部分线性模型的模态正交经验似然推断

本文考虑部分线性模型的有效经验似然统计推断问题.通过结合模态回归和正交投影技术,提出了一种模态经验似然统计推断过程.证明了提出的经验似然比函数渐近服从中心卡方分布,进而构造了模型参数的置信区间.所提出的估计方法可以对模型的参数分量和非参数分量分别估计,而互不影响,具有较好的稳健性和有效性.     

电感耦合等离子体原子发射光谱法测定陶瓷色釉料中稀土元素

为了防止稀土的低附加值滥用,控制陶瓷色釉料中的稀土含量尤为重要,本方法为制订出入境检验检疫行业标准《陶瓷色釉料中稀土总量的测定电感耦合等离子体原子发射光谱法》提供可靠依据。由于陶瓷色釉料极其稳定的化学性质,因此不能采用传统的消解方法进行样品前处理,本文提出了用改进后的氢氧化钠和过氧化钠体系高温碱熔陶瓷色釉料,再用电感耦合等离子体原子发射光谱仪测定La,Ce,Pr,Nd,Sm,Eu,Gd,Tb,Dy,Ho,Er,Tm,Yb,Lu,Y 15种稀土元素总量的方法。在陶瓷色釉料的消解方法、待测元素波长的选择和基体干扰校正方面进行重点研究。选取具有代表性的陶瓷色釉料样品进行回收率、精密度及重现性试验,测得方法的回收率在94.7%~102.7%,精密度小于2.7%,重现性小于4.3%。计算了15种稀土元素的检出限均小于0.51 mg·kg-1。     

High throughput N-modular redundancy for error correction design of memristive stateful logic

Memristive stateful logic is one of the most promising candidates to implement an in-memory computing system that computes within the storage unit. It can eliminate the costs for the data movement in the traditional von Neumann system. However, the instability in the memristors is inevitable due to the limitation of the current fabrication technology, which incurs a great challenge for the reliability of the memristive stateful logic. In this paper, the implication of device instability on the reliability of the logic event is simulated. The mathematical relationship between logic reliability and redundancy has been deduced. By combining the mathematical relationship with the vector-matrix multiplication in a memristive crossbar array, the logic error correction scheme with high throughput has been proposed. Moreover, a universal design paradigm has been put forward for complex logic. And the circuit schematic and the flow of the scheme have been raised. Finally, a 1-bit full adder (FA) based on the NOR logic and NOT logic is simulated and the mathematical evaluation is performed. It demonstrates the scheme can improve the reliability of the logic significantly. And compared with other four error corrections, the scheme which can be suitable for all kinds of R-R logics and V-R logics has the best universality and throughput. Compared with the other two approaches which also need additional complementary metal-oxide semiconductor (CMOS) circuits, it needs fewer transistors and cycles for the error correction.     

双分布聚乙二醇接枝纳米二氧化硅的高效可控制备

在混合溶剂中通过"grafting to"的方法将2种分子量不同的聚乙二醇单甲醚(MPEG M_w=750,4000)接枝到氨基修饰的St?ber法二氧化硅(SiO_2-NH_2)表面,制备双分布纳米接枝复合物.采用二步法,先将带环氧端基的低分子量聚乙二醇单甲醚(MPEG-EO)与SiO_2-NH_2在甲苯溶剂中充分反应后,与高分子量的MPEG-EO在甲苯和正癸烷的混合溶剂中使用相同的反应条件和后处理方法,能便捷制备出具有双分布接枝的纳米复合物.在接枝反应体系中,分子链的链段尺寸和接枝密度之间存在着密切关系.一定的范围内,接枝密度随链段尺寸减小而增大.通过改变混合溶剂比例来调控接枝链段的尺寸,可以很好控制聚合物的接枝密度.在双分布接枝的纳米复合物中,低分子量的接枝密度为0.85 chains/nm~2,高分子量的接枝密度能达到0.40 chains/nm~2,体现出了简单、高效、可控的特点,与聚环氧乙烷(PEO)共混后分散良好,对于制备出均匀分散的纳米复合材料起到了一定的指导作用.     

