不同窑口古代青瓷的产地特征的中子活化分析

产地属性是科学鉴别遗址和墓葬中出土的古陶瓷烧制产地的重要依据.用仪器中子活化（INAA）有损分析了浙江寺龙口越窑、江西洪州窑和陕西耀州窑出土的古瓷碎片样品,通过实验数据的统计分析,结果表明3个窑口古瓷的元素组成具有各自的特征,它们之间具有可以区分的依据,寺龙口越窑与南方江西洪州窑的制胎原料关系较近,与北方陕西耀州窑的关系较远.这些试验结果将为古陶瓷地研究提供重要参数.Provenance characteristic is an important scientific parameter to identify ancient porcelain wares unearthed from sites and graves.The porcelain samples of Si Long Kou kiln of Zhejiang Province,Hong Zhou kiln of Jiangxi Province and Yao Zhou kiln of Shanxi Province have been analyzed with neutron activation analysis(NAA) in this paper.The experimental data were studied with statistic methods.The results show that the chemical compositions of porcelain body samples for three kilns were different. The difference was been able identified. The body materials of both Si Long Kou Yue kiln and Hong Zhou kiln of Jiangxi were similar. The samples of Yao Zhou kiln in north of China existed obvious difference.     

基于偏好信息一致性程度最大的多属性决策方法

研究了方案偏好信息以区间数互反判断矩阵形式给出,属性偏好信息以区间数互补判断矩阵形式给出的不确定多属性决策问题。首先针对属性值以实数形式给出的多属性决策问题,基于区间数判断矩阵一致性的性质,建立了求解属性和方案偏好信息一致性程度最大化的线性规划模型,然后把其推广到属性值以区间数形式给出的多属性决策问题,最后通过一个算例说明了该方法的适用性和有效性。     

Study of the circumstance influence on the elemental distribution in ancient animal bone using μ-XRF

Elemental analysis of archaeological bone plays an important role in the study of the dietary habits of ancient animals. The elemental characteristic of diagenetic skeletons depends on the surrounding circumstance. The study of environmental influence on the elemental concentration of ancient bone is significant. In this paper, the diagenetic influence on archaeological skeletons is analyzed by microbeam X-ray fluorescence （p.-XRF）. The results show that the enamel is an excellent barrier to the diagenesis and the element Sr in bone isn＇t susceptible to contamination from the buried environment.     

Study on the chemical composition features of Longquan celadon excavated from the Chuzhou site of Huai'an City in Jiangsu Province by EDXRF

A mass of Longquan celadon shards were excavated from the Chuzhou site of Huai'an City in Jiangsu Province, China. These celadon shards were fired during the period of the Late Yuan Dynasty to the Tianshun era of the Ming Dynasty, as identified by archaeologists at Nanjing Museum. In order to research the chemical composition features of this ancient celadon porcelain, energy dispersive X-ray fluorescence (EDXRF) for non-destructive analysis was used to determine the chemical composition of the porcelain body and glaze in these shards. The results indicate that Ti and Fe in the body of Longquan celadon are characteristic elements which can distinguish porcelain produced during the Late Yuan Dynasty from those produced in the Ming Dynasties. The results of the principal component analysis (PCA) show that different body and glaze raw materials were used for the production of porcelain in different periods and the raw materials of the body and glaze are also different for various vessel shapes. The chemical compositions in the porcelain body of civilian ware are slightly different. The imperial and civilian Longquan celadon porcelains produced during the Hongwu era to the Tianshun era of the Ming Dynasty are distinguishable by the MnO, Fe₂O₃, Rb₂O and SrO content in their porcelain glaze.     

