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Numerical Algorithms - This paper considers the inverse problem for identifying the initial value problem of a space-time fractional diffusion wave equation. In general, this problem is ill-posed... 相似文献
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Two heterometallic uranium oxyfluorides with hybrid networks were hydrothermally synthesized by incorporating two imidazoles, 1-(biphenyl-4-yl)-1H-imidazole(bpi) and 1,4-di(1H-imidazol-1-yl)benzene(dib), formulated as Zn(bpi)2(UO2)2(H2O)F6(1) and Zn(dib)(UO2)F4 0.5H2O(2). Compound 1consists of chains of edge-sharing UO2F5 and UO2F4(H2O) pentagonal bipyramids, which are linked by Zn(bpi)2moieties to form the sheet structure with decorated bpi. While in compound 2, sheets of edgesharing dimers of UO2F5 pentagonal bipyramids and Zn F3N2 polyhedra are linked by dib, creating a pillared three-dimensional framework. The two compounds represent the few examples of heterometallic uranium oxyfluorides incorporating organic ligands. The syntheses, structure as well as the IR spectra, UV–vis spectra and luminescent properties of the bimetallic uranium oxyfluorides are studied. 相似文献
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采用RNG k-ε 湍流模型对超临界CO2流体在内径为4 mm, 长度2000 mm, 节距为10 mm, 曲率为0.1的水平螺旋管内的冷却换热进行了数值模拟.研究了质量流量、热流量以及压力对换热系数的影响, 并和超临界CO2在水平直管内的冷却换热进行了对比.研究结果表明, 超临界CO2在水平螺旋管内流动产生的二次流强于水平直管内的二次流, 前者的换热系数大于后者; 换热系数随质量流量的增加而增大; 在似气体区, 换热系数随着热流量的增加而增大, 而在似液体区, 热流量对换热系数几乎没有影响; 换热系数峰值点随着压力的升高而下降, 并向高温区偏移. 相似文献
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Guo-Qiang Tang Xian-Hua Li Qiu-Li Li Yu Liu Xiao-Xiao Ling 《Surface and interface analysis : SIA》2020,52(5):190-196
Carbonate oxygen (O) and carbon (C) isotopes are widely used as proxies for tracing the processes and physicochemical conditions of many geological events and environmental changes in Earth Science. In particular, O and C isotopic variations at micrometer scales revealed by modern microbeam analytical techniques such as SIMS and NanoSIMS are robust archives for reconstructing palaeoenvironment and paleoclimate changes at annual and seasonal resolution or even higher temporal resolution. Widespread application of carbonate O and C isotopic microanalysis in Earth Sciences, however, has been restricted due to limitation of high-quality carbonate reference materials for O and C isotopic microanalysis. We introduce in this paper a new calcite reference material for calcite O and C isotopic microanalysis. This calcite is collected from a drill-core of the Oka carbonatite complex (Quebec, Canada). We demonstrated that the Oka calcite is fairly homogeneous in O and C isotopic compositions at micrometer scales based on homogeneity test by hundreds of SIMS O and C isotopic analyses. Precise determinations by using conventional gas-source IRMS yield the recommended value of δ18OVPDB = −23.12 ± 0.15‰ (1SD) and δ13CVPDB = −5.23 ± 0.06‰ (1SD) for the Oka calcite, which has been certified as the first class of Chinese national certified reference material (GBW04481) for O and C isotopic microanalysis. 相似文献
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研究变质量Chetaev型非完整系统Appell方程的Mei对称性和Mei守恒量.建立变质量Chetaev型非完整系统的Appell方程和系统的运动微分方程; 给出函数沿系统运动轨道曲线对时间t全导数的表示式,并在群的无限小变换下,给出变质量Chetaev型非完整系统Appell方程Mei对称性的定义和判据;得到用Appell函数表示的Mei对称性的结构方程和Mei守恒量的表达式,并举例说明结果的应用.
