全文获取类型
收费全文 | 79492篇 |
免费 | 439篇 |
国内免费 | 377篇 |
专业分类
化学 | 25171篇 |
晶体学 | 797篇 |
力学 | 6781篇 |
数学 | 32050篇 |
物理学 | 15509篇 |
出版年
2021年 | 59篇 |
2020年 | 63篇 |
2019年 | 50篇 |
2018年 | 10455篇 |
2017年 | 10273篇 |
2016年 | 6128篇 |
2015年 | 878篇 |
2014年 | 383篇 |
2013年 | 419篇 |
2012年 | 3881篇 |
2011年 | 10622篇 |
2010年 | 5717篇 |
2009年 | 6122篇 |
2008年 | 6697篇 |
2007年 | 8808篇 |
2006年 | 283篇 |
2005年 | 1373篇 |
2004年 | 1561篇 |
2003年 | 2003篇 |
2002年 | 1030篇 |
2001年 | 259篇 |
2000年 | 300篇 |
1999年 | 170篇 |
1998年 | 198篇 |
1997年 | 151篇 |
1996年 | 214篇 |
1995年 | 128篇 |
1994年 | 90篇 |
1993年 | 110篇 |
1992年 | 65篇 |
1991年 | 78篇 |
1990年 | 60篇 |
1989年 | 69篇 |
1988年 | 68篇 |
1987年 | 65篇 |
1986年 | 68篇 |
1985年 | 60篇 |
1984年 | 59篇 |
1983年 | 51篇 |
1982年 | 56篇 |
1981年 | 48篇 |
1980年 | 50篇 |
1979年 | 50篇 |
1978年 | 41篇 |
1914年 | 45篇 |
1913年 | 40篇 |
1912年 | 40篇 |
1909年 | 41篇 |
1908年 | 40篇 |
1907年 | 32篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
Angshuman Ghosh Soumen Kumar Dubey Dr. Maxcimilan Patra Jishu Mandal Narendra Nath Ghosh Priyanka Das Arpita Bhowmick Dr. Keka Sarkar Dr. Suprabhat Mukherjee Rajat Saha Dr. Subham Bhattacharjee 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(63):e202201621
We have shown solvent- and substrate-dependent chiral inversion of a few glycoconjugate supramolecules. (Z)-F-Gluco, in which d -glucosamine has been attached chemically to Cbz-protected l -phenylalanine at the C terminus, forms a self-healing hydrogel through intertwining of the nanofibers wherein the gelators undergo lamellar packing in the β-sheet secondary structures with a single chiral handedness. Dihybrid (Z)-F-gluco nanocomposite gel was prepared by in-situ formation of silver nanoparticles AgNPs in the gel; this enhances the mechanical properties of the composite gel through physical crosslinking without altering the packing pattern. In contrast, (Z)-L-gluco bearing an l -leucine moiety does not form a hydrogel but an organogel. Interestingly, the chiral handedness of the aggregates of (Z)-L-gluco can be reversed by choosing suitable solvents. In addition to self-healing behavior, (Z)-L-gluco gel revealed shape persistency. Further, (Z)-F-gluco hydrogel is benign, nontoxic, non-immunogenic, and non-allergenic in animal cells. AgNP-loaded (Z)-F-gluco hydrogel showed antibacterial activity against both Gram-positive and Gram-negative bacteria. 相似文献
2.
Designs, Codes and Cryptography - We propose a deterministic algorithm to recover some state bits of any FSR-based stream cipher knowing some keystream bits by fixing some state bits. This... 相似文献
3.
Energy transfer has been employed in third‐generation solar cells for the conversion of light into electrical energy. Long‐range nonradiative energy transfer from semiconductor quantum dots (QDs) to fluorophores has been demonstrated by using CdS QDs and thiophene?BODIPY (boron dipyrromethene, abbreviated as TG2). TG2 shows a broad photoluminescence (PL) spectrum, which varies with concentration. At very low concentrations, monomeric units are present; then, upon increasing the concentration, these monomers form a mixed (J‐/H‐)aggregated state. Energy transfer between the CdS QDs and TG2 was confirmed by separately investigating the interactions between CdS and the monomer of TG2 and between CdS and the aggregated states of TG2. Size‐dependent PL quenching confirmed that nonradiative Förster resonance energy transfer (FRET) from photoexcited CdS QDs to the J‐aggregate state of TG2 was the major energy‐relaxation channel, which occurred on the timescale of hundreds of fs. These results have broad applications in the field of light harvesting based on the assembly of molecular aggregates. 相似文献
4.
Yuliang Zhao 《中国科学:化学(英文版)》2018,61(12):1481-1482
正Living organisms have developed their unique strategies during the natural evolution for building hard tissues with minerals, including silica, calcium carbonate, calcium phosphate, and ferric oxide [1]. Such biomineralized materials generally have complex hierarchical structures with excellent mechanical properties. Although bioinspired approaches have led to the creation of well-defined synthetic structural materials ranging from micro to macro scales, the rational design of discrete biomimetic structures at the nanoscale remains a grand challenge. 相似文献
5.
JuHong Ge 《Nonlinear dynamics》2018,94(1):87-98
A five-neuron network model with multiple delays is proposed. This paper presents the combined effect of different delays on the dynamics of the proposed network. Pitchfork bifurcation is discussed in detail with the variation of the value of coupled weight or attenuation rate of internal neurons. By analyzing the corresponding characteristic equation, some stable criteria on delay-dependence and delay-independence are derived including multiple delays and coupled weights and the periodic oscillation arises bifurcated from the trivial equilibrium after the network loses its stability. Stable regions on delay-dependence are displayed in the two delayed parameter plane. It is shown that multiple delays can produce stability switching between resting state and periodic activity. Finally, theoretical results are justified by providing two illustrative examples. 相似文献
6.
It is shown that the countably infinite dimensional pointed vector space (the vector space equipped with a constant) over a finite field has infinitely many first order definable reducts. This implies that the countable homogeneous Boolean-algebra has infinitely many reducts. 相似文献
7.
8.
Ajay Gupta Fillip Kumar Sarkar Rajib Sarkar Ramen Jamatia Chang Yeon Lee Gajendra Gupta Amarta Kumar Pal 《应用有机金属化学》2020,34(9):e5782
Magnetically retrieval CuFe2O4@MIL-101(Cr) metal–organic framework was successfully prepared from easily available starting materials and characterized using various spectroscopic and analytical techniques such as powder X-ray diffraction, scanning electron microscopy, energy dispersive X-ray, transmission electron microscopy, elemental mapping, Fourier transform infrared spectroscopy, thermogravimetric analysis, X-ray photoelectron spectroscopy, Brunauer–Emmett–Teller, vibrating sample magnetometer, and inductively coupled plasma optical emission spectroscopy. The catalyst was then used in the synthesis of benzodiazepines containing a triazole moiety in water. The advantages of this protocol include high yields, reusability of the catalyst, and gram-scale synthesis. 相似文献
9.
10.
Zinovy Reichstein 《Archiv der Mathematik》2018,111(5):449-455
We use a recent advance in birational geometry to prove new lower bounds on the essential dimension of some finite groups. 相似文献