基于卷积神经网络的古陶瓷窑口甄别

古陶瓷作为中华文化的瑰宝,自古以来不仅在国内受到追捧,在国外同样被视若珍宝。伴随着古代商贸的进行,中国古陶瓷遍布全球各地,辗转流传被私人或博物馆收藏,还有部分古陶瓷经墓葬发掘以及沉船打捞后被收藏于博物馆,这类古陶瓷的产地溯源一直以来都是陶瓷考古的重点,对于研究古代商贸和文化交流有重要的意义。通过便携式数码显微镜、分光光度计、 X射线荧光等方法对从越窑后司岙、越窑寺龙口、龙泉枫洞岩窑、耀州窑发掘出土的青釉瓷样品进行分析测量,获得了来自四个窑青釉瓷样品的微观气泡尺寸分布特征、紫外可见近红外光谱特征、釉的成分数据。将来自四个窑青釉瓷样品的这三种特征作为变量建立卷积神经网络分类模型进行训练和验证,结果表明青釉瓷的微观气泡尺寸分布特征、紫外可见近红外光谱特征以及瓷釉成分数据均有效,但是不同特征的分类准确率差异非常明显。三十次随机划分训练集与测试集的模型训练平均准确率：微观气泡尺寸分布特征模型为75%,紫外可见近红外光谱特征模型为89.2%,成分数据模型为92.1%,成分数据模型准确率最高且训练集与测试集准确率相差最小。将基于不同特征训练好的模型参数保存进行融合后再训练发现基于紫外可见近红外光谱特...     

基于理想关联度的不确定多属性决策方法

针对只有部分属性权重信息且属性值以区间数形式给出的不确定多属性决策问题,提出了一种逼近理想关联度的决策分析方法。首先改进了文[4]给出的区间数决策矩阵的规范化方法;然后提出了利用期望-方差区间数排序方法求解理想最优方案;最后依据关联系数矩阵给出了属性权重信息不完全的区间数多属性决策问题的求解方法,其核心是求解线型规划得到属性权重,进而根据各个方案与理想最优方案的综合关联度大小进行排序。特别地,给出了属性权重完全未知的简洁方法,文后的实例验证了方法的可行性和有效性。     

越窑青瓷釉层元素组成的SRXRF无损分析及其在考古学中的应用

利用同步辐射X荧光(SRXRF)无损分析研究了越窑青瓷的釉面元素组成,探讨了越窑古瓷无损分析的可行性实验方法.对寺龙口越窑6个文化期的古青瓷样品进行了无损分析,选用晚唐时期荷花芯越窑的古青瓷样品作对比分析.实验数据经统计分析后表明,寺龙口越窑古青瓷具有较明显的年代特征和产地特征,不同文化期烧制的青瓷样品具有一定的相关性.     

Attenuation correction of L-shell X-ray fluorescence computed tomography imaging

X-ray Fluorescence Computed Tomography (XFCT) is a widely-used experimental technique for investigating the spatial distribution of elements in a sample. However, image reconstruction for this technique is more difficult than for transmission tomography, one problem being self-absorption. In this work, we make use of known quantities and unknown density of elements of interest to express unknown attenuation maps. The attenuation maps are added to the contribution value of the pixel in the Maximum Likelihood Expectation Maximization (MLEM) reconstruction method. Results indicate that the relative error is less than 14.1%, which shows that this method can effectively correct L-shell XFCT.     

基于犹豫模糊二元语义的多属性决策方法

深入研究了犹豫模糊二元语义多属性决策问题。首先利用幂均算子给出了犹豫模糊二元语义集的均值函数,并基于均匀分布概率准则和二元语义的距离测度提出了犹豫模糊二元语义集两两比较的可能度公式,进一步给出了可能度排序公式的性质。针对属性值为犹豫模糊二元语义集的多属性决策问题,提出了一种基于熵权的多属性决策方法。最后结合实际问题,验证了该方法的有效性和可行性。     

群决策中判断的一致性分析及方案排序

对群决策中基于区间数互补判断矩阵形式偏好信息的一致性问题进行了探讨。首先,给出了区间数互补判断矩阵相容性指标定义及性质;然后,通过定义群和个体判断的一致性指标,提出了群判断的一致性判别方法和不一致的协调方法;同时依据个体判断的一致性指标大小,即群成员评判水平的高低,给出了群偏好信息的集结方法;最后给出了由区间数互补判断矩阵导出方案排序权重的计算方法及应用算例。