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Structure phase transformation and equation of state of cerium metal under pressures up to 51 GPa 下载免费PDF全文
This study presents high pressure phase transitions and equation of states of cerium under pressures up to 51 GPa at room temperature. The angle-dispersive x-ray diffraction experiments are carried out using a high energy synchrotron x-ray source. The bulk moduli of high pressure phases of cerium are calculated using the Birch–Murnaghan equation. We discuss and correct several previous controversial conclusions, which are caused by the measurement accuracy or personal explanation. The c/a axial ratio of ε-Ce has a maximum value at about 29 GPa, i.e., c/a ≈ 1.690. 相似文献
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Effect of f-c hybridization on the $\gamma\to \alpha$ phase transition of cerium studied by lanthanum doping 下载免费PDF全文
Yong-Huan Wang 《中国物理 B》2022,31(8):87102-087102
The hybridization between the localized 4f level (f) with conduction (c) electrons in $\gamma $-Ce upon cooling has been previously revealed in single crystalline thin films experimentally and theoretically, whereas its influence on the $\gamma \to \alpha $ phase transition was not explicitly verified, due to the fact that the phase transition happened in the bulk-layer, leaving the surface in the $\gamma $ phase. Here in our work, we circumvent this issue by investigating the effect of alloying addition of La on Ce, by means of crystal structure, electronic transport and angle resolved photoemission spectroscopy measurements, together with a phenomenological periodic Anderson model and a modified Anderson impurity model. Our current researches indicate that the weakening of f-c hybridization is the major factor in the suppression of $\gamma \to \alpha $ phase transition by La doping. The consistency of our results with the effects of other rare earth and actinide alloying additions on the $\gamma \to \alpha $ phase transition of Ce is also discussed. Our work demonstrates the importance of the interaction between f and c electrons in understanding the unconventional phase transition in Ce, which is intuitive for further researches on other rare earth and actinide metals and alloys with similar phase transition behaviors. 相似文献
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