环氧大豆油与丙交酯星形共聚物支化度的表征

采用凝胶色谱(GPC)/示差检测器(RI)/十八角激光光散射仪(MALLS)联用技术, 对环氧大豆油(ESO)与丙交酯形成的星形共聚物(ESO-丙交酯)的结构进行了表征。实验结果表明: 随着ESO-丙交酯星形共聚物分子量的增长, 接枝数目呈现增多趋势、支化度从0.46E-4增大到0.78E-4、支化因子从0.82减小到0.15。本研究为高分子ESO-丙交酯星形支化共聚物的研究提供了科学依据。     

Electric and magnetic behaviour in double doped La2/3＋4x/3Sr1/3-4x/3Mn1-xMgxO3

The double-doped La2/3＋4x/3Sr1/3-4x/3Mn1-xMgxO3 samples with fixed Mn^3＋/Mn^4＋ ratio equal to 2/1 are investigated by means of magnetism and transport measurements. Phase separation is observed at temperature higher than T^onset c for x = 0.10 and 0.15. For x = 0.10, rather strong phase separation induces drastic magnetic random potential and results in the localization of carriers. Thus, the varlable-range hopping process dominates. For other samples, there is no or only weak phase separation above T^onset c. Thus, thermal activation mechanism is responsible for the high temperature transport behaviour. For x = 0.20 and 0.25, unexpected AFM behaviour is observed at low temperature. All these results are well understood by considering the special role of the ＂double-doping＂.     

双掺杂La0.67+1.33xSr0.33-1.33xMn1-xMgxO3体系的磁性和输运行为

用标准的固相反应法制备了双掺杂La0.67 1．33xSr0．33-1．33xMn1-xMgxO3(x=0．00,0．05,0．10,0．15,0．20,0．25)多晶样品,研究了它们的磁性和输运行为。对x=0．10和0．15,在温度高于Tc^cnset时出现相分离;对x=0．20和0．25,在低温区出现反铁磁行为。低掺杂样品ρ-T关系存在金属．绝缘体相变,高掺杂样品在测量温区内仅显示绝缘体行为。这些奇异现象用M-H关系、ESR曲线和拉曼光谱给予了很好的解释。     

中国优秀传统文化融入STEAM实践的教学——沉淀溶解平衡

基于STEAM理论，以中国山水画的传统艺术为教学情境，以沉淀溶解平衡知识为载体，以化学试剂为色彩将优秀传统文化融入化学学科教学设计，引导学生在获取知识的过程中提高人文素养，增强文化自信。