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本文通过传统的固相反应法制备了R型六角铁氧体BaFe4-xTi2+xO11 (x= 0, 0.25, 0.5, 0.75, 1), 并且对它的原子价态以及磁性行为进行了研究. X 射线光电子能谱(XPS)结果显示了随着掺杂含量的增加, 体系中Fe3+离子逐渐减少而Fe2+离子逐渐增加. 由于具有非对称结构的阻挫晶格中存在各种关联作用的竞争, 使得BaFe4-xTi2+xO11体系表现出了复杂的磁有序行为, 在T1~250 K和T2~83 K两处存在磁转变. 对这一系列掺杂样品, 在相变温度T1之上表现顺磁行为, 而在相变温度T2前后的磁化强度都表现出低场下随磁场的增加快速增加, 高场下则线性变化且在5×104 Oe时还未达到饱和的行为, 表明这一系列掺杂样品是典型的倾斜反铁磁态(canted antiferromagnetic) 或者亚铁磁态. 相似文献
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We present the temperature-dependent susceptibility and specific heat measurement of spinel ZnV_2O_4.The structural transition with orbital ordering and the antiferromagnetic transition with spin ordering were observed at 50 K and 37 K,respectively.By analysis of the hysteresis behavior between the specific heat curves obtained in warming and cooling processes,the structural transition was confirmed to be the first-order transition,while the antiferromagnetic transition was found to be of the second-order type.At the structural transition,the latent heat and entropy change were calculated from the excess specific heat,and the derivative of pressure with respect to temperature was obtained using the Clausius-Clapayron equation.At the magnetic transition,the width of the critical fluctuation region was obtained to be about 0.5 K by comparing with Gaussian fluctuations.In the critical region,the critical behavior was analyzed by using renormalization-group theory.The critical amplitude ratio A~+/A~- = 1.46,which deviates from the 3D Heisenburg model;while the critical exponent α is-0.011,which is close to the 3D XY model.We proposed that these abnormal critical behaviors can be attributed to strong spin-orbital coupling accompanied with the antiferromagnetic transition.Moreover,in the low temperature range(2-5 K),the Fermi energy,the density of states near the Fermi surface,and the low limit of Debye temperature were estimated to be2.42 eV,2.48 eV~(-1),and 240 K,respectively. 相似文献
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弹性或弹塑性土体中桩基的大变形分析 总被引:1,自引:0,他引:1
采用弧坐标,首先建立了位于弹性地基或弹塑性地基上并具有初始位移的桩基大变形行为的非线性微分方程组,并采用Winkeler模型来模拟地基对桩基的抗力;其次,应用微分求积方法离散非线性微分方程组,得到一组离散化的非线性代数方程,并给出了利用Newn-Raphson方法求解非线性代数方程的步骤;作为应用给出了数值算例,得到了桩顶受组合载荷作用时,变形后桩基的构形、弯矩和剪力,考察了土的弹性和弹塑性性质、桩基初始位移、荷载等参数对桩基力学行为的影响.最后将模型进行简化,得到了小变形理论的解析解,并比较了由大变形理论与小变形理论所得结果的差别. 相似文献
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Based on the assumption of finite deformation, the Hamilton variational principle is extended to a nonlinear elastic Euler-type beam-column structure located on a nonlinear elastic foundation. The corresponding three-dimensional (3D) mathematical model for anaiyzing the nonlinear mechanical behaviors of structures is established, in which the effects of the rotation inertia and the nonlinearity of material and geometry are considered. As an application, the nonlinear stability and the post-buckling for a linear elastic beam with the equal cross-section located on an elastic foundation are analyzed.One end of the beam is fully fixed, and the other end is partially fixed and subjected to an axial force. A new numerical technique is proposed to calculate the trivial solution,bifurcation points, and bifurcation solutions by the shooting method and the Newton-Raphson iterative method. The first and second bifurcation points and the corresponding bifurcation solutions are calculated successfully. The effects of the foundation resistances and the inertia moments on the bifurcation points are considered. 相似文献
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粘弹性矩形板的稳定性分析 总被引:11,自引:0,他引:11
根据动力系统的观点研究了四边简支粘弹性矩形板的稳定性,利用Laplace变换得到了蠕变临界载荷λcr和瞬时临界载荷λcs。同时采用Laplace变换和Galrkin方法计算了时间相关载荷λ(t)的峰值λ满足条件λer〈λ〈λcs时,线性和非线性问题的挠度随时间的变化规律。 相似文献
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本文采用弧坐标首先建立了弹性地基中受轴向载荷作用的高柔性抗震拼接头桩(High Ductility Aseis-matic Joint Spliced Pile)的非线性数学模型,并假定土(基础)对桩基的反作用力服从Winkler模型;在此基础上对该模型进行了线性化,并得到HDAJ接头桩的临界载荷。最后根据分叉理论的观点和方法,讨论了HDAJ接头桩在临界载荷处的稳定性问题。研究结果表明HDAJ接头桩在临界载荷附近必发生分叉,且分叉解是唯一的,稳定的,并且给出了分叉解的渐近表达式。物理上,这表示HDAJ接头桩的平衡构形在临界载荷处必然发生改变,并且从一个稳定的平衡构形变化到另一个稳定的平衡构形。同时考察了土的液化对临界载荷的影响,说明液化的影响是非常明显的。当考虑土的液化时,桩基的临界载荷低于不考虑土的液化时桩基的临界载荷。 相似文献
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本文综合应用无网格方法(EFGM)、线性粘弹性与弹性力学之间的对应原理,Laplace变换和逆变换等方法求解了拟静态平面弹性和粘弹性力学问题。首先,利用Laplace变换和逆变换推导了平面问题的粘弹性本构关系,建立了拟静态粘弹性平面问题的边值问题;其次,利用粘弹性与弹性力学之间的对应原理得到了Laplace变换域中平面问题的基本方程,在Laplace变换域中建立了相应的泛函,并得到了用无网格方法离散的控制方程;同时,求解了几个拟静态弹性和粘弹性平面问题,给出了它们的表达式和数值结果;最后,采用Laplace逆变换和数值逆变换,得到了粘弹性力学平面问题在物理空间中的解,并比较了由解析解和无网格数值方法所得到的数值结果,可以看到它们是非常吻合的。说明本文方法的正确性和有效性。 相似文献