脱水温度为, T0=(324.27±0.37) K. 将该温区的摩尔热容实验值用最小二乘法拟合得到摩尔热容(Cp, m)对温度(T)的多项式方程, 并且在此基础上计算出了它的舒平热容值和各种热力学函数值. 依据Hess定律, 通过设计热化学循环, 选择体积为100 mL浓度为2 mol·L-1 的盐酸作为量热溶剂, 利用等温环境溶解-反应热量计分别测定混合物{ZnSO4·7H2O(s)+2NaNO3(s)+L-Phe(s)}和{Zn(Phe)(NO3)2·H2O(s)+Na2SO4(s)}的溶解焓为, ⊿dH0m,1 =(69.42±0.05) kJ·mol-1, ⊿dH0 m,2 =(48.14±0.04) kJ·mol-1, 进而计算出该配合物的标准摩尔生成焓为, ⊿fH0m =-(1363.10±3.52) kJ·mol-1. 另外, 利用紫外-可见(UV-Vis)光谱和折光指数(refractiveindex)的测量结果检验了所设计的热化学循环的可靠性. 相似文献
7.
ZHANG Hui LU Jin-Feng ZHANG Shu-Fang TANG Ke ZHOU Zheng-Yu 《结构化学》2007,26(11):1373-1379
Adiabatic and vertical ionization potentials (IPs) and valence electron affinities (EAs) of alaninamide in gas phase have been determined using density functional theory (BLYP,B3LYP,B3P86) methods with 6-311++G(d,p) basis set,respectively. IPs and EAs of alaninamide in solutions have been calculated at the B3LYP/6-311++G(d,p) level. Five possible conformers of alaninamide and their charged states have been optimized employing density functional theory B3LYP method with 6-311++(d,p) basis set,respectively. 相似文献
8.
An efficient hybrid field solution to the general multilayer substrates transmission line problems with full shielded and half open cross-sectional geometry is presented by using the waveguide modes coupling and decoupling procedure in the spectral domain. Modal transverse transmission lines corresponding to the LSE and LSM modes are taken into account so that the Green's elements for the edge conditions can be derived by a simple iterative method. In this paper, we analyze not only the propagation constants and characteristic impedances but also the available transmission power capacity and power distribution of most commonly used structures. Normalized eigenmode power levels characterizing the propagation features are computed. 相似文献
9.
Low-temperature heat capacities of the solid compound NaCuAsO4 · 1.5H2O(s) were measured using a precision automated adiabatic calorimeter over a temperature range of T = 78 K to T = 390 K. A dehydration process occurred in the temperature range of T = 368-374 K. The peak temperature of the dehydration was observed to be TD = (371.828±0.146) K by means of the heat-capacity measurement. The molar enthalpy and entropy of the dehyperimental values of heat capacities for the solid(Ⅰ) and the solid-liquid mixture(Ⅱ) were respectively fitted to two polynomial equations by the least square method. The smoothed values of the molar heat capacities and the fundamental thermodynamic functions of the sample relative to the standard reference temperature 298.15 K were tabulated at an interval of 5 K. 相似文献
10.
摘要运用多参考微扰理论(Multireference MΦller-Plesset theory)计算了SSCH3垂直激发能及其S-C与S-S两种断键方式的绝热(Adiabatic)与非绝热(Diabatic)的基态和激发态势能曲线, 研究了在193nm激光作用下SSCH3的光解离过程, 理论计算值与实验值相符. 相似文献