大孔苯乙烯—二乙烯苯共聚物孔结构稳定性的研究

通过溶剂处理和加热处理,研究了致孔剂种类、配比、用量及单体DVB中异构体组成对苯乙烯—二乙烯苯共聚物孔结构稳定性的影响,及其这种影响与共聚物交联度的关系。     

Birefringence Grating and Surface Grating in Azobenzene Polymer Liquid Crystal Films Investigated by Near—Field Optical method

The birefringence grating and the surface grating in azobenzene polymer liquid-crystal (Azo-PLC) films are studied by a near-fied scanning optical microscope.With laser irradiation,the refractive index change caused by birefringence and the sinusoidal surface profile are observed at the near-field transmittance image and the surface topography of the grating.The grating period and the peak-to-peak value of the sinusoidal surface profile are 0.8μm and 40nm,respectively.The maximum diffractive efficiency of the grating is 2% .The dynamic process of the grating formation is probed and analysed.The mass diffusion responsible for the formation of the surface grating due to the temperature rise is analysed.     

季碳的偶极-偶极弛豫分离——睾丸甾酮丙酸酯的~(13)C NMR弛豫时间的研究

本文提出了分离偶极—偶极驰豫的新方法 参数分离法。对于稳固的刚性分子,可以通过仲碳和叔碳弛豫时间的测量算出扩散系数,这不仅可以用于研究分子的动态特性。还可以用于计算季碳的偶极—偶极弛豫。文中报道了睾九甾酮丙酸酯驰豫的研究结果,表明参数分离法可对季碳的驰豫机制进行有效的研究。     

Polarized Emission of an Eu^3＋ Doped Azo-Polymer Waveguide

We investigate the polarized emission behaviour of an Eu^3 doped azo-polymer waveguide. Affected by the azobenzene groups in the photoinduced orientation process by the 532nm linearly polarized laser, the ligands were realigned orderly perpendicular to the direction of the orientation direction. This leads to the polarized absorption and emission of the waveguide in the orientation direction. By an m-line apparatus based on the prism coupling technique, two guided propagation modes were observed in the waveguide, and the refractive index at 650hm in TE polarizations is 1. 7505.     

Cu1-xZnxIr2S4系统的超导电性

具有常式尖晶石结构的CuIr2S4在约为230K时经历金属-绝缘体一级相变.研究发现,用Zn替代Cu时,系统的基态由绝缘体转变为超导体.本文概述了Cu1-xZnxIr2S4系统的超导参量以及压力效应的实验研究,结果表明该超导体系符合基于电-声作用的BCS超导理论.压力导致的超导体-半导体转变显示出超导Cooper对与小双极化子的竞争,暗示系统具有较强的电-声耦合.