基于光声光谱技术的NO,NO2气体分析仪研究

NO, NO₂是大气污染源中的常见气体, 对环境具有严重的危害性. 为检测污染源中这两种气体的浓度, 构建了成本较低的基于红外热辐射光源的光声光谱气体检测系统. 分析计算得到了NO, NO₂ 在2500–6667 nm波段吸收谱线. 通过建立光声传输线RLC振荡电路模型和仿真得到品质因数、声压大小与谐振腔长、内腔半径以及调制频率的关系, 据此设计了光声池几何结构. 实验表明该系统所测得的光声信号与气体浓度有很好的线性关系, 并且对NO, NO₂气体极限检测灵敏度分别达到4.01 和1.07 μL. 通过调节激光发射波长和选取滤波片, 该系统还可用于其他微量气体的浓度检测. 关键词： 大气污染 光声光谱 气体检测     

光声池中微弱光声信号检测

大气中的污染源气体含量很少, 用光声光谱对其进行监测得到的光声信号极其微弱. 本文首先分析微弱信号产生机理, 在分析Holmes Duffing方程的基础上, 提出了适合光声池微弱信号检测的变尺度差分方法. 该方法通过对信号进行尺度变换, 再做差分来检测微弱信号. 理论分析和实验表明, 变尺度差分方法能很好地抑制系统相空间的共模噪声, 而且能很好地凸显混沌状态临界值. 变尺度差分方法测出的信号相对误差都小于5%, 说明其可以用于较高频率、 相位和频率都未知的微弱光声信号幅值检测. 关键词： 光声光谱 微弱信号 幅值 Duffing     

Self-calibration wavelength modulation spectroscopy for acetylene detection based on tunable diode laser absorption spectroscopy

The expressions of the second harmonic(2f) signal are derived on the basis of absorption spectral and lock-in theories.A parametric study indicates that the phase shift between the intensity and wavelength modulation makes a great contribution to the 2f signal.A self-calibration wavelength modulation spectroscopy(WMS) method based on tunable diode laser absorption spectroscopy(TOLAS) is applied,combining the advantages of ambient pressure,temperature suppression,and phase-shift influences elimination.Species concentration is retrieved simultaneously from selected 2f signal pairs of measured and reference WMS-2f spectra.The absorption line of acetylene(C_2H_2) at 1530.36 nm near-infrared is selected to detect C_2H_2 concentrations in the range of 0-400 ppmv.System sensitivity,detection precision and limit are markedly improved,demonstrating that the self-calibration method has better detecting performance than the conventional WMS.