Scanning tunnelling microscope studies of growth of RuO2（110） thin layer on Ru（0001）

This paper reports that the growth of RuO_x(110) thin layer growth on Ru(0001) has been investigated by means of scanning tunnelling microscope (STM). The STM images showed a domain structure with three rotational domains of RuO_x(110) rotated by an angle of 120℃. The as-grown RuO_x(110) thin layer is expanded from the bulk-truncated RuO_x(110) due to the large mismatch between RuO_x(110) and the Ru(0001) substrate. The results also indicate that growth of RuO_x(110) thin layer on the Ru(0001) substrate by oxidation tends first to formation of the Ru-O (oxygen) chains in the [001] direction of RuO_x(110).     

钌(Ⅱ)卟啉催化顺式二苯乙烯类化合物的选择性合成

由芳醛制得的腙盐在钌(Ⅱ)卟啉催化下发生自身偶合，以较高收率合成了二苯乙烯类化合物(～90％的顺式选择性)。部分中间体及目标化合物的结构经^1H NMR，^13C NMR和MS表征。     

Synthesis and Photochemical Properties of a New Substituted Phenol Covalently Linked to Ruthenium （Ⅱ） Tris-bipyridine Containing Four Ester Groups as Sensitizer

As photosensitizer for solar cell, a new ruthenium (Ⅱ) complex with four ester groups had been synthesized, in which a phenol substituted by {[(2-hydroxy-5-tert-butylbenzyl)(pyridyl-2-methyl)amino]methyl} is covalently linked to ruthenium (Ⅱ) tris-bipyridine. The structures of the new compounds were confirmed by NMR and ESI-MS spectra. The electrochemical and photochemical properties were also studied.     

钐(Ⅱ)类卡宾CH_3SmCH_2X(X=Cl、Br和Ⅰ)促进乙烯环丙烷化反应途径的理论研究(英文)

用密度泛函B3LYP方法研究了过渡金属钐类卡宾与乙烯的环丙烷化反应的机理。对三种不同的钐的SS试剂CH_3SmCH_2X(其中X=Cl、Br和Ⅰ)分别和CH_2CH_2反应的各反应物、中间体、过渡态和产物构型的全部结构几何参数进行了优化,用内禀反应坐标(IRC)计算和频率分析方法,对过渡态进行了验证。结果表明：CH_3SmCH_2X(其中X=Cl、Br和Ⅰ)与CH_2CH_2环丙烷化反应按亚甲基转移通道(通道A)和卡宾金属化通道(通道B)都可以进行,与锂类卡宾的反应机理相同,只是按亚甲基转移通道(通道A)进行反应较容易一些,而且此反应在较低的温度下就可以发生。     

对甲苯胺配位的羰基钌簇合物[HRu~3(CO)~1~0(C~7H~8N)]的合成及晶体结构

合成对甲苯胺配位的羰基钌簇合物.用IR,NMR和元素分析.X射线衍射等手段对此簇合物进行了结构表征.此谈合物含有钌-氢键,是瑞金属氢键.簇合物为单斜晶系,空间群为P2_1/C.晶胞参数:α=1.3816(2),b=0.9941(2),c=1.6005(2)nm,α=γ=90.00(0)°,β=98.39(l)°,V=2.1747(6)nm~3,Z=4,μ=20.70cm~(-1),D_c=2.11g/cm_3,F(000)=1320,最终偏差因子:R=0.0311.     

可溶于水的钉原子簇新体系催化丙烯和乙烯的醛化

1.前言 近年来,随着金属簇合物合成化学的迅速发展,已出现了一类可溶于水的金属簇合物。分子中含有55个金属原子的可溶于水的簇合物Au_(55)[Ph_2PC_6H_4SO_3Na)_12Cl_6已被合成和表征。金属簇合物被期待发挥特异的催化性能。用水作反应溶剂,好处很多。水不仅便宜易得,反应原料气无须经除水净化,反应体系简单,而且某些反应,例如水煤气变换和