关键词:
变质量
非完整系统
Appell方程
Mei守恒量 相似文献
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基于磷酸化修饰的核/壳硅纳米颗粒药物缓释体研究 总被引:1,自引:0,他引:1
采用反相微乳液体系中功能化基团同步修饰方法制备了包载抗肿瘤药物平阳霉素(PYM)的磷酸化核/壳硅纳米颗粒(PYM-PO4SiNP), 考察了不同量的磷酸化修饰试剂对PYM-PO4SiNP的影响. 结果表明, 随着磷酸化修饰试剂量的增加, 制备的PYM-PO4SiNP的电位逐渐降低, 其包载的PYM 的释放速率逐渐加快, 但对颗粒的粒径没有明显影响. 本文选择能使药物平稳、缓慢释放的磷酸化修饰试剂用量, 制备了稳定性好、药物缓释时间长的PYM-PO4SiNP, 其载药量和包封率分别为7.2%和37.81%, 通过与CNE-2细胞共培育后, 可以使CNE-2细胞的存活率逐渐下降, 而磷酸化核/壳硅纳米颗粒PO4SiNP载体本身是没有毒性的. 这一研究工作的开展拓宽了核/壳硅纳米颗粒在药物载体领域中的应用. 相似文献
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闪点是衡量化合物易燃程度的物理量,也是可燃性液体的一个重要安全性指标。本文对含氧有机化合物(包括醇、酚、醚、醛、酮、羧酸、酯等)的闪点与分子结构之间的关系进行分析,提取并计算了顶点度-距离指数(VDI)、奇偶指数(OEI)、边度-距离指数(EDI)、分子体积参数(MVI)和氢键指示变量(HB)等分子结构参数,并结合分子隐氢图顶点数(N)的2/3次方(N~(2/3)),对训练集中81个含氧有机化合物的闪点进行定量结构-性质相关分析。结果表明,由N~(2/3)、VDI、EDI、OEI、MVI和HB等6个参数对闪点建立的多元线性回归模型的相关系数(R)为0.9909,标准偏差(s)为6.39K,平均相对误差(ARD)为1.60%。用该模型对测试集中20个含氧有机化合物的闪点进行了预测,ARD为1.84%。 相似文献
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锂硫电池中较差的循环稳定性和倍率性能是实现锂硫电池商业化的技术障碍,其主要原因之一是多硫化物在硫电极内的电化学转化动力学较为缓慢。为此,我们以ZIF-9为前驱体,采用先碳化,再酸化刻蚀,最后硒化的方法合成了含少量催化剂的CoSe修饰氮掺杂多孔碳(CoSe/NC)电极材料,以期提高硫电极内多硫化物的电化学转化动力学性能,并通过流动液相三电极体系对该材料进行电化学动力学表征。结果显示,相较于对比材料,CoSe/NC能够加快多硫化物的氧化还原反应速率,在 0.2mA·cm-2电流密度下,多硫化物氧化还原反应在CoSe/NC电极上有最小的反应过电位;同时,在0.1 V过电位下,各氧化还原反应也有最大的响应电流。因此,将 CoSe/NC作为硫宿主材料组装电池展现了优异的电化学性能:在 1C(1C=1 675 mA·g-1)下初始放电比容量为1 068 mAh·g-1,经过500次循环后,可逆容量仍保持在693 mAh·g-1。另外,在3C的高电流密度下,放电比容量可高达819 mAh·g-1。 相似文献
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Mei symmetry and Mei conserved quantity of Appell equations for a variable mass holonomic system of relative motion 下载免费PDF全文
Mei symmetry and Mei conserved quantity of Appell equations for a variable mass holonomic system of relative motion are studied.The definition and criterion of the Mei symmetry of Appell equations for a variable mass holonomic system of relative motion under the infinitesimal transformations of groups are given.The structural equation of Mei symmetry of Appell equations and the expression of Mei conserved quantity deduced directly from Mei symmetry for a variable mass holonomic system of relative motion are gained.Finally,an example is given to illustrate the application of the results. 相似文献
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