聚乙烯/氧化铝复合材料形态、流变和力学性能

将聚乙烯（PE）和氧化铝（AO）熔融共混制得综合性能更好的PE/AO复合材料。通过对其进行流变分析、热力学性能分析、力学性能分析、导热性能分析和断面微观结构分析,探究AO质量分数对复合材料结构及性能的影响。结果表明,随着AO质量分数的增加,复合材料逐步转为脆性材料,其弹性模量、屈服强度、导热系数、储能模量同步增加;当AO质量分数为10%时,复合材料的断裂强度为18.2 MPa,综合性能最好。     

The Perturbation Parameter in the Problem of Large Deflection of Clamped Circular Plates

In the problems of large deflection of clamped circular plates under uniformly distributed loads,various perturbation parameters relating to load,deflection,slope of deflection,membrane force,etc.are studied.For a general perturbation parameter,the variational principle is used for the solution of such a problem.The applicable range of these perturbation parameters are studied in detail.In the case of uniformly loaded plate,perturbation parameter relating to central deflection seems to be the best among all others.The method of determination of perturbation solution by means of variational principle can be used to treat a variety of problems,including the large deflection problems under combine loads.     

基础滑移隔震体系的地震响应计算

利用随机振动理论求出了基础滑移隔震房屋在无频谱过程的白噪声过程作用下的响应特性，探讨了基础滑移隔震的振动时最佳阻尼系数取值，提出了基础最大滑移量在白噪声过程作用下的计算公式，并进行了基础滑移隔震位移量的试验测定。计算结果与试验结果表明，本文提出的基础滑移隔震体系的计算公式是可行的，为滑移隔震房屋设计证结构安全、合理提供了理论依据。     

三峡工程坝址花岗岩体缓倾角结构面成因综合研究

本文对长江三峡工程坝址花岗岩体中缓倾角结构面成因进行了全面的综合研究。从野外地质调查人手,在大量野外勘测的基础上进行宏观分析,同时辅之以扫描电镜、透射电镜、包体温度测定等方法进行微观构造组构、差异应力等的研究。在地质力学宏观分析的基础上,利用地质力学物理模拟进行相似条件下的反演,并利用非线性有限元数值模拟进行验证。同类研究在国内外均未见先例,可为同类工程研究借鉴。     

共线式热电发电机在侧面散热情况下的性能

热电材料是一种环境友好型功能材料,其可以实现热能与电能的相互转化,在热电发电、热电制冷中具有许多应用.传统的热电发电机为$\pi$型结构,要求热电腿的长度相等,在某些情况该结构不利于热电发电机的优化设计.热电发电机在高温工况下会引起强烈的热应力甚至应力集中,从而缩短了其工作寿命.另外,热电发电机的工作温度于环境温度,这样必然会有一部分热量散失到环境中,从而影响热电发电机的性能.针对该现象,本文建立了考虑散热的新型共线式热电发电机模型,该模型的热电腿可以独立进行优化,基于有限元方法,对考虑侧面散热的共线式热电发电机进行了仿真模拟,分析了其在狄利克雷边界条件下的热电性能和力学性能,得到了热电发电机的温度场、电势场、应力场,探究了不同强度的对流散热系数对热电发电机热电性能和力学性能的影响.结果表明,对流散热会降低热电发电机的能量转化效率,当对流换热系数达到~100W/(m$^{2}\cdot$\textcelsius) 时,效率为~0.0479,该值比绝热状态的转化效率0.066 7 低28%.对流散热使热电发电机侧面热损失增加,降低了热应力.在实际应用中,应合理优化设计隔热系统,提高能量的转化效率.      

Improve the performance of interferometer with ultra-cold atoms

Ultra-cold atoms provide ideal platforms for interferometry.The macroscopic matter-wave property of ultra-cold atoms leads to large coherent length and long coherent time,which enable high accuracy and sensitivity to measurement.Here,we review our efforts to improve the performance of the interferometer.We demonstrate a shortcut method for manipulating ultra-cold atoms in an optical lattice.Compared with traditional ones,this shortcut method can reduce the manipulation time by up to three orders of magnitude.We construct a matter-wave Ramsey interferometer for trapped motional quantum states and significantly increase its coherence time by one order of magnitude with an echo technique based on this method.Efforts have also been made to enhance the resolution by multimode scheme.Application of a noise-resilient multi-component interferometer shows that increasing the number of paths could sharpen the peaks in the time-domain interference fringes,which leads to a resolution nearly twice compared with that of a conventional double-path two-mode interferometer.With the shortcut method mentioned above,improvement of the momentum resolution could also be fulfilled,which leads to atomic momentum patterns less than 0.6hkL. To identify and remove systematic noises,we introduce the methods based on the principal component analysis (PCA) that reduce the noise in detection close to the 1/√2 of the photon-shot noise and separate and identify or even eliminate noises.Furthermore,we give a proposal to measure precisely the local gravity acceleration within a few centimeters based on our study of ultracold atoms in precision measurements.