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排序方式: 共有104条查询结果,搜索用时 15 毫秒
1.
Amano Yuki Ishikawa Satoshi Yoshitake Tatsuhiro Kondou Takahiro 《Nonlinear dynamics》2021,104(3):1917-1935
Nonlinear Dynamics - Rectangular flat-bottom liquid tanks known as tuned liquid dampers (TLDs) are often used as passive mechanical dampers. Sloped- and triangular-bottom TLDs have been reported to... 相似文献
2.
Kento Imanishi Benny Wahyudianto Dr. Tatsuhiro Kojima Dr. Nobuto Yoshinari Prof. Takumi Konno 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(8):1827-1833
Here a unique single-crystal-to-single-crystal (SCSC) transformation of a 116-nuclear AuI72CdII40NaI4 cage-of-cage ( 2 CdNa) is reported, which was created from a trigold(I) metalloligand with d -penicillamine by way of a 9-nuclear AuI6CdII3 cage ( 1 ). Cage-of-cage 2 CdNa is composed of 12 cages of 1 that are linked by 4 Cd2+ and 4 Na+ ions, with its surface being covered by 12 NO3− ions to form a discrete, spherical molecule with a diameter ca. 4.7 nm. In crystal 2 CdNa, the cage-of-cage molecules are packed in a cubic lattice with a huge cell volume of ca. 4.5×105 Å3, so as to have large interstices with diameters of more than 3 nm. Upon soaking crystals 2 CdNa in aqueous Cu(NO3)2, all Cd2+ and Na+ were quickly exchanged by Cu2+ to produce an analogous AuI72CuII44 cage-of-cage ( 2 Cu) in a SCSC manner. Prolonged soaking led to the SCSC transformation to another supramolecular structure ( 2′ Cu) consisting of 152-nuclear AuI72CuII80 cage-of-cages that are alternately H-bonded with the AuI72CuII44 cage-of-cages. 2′ Cu showed the accommodation of MoO42− and the conversion of MoO42− to β-Mo8O264− in the crystal, with retention of single-crystallinity. 相似文献
3.
Dr. Tatsuhiro Murakami Kanon Ogino Yu Hashimoto Prof. Toshiyuki Takayanagi 《Chemphyschem》2023,24(10):e202200939
In the interstellar medium, the H2 adsorption and desorption on the solid water ice are crucial for chemical and physical processes. We have recently investigated the probabilities of H2 sticking on the (H2O)8 ice, which has quadrilateral surfaces. We have extended the previous work using classical MD and ring-polymer molecular dynamics (RPMD) simulations to the larger ice clusters, (H2O)10 and (H2O)12, which have pentagonal and hexagonal surfaces, respectively. The H2 sticking probabilities decreased as the temperature increased for both cluster cases, whereas the cluster-size-independent profiles were observed. It is thought that the size independence of the probabilities is qualitatively understood from the similar binding energies for all the three cluster systems. Furthermore, the RPMD sticking probabilities are smaller than the classical ones because of the reduction in the binding energies owing to nuclear quantum effects, such as vibrational quantization. 相似文献
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Dr. Hikaru Sotome Dr. Hajime Okajima Tatsuhiro Nagasaka Yuka Tachii Prof. Akira Sakamoto Prof. Seiya Kobatake Prof. Masahiro Irie Prof. Hiroshi Miyasaka 《Chemphyschem》2020,21(14):1524-1530
The geometrical evolution of the reactant and formation of the photoproduct in the cycloreversion reaction of a diarylethene derivative were probed using time-resolved absorption spectroscopies in the visible to near-infrared and mid-infrared regions. The time-domain vibrational data in the visible region show that the initially formed Franck-Condon state is geometrically relaxed into the minimum in the excited state potential energy surface, concomitantly with the low-frequency coherent vibrations. Theoretical calculations indicate that the nuclear displacement in this coherent vibration is nearly parallel to that in the geometrical relaxation. Time-resolved mid-infrared spectroscopy directly detected the formation of the open-ring isomer with the same time constant as the decrease of the closed-ring isomer in the excited state minimum. This observation reveals that no detectable intermediate, in which the population is accumulated, is present between the excited closed-ring isomer and the open-ring isomer in the ground state. 相似文献
7.
Florian J. Stadler Tatsuhiro Takahashi Koichiro Yonetake 《European Polymer Journal》2011,(5):1048-1053
Ethene-/α-olefin copolymers having a wide range of comonomers between 8 and 26 carbon atoms in length were characterized by wide angle X-ray diffraction (WAXD). It was found that the crystallinities for the shorter comonomers (C8, C12) matched fairly well with the crystallinities from DSC and volumetric measurements, while for the longer comonomers (C18, C26) distinct differences between the three methods were found. This was explained by the presence of an additional crystalline phase of the side chains slightly deforming the amorphous peak. 相似文献
8.
A mechanistic study on the Nieuwland catalysis for dimerization of acetylene is performed by detecting copper–acetylene and copper–monovinylacetylene π‐complexes and also by examining the kinetics under virtually the same reaction conditions employed in the industrial process. An efficient H/D exchange occurs between acetylene and protons in the Nieuwland catalytic system. Addition of a coordinating ligand to the conventional Nieuwland catalytic system results in improvement of the catalytic activity and selectivity for the acetylene dimerization. The kinetic analysis including the kinetic deuterium isotope effect provides valuable insight into the Nieuwland catalytic mechanism of the dimerization of acetylene. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献
9.
Hiroshi Mizukawa Tatsuhiro Nakajima Ryoji Seno Hiro-Fumi Yamada 《Letters in Mathematical Physics》2014,104(10):1317-1331
A Lie theoretic interpretation is given for some formulas of Schur functions and Schur Q-functions. Two realizations of the basic representation of the Lie algebra \({A^{(2)}_2}\) are considered; one is on the fermionic Fock space and the other is on the bosonic polynomial space. Via the boson–fermion correspondence, simple relations of the vacuum expectation values of fermions turn out to be algebraic relations of Schur functions. 相似文献
10.
Akinari Minegishi Akihiro Nishioka Tatsuhiro Takahashi Yuichi Masubuchi Jun-ichi Takimoto Kiyohito Koyama 《Rheologica Acta》2001,40(4):329-338
A series of polystyrene (PS) and a small amount of ultra high molecular weight (UHMW) PS blends have been prepared by using
tetrahydrofuran (THF). Matrix PS has an Mw of 423,000 (Mw/Mn= 2.36) and UHMW-PS has either an Mw of 3,220,000 (Mw/Mn= 1.05) or 15,400,000 (Mw/Mn=1.30) in the range of concentration from 0 wt% to 1.5 wt%. The influence of a small amount of UHMW on dynamic viscoelasticity
was investigated. At the frequency lower than 0.001 rad/s, the enhancement of G′ was observed by the incorporation of a small
amount of UHMW. And the degree of enhancement was in the order of Mw of UHMW and its concentration. The measurement of uniaxial elongational viscosity for the blends was performed and the effects
of UHMW on strain-hardening properties were analyzed at equal strain-rate conditions. The concentration of UHMW where the
strain-hardening becomes substantially stronger was determined. To get more insight into the cause of enhancement of strain-hardening
at a certain concentration, the damping function from step-shear stress relaxation was measured. The influence of a small
amount of UHMW on the damping function was found to be small. It was interpreted, from time- and strain-dependency points,
that the enhancement of strain-hardening by a small amount of UHMW was governed by the long relaxation time.
Received: 6 September 2000 Accepted: 11 January 2001 相似文献