多巴胺在聚溴甲酚绿修饰碳糊电极上的电化学行为

以碳糊电极(CPE)为基底,采用电聚合方法制备出聚溴甲酚绿修饰碳糊电极(PBG/CPE),运用循环伏安法(CV)对修饰电极进行表征,通过扫描电子显微镜(SEM)对聚合膜的表面形貌进行观察分析。利用PBG/CPE研究了多巴胺(DA)的电化学行为,并对最佳实验条件进行了探讨。研究结果表明:DA在PBG/CPE上于0.32V和0.24V处分别出现一对可逆氧化还原峰,PBG/CPE对DA有显著的催化作用,该催化过程受吸附控制。DA催化氧化还原峰电流与其浓度在1.0×10-5~2.0×10-4mol/L范围内呈现良好的线性关系,检出限为1.0×10-6mol/L。     

Electrical Properties of La-Doped Al2O3 Films on Si （100） Substrates as a High-Dielectric-Constant Gate Material

Amorphous La-doped Al2O3 （La： Al2O3） thin films are deposited on n-type （100） Si substrates by rf magnetron co-sputterlng. The composition of the deposited films is measured by energy dispersive x-ray spectroscopy： Capacitance-voltage measurement shows that the dielectric constant k of La-doped Al2O3 films ranges from 8.5 to 11.6 with the increasing La content, and the highest k value of 11.6 is obtained for the 20.14% La content film. In the structure of the Al/La：Al2O3/Si metal oxide semiconductor, the dominant conduction stems from the space- charge-limited current at different temperatures. In addition, the wavelength dependence of the transmittance is studied by ultraviolet spectroscopy and the band gap of all the deposited films is above 5.5eV. The results demonstrate that La-doped Al2O3 can meet the requirement of next-generation gate materials.     

Photonic Band Gap Properties of Three-Dimensional SiO2 Photonic Crystals

Three-dimensional SiO2 photonic crystals （PhCs） are fabricated on quartz substrates by the vertical deposition method. Scanning electron microscopy measurement reveals that the samples exhibit an ordered close-packed arrangement of SiO2 spheres. It is found that the position of the [111] photonie band gap （PBG） shifts to a long wavelength （red shift） with increasing sphere size. Gap broadening effects are observed due to the presence of defects in the samples. Moreover, the optical properties of the PBG are very sensitive to the annealing temperature. Our results indicate that the optical properties of the PBG can be easily tuned in the visible region by appropriate experimental parameters, which will be useful for practical applications of PhC optical devices.     

Preparation of ZnO Nanospheres and Their Applications in Dye-Sensitized Solar Cells

ZnO nanospheres are synthesized by a two-step self-assembly method. X-ray diffraction pattern and Raman scattering spectra measurements show that all the samples present a typical wurtzite structure. A regular sphere shape is inspected by field emission scanning electron microscope and transmission electron microscope for the samples. It is shown that the as-synthesized ZnO nanosphere is composed of numbers of primary particles with size of around 1Ohm. A possible growth mechanism for the two-step self-assembly ZnO nanosphere is proposed. After applying the ZnO nanospheres to dye-sensitized solar cells （DSSCs）, a 117% increase of the overall light to electricity conversion efficiency η is observed compared with that of the ZnO nanopartieles based DSSCs. Associated with the UV-vis results, light scattering is assigned to the great improvement of η.     

铝的嵌入原子模型参数和性能计算

运用普适的嵌入原子理论 (GEAM)计算了FCC结构金属铝的嵌入原子模型参数 ,并用该模型计算了铝的单空位形成能、双空位结合能、表面能、结构稳定性、弹性常数和声子谱等性质。计算结果与已有的实验结果相符     

一类具有脉冲效应的非线性竞争系统的持久及全局吸引性(英文)

通过利用常微分方程比较定理以及构造恰当Lyapounov泛函,研究了一类具有脉冲效应的广义非自治n种群Gilpin-Ayala竞争系统,给出了使系统正解持久以及全局吸引的充分性条件,所得结论改进并推广了一些现有结果.     

具有周期系数的两竞争种群系统的最优捕获策略

在竞争关系的生态模型基础上,通过引入周期性参数形成一个竞争的二维周期系统.对此非自治生态系统,利用比较定理探讨了系统的持续存在性;由Brouwer不动点定理及稳定性理论证明了其周期解的唯一存在性;最后,讨论了相应的最优控制问题,并给出了问题的最优收获策略Eopt(t).     

改性纳米TiO2降解水中微量次甲基蓝的动力学研究

改性纳米TiO2降解水中微量次甲基蓝的动力学研究;光催化氧化;动力学;表观一级反应     

基于高斯原理的非理想系统动力学建模

高斯原理给出了通过求函数极值、从可能运动中鉴别出真实运动的规则, 它可以使得多体系统动力学问题不需通过求解微分(代数)方程, 而是采用求解最小值的优化方法来解决, 从而提供了一种适用于优化算法的建模思路, 因此, 如何定义恰当的高斯拘束函数是动力学优化方法得以实现的前提. 对于理想系统而言, 约束对系统的作用可以通过约束方程来体现, 故高斯拘束可表达为系统质点加速度的函数, 系统的动力学问题因此可以描述为目标函数为高斯拘束函数、优化变量为质点加速度的约束最优化问题; 当系统中需要考虑干摩擦等非理想因素时, 部分相互作用不能被所定义的约束方程所涵盖而需要采用额外的物理规律来描述, 这种相互作用破坏了原有的针对理想系统的高斯拘束函数的极值特性. 基于变分类的高斯原理, 推导并证明了目标函数以理想约束力所表达的非理想系统的极值原理, 针对目前文献中用于非理想系统的高斯原理进行了讨论, 指出其实际为文中的极值原理在非理想约束力与理想约束力无明显关联时的一种特殊表达形式, 当非理想约束力与理想约束力有明显的函数关系(如库仑摩擦定律中滑动摩擦力与法向约束力间的线性关系)时, 该形式失效; 同时根据文中的极值原理, 得到了考虑库仑摩擦时非理想的多体系统动力学问题的优化模型. 例子中分析了优化模型及相应的线性互补性模型的关系, 分析发现在满足刚体滑动问题的唯一性条件下二者互为充分必要条件, 从而证明了文中优化模型的可靠性; 并采用优化计算方法进行了动力学模拟, 模拟结果显示了将高斯原理与优化算法相结合的可行性及有效性.      

周期性Gompertz差分模型的最优脉冲收获策略

考虑一个具有周期性脉冲收获的Gompertz差分系统,推导了保证种群系统持续生存、绝灭以及存在全局吸引的正脉冲周期解的充要条件,以一个周期内持续产量最大化为管理目标,通过利用离散的Pontryagin最大值原理获得了最优的脉冲收获策略,推广了现有的结论.