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Size distribution of sulfur species in fine and ultrafine aerosol particles using sulfur K-edge XANES 总被引:1,自引:0,他引:1
The sulfur species existing in different size aerosol particles were determined based on the 'white line' energy shift and the features of post edge structure of sulfur K-edge XANES (X-ray Absorption Near Edge Structure). The results indicated that sulfates were dominant sulfur species in aerosol particles. However, small amount of reductive sulfur species were also found in the ultrafine aerosol particles(〈0.1 μm). Sulfates in aerosols mostly exhibited as (NH4)2SO4 and gypsum. than 0.952 μm, while gypsum was the dominant sulfate Most (NH4)2SO4 distributed in aerosol particles finer in coarse aerosols. 相似文献
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研制了一种用于同位素分离在线穆斯堡尔谱学的平行板雪崩计数器,计数器仅重40g。用它测量由穆斯堡尔共振吸收后放出的内转换电子,采用85%^119Sn同位素增丰的SnO2作为阴极吸收材料,测得的穆斯堡尔谱的信噪比为11,是一种适合在线穆斯堡尔实验的计数器。对该计数器的性能进行了讨论。A Parallel Plate Avalanche Counter (PPAC) with weighted about 40 g was developed for isotope separator on-line Moessbauer Spectroscopy. It detects the internal conversion electrons emitted from the resonance Moessbauer nuclide. The signal-to-noise ratio of the spectra reaches 11 for 85% enriched ^119SnO2 cathode and absorber. It is an effective detector for on-line Moessbauer experiments. The perform ance of the counter was discussed in detail. 相似文献
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通过研究大气颗粒物中222Rn子体活度比与颗粒物平均寿命之间的关系,建立了基于活度比估算大气颗粒物滞留时间(residence time of atmospheric aerosol,RTAA)的方法,并在相对理想条件下进行了实验验证.当氡室浓度稳定为1.816kBq/m3时,由214Bi/214Pb活度比计算出的RTAA为112.17min,与氡室的平均换气时间(104.17min)相当,表明大气颗粒物中同一衰变链上的放射性核素活度比(如214Bi/214Pb,210Bi/210Pb或210Po/210Pb)可以用于估算RTAA. 相似文献
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The static and dynamic magnetic properties of a Prussian blue analogue, molecular magnet Cu^Ⅱ_{3}[Fe^Ⅲ(CN)_6]_2·3NH_3·6H_2O were investigated in detail. The H dependence of the linear AC susceptibility, the irreversibility in the field-cooled (FC)/zero-field-cooled (ZFC) magnetization (M_{FC}/M_{ZFC}) and the relaxation of M_{ZFC} suggest that the magnetic system can be visualized as containing a ferromagnetic cluster of spin below T_C, mixed with small spin-glass clusters formed below temperature T_g less than T_C. The observed magnetic properties are explained with a ferromagnetic-spin-glass phase model. The magnetic ordering of the sample occurs below 19.8K. 相似文献
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