A Mossbauer study of the magnetic coupling in iron phosphorous trisulfides

The polycrystalline sample of layered compound FePS_3 has been investigated by using M?ssbauer spectroscopy (12K to 300K), magnetic susceptibility measurements, x-ray diffraction and FTIR spectroscopy. The antiferromagnetic order exists below T_N=120.5±1K. The M?ssbauer spectra below T_N indicate that the magnetization axis is perpendicular to the layer of FePS_3, and the divalent iron cations are in their high spin configurations. By fitting the hyperfine field parameters near the Néel temperature, we obtain information on the nature of magnetic interactions in the material. The results show that the magnetic coupling can be treated by the two-dimensional Ising model, and it can be interpreted on the basis of a crystal-field effect.     

多孔硅薄层的正电子湮灭寿命研究

用阳极氧化法按不同腐蚀条件制备的多孔硅，其薄层厚度仅为几十纳米，远小于^22Na源的正电子平均射程．文章提出了一种用控Na的正电子测量体寿命谱并扣除基片贡献的方法，来确定多孔硅薄层的平均孔径。     

Spin-glass state and ferromagnetic order in Cu(II)－Fe(III) cyanides

The static and dynamic magnetic properties of a Prussian blue analogue, molecular magnet Cu^Ⅱ_{3}[Fe^Ⅲ(CN)_6]_2·3NH_3·6H_2O were investigated in detail. The H dependence of the linear AC susceptibility, the irreversibility in the field-cooled (FC)/zero-field-cooled (ZFC) magnetization (M_{FC}/M_{ZFC}) and the relaxation of M_{ZFC} suggest that the magnetic system can be visualized as containing a ferromagnetic cluster of spin below T_C, mixed with small spin-glass clusters formed below temperature T_g less than T_C. The observed magnetic properties are explained with a ferromagnetic-spin-glass phase model. The magnetic ordering of the sample occurs below 19.8K.     

Moessbauer Studies on Spin Transition in Zinc Dilution Complexes [Fe1—xZnx（dpp）2（NCS）2]py（x=0.05—0.40）

A series of spin transition complexes [Fe1-xZnx(dpp)2(NCS)2]ph(x=0.05,0.10,0.15,0.20,0.25,and 0.40;py=pyridine) has been synthesized and studied by Moessbauer spectroscopy.The high-spin structure is frozen at room temperature,and the induced meta-stable high-spin phase by the so-called rapid cooling method is monitored by temperature and time-dependent Moessbauer spectra.The investigation on dynamic relaxation of the high-spin state to the low-spin state at 80-K reveals sigmoid behaviour and existence of cooperative effect for low diluted complexes.This cooperative effect is wrecked by the dilution of Zn(Ⅱ）ions in Fe（Ⅱ）ion sites,and relaxation curves gradually become to obey the first-order kinetics as the ratio of the dilution increases.     

嵌入化合物Fe0.95PS3(MV)0.11的合成与磁性能研究

利用嵌入反应合成了有机-无机嵌入化合物Fe0.95PS3(MV)0.11(MV为1,1'-二甲基-4,4'-联吡啶阳离子),对其结构和磁性进行了研究.x射线衍射数据表明,此嵌入化合物的晶体结构仍为单斜晶系,空间群为C2/m,晶胞参数a=0.879 nm,b=0.944 nm,c=1.070 nm,β=114.76°.相对于纯FePS3,层间距离增大0.33 nm.磁化率研究表明,从室温降到4.2 K过程中,此化合物经历了两级磁相变.在居里温度TC=84 K以下发生铁磁相变,奈尔温度TN=26 K以下为反铁磁相变.12-300 K变温Mossbauer谱研究证实,此化合物存在三个高自旋二价铁的位置,表明在嵌入反应过程中有电荷从客体分子转移到主体晶格中Fe-S的e*g反键轨道上,并有部分铁离子从晶格中脱出,从而在主体晶格中产生金属阳离子空位.铁磁性是由于自旋倾斜所致,而极低温度下自旋倾斜消失,又表现为反铁磁性.     

嵌入化合物Fe0.95PS3(MV)0.11的合成与磁性能研究

利用嵌入反应合成了有机-无机嵌入化合物Fe_0.95PS₃(MV)_{0.1 1}(MV为1,1′- 二甲基-4,4′-联吡啶阳离子)，对其结构和磁性进行了研究.x射线衍射数据表明，此嵌入化 合物的晶体结构仍为单斜晶系，空间群为C2/m，晶胞参数a=0.879 nm, b=0.944 nm, c=1.07 0 nm, β=114.76°.相对于纯FePS₃, 层间距离增大0.33 nm.磁化率研究表明， 从室温降 到4.2 K 关键词： 嵌入化合物 Mssbauer谱 磁相互作用 分子磁体     

船舶无空泡螺旋桨非定常推力脉动及其诱导线谱噪声分析

对船舶无空泡螺旋桨非定常推力脉动及其诱导的线谱噪声进行了研究,主要目的在于螺旋桨非定常推力脉动理论预报方法的验证。基于速度势面元法计算得到非均匀流场中无空泡螺旋桨的推力脉动,在大型循环水槽中利用非定常动力仪测试得到全附体船后螺旋桨的脉动推力,以脉动推力作为声源项预报得远场线谱噪声。一阶叶频非定常推力系数理论计算值与试验值最大相差29.3%,由此引起的线谱噪声差别为3.0 dB。上述结果表明,面元法预报船后螺旋桨非定常推力脉动已达到较高精度,为船舶螺旋桨低频线谱噪声的预报提供了物理基础和重要参数。      

双钙钛矿型Ba2SmSbO6的水热合成和结构表征

在温和水热条件下合成了双钙钛矿型Ba2SmSbO6,通过XRD,IR,ICP,XPS,VSM和121SbMöss-bauer谱对产物的物相、结构、锑离子价态和磁化率等进行了表征.Ba2SmSbO6具有立方钙钛矿结构,Fm3m空间群,晶胞参数a=0.85097(20)nm,V=0.61623(20)nm,Sm和Sb离子呈岩盐型有序排列,锑为+5价.     

具有界面相的球形粒子在无限大基体中的应力集中分析

研究了无限大基体内具有界面相的球形粒子在轴对称载荷作用下的应力场,并与线弹簧界面模型的情形进行了比较,对粒子／界面相以及界面相／基体两个界面的应力集中系数以及粒子内部的应力集中系数进行了分析．研究了应力二轴度、界面相厚度以及三相的模量对应力集中系数的影响．结果表明,对给定的模量和界面相厚度值,存在一个临界应力三轴度值．若应力二轴度小于此临界值,则界面相／基体界面的应力集中系数大于粒子／界面相界面的应力集中系数;否则,前者会小于后者．所做的应力分析可以为颗粒增强复合材料的强韧化设计提供一定参考．     

用遗传算法拟合Eu-151穆斯堡尔谱

以Eu2O3(立方晶系)为例，论述遗传算法(GA，Genetic Algorithm)求解穆斯堡尔谱的过程，并将解谱结果与文献数据和Moss Win解谱结果进行比较。