排序方式: 共有61条查询结果,搜索用时 15 毫秒
1.
Meng Xia Wang Lizhen Zhai Yunge Duan Hongdong 《Research on Chemical Intermediates》2020,46(12):5517-5533
Research on Chemical Intermediates - Two novel Schiff-base fluorescent probes bearing different substituents were synthesized by the reaction of indole derivatives with 4-aminoantipyrine. The... 相似文献
2.
Let A and B be algebras, and let T be the dual extension algebra of A and B. We provide a different method to prove that T is Koszul if and only if both A and B are Koszul. Furthermore, we prove that an algebra is Koszul if and only if one of its iterated dual extension algebras is Koszul, if and only if all its iterated dual extension algebras are Koszul. Finally, we give a necessary and sufficient condition for a dual extension algebra to have the property that all linearly presented modules are Koszul modules, which provides an effective way to construct algebras with such a property. 相似文献
3.
工业二乙烯苯悬浮聚合制备的大孔树脂,在二氯乙烷溶剂中以无水三氯化铁为催化剂进行悬挂双键后交联反应,得到的后交联树脂的比表面积和孔容都有显著增加.低温氮气吸附/脱附等温线得到的孔径分布曲线证明初始共聚物PDT-55(polydivinylbenzene,toluene as porogen)和PDH-55(polydivinylbenzene,heptane andtoluene as porogen)经后交联反应,所形成的新孔以微孔为主.树脂对水溶液中苯酚和维生素B12(VB12)的静态吸附研究发现树脂经后交联后,对苯酚的吸附量有显著提高,但对VB12的吸附量增加不大,原因是分子尺寸较大的VB12无法进入由悬挂双键后交联反应所形成的微孔.树脂PDT-55pc对苯酚的吸附量大于商品树脂XAD-4;后交联前后树脂PDT-55、PDT-55pc(post-crosslinking of PDT-55)、PDH-55、PDH-55pc(post-crosslinking ofPDH-55)对VB12的吸附量均大于树脂XAD-4.在本研究的实验条件下,Langmiur和Freundlich吸附等温线方程能很好地拟合树脂对水溶液中苯酚和VB12的吸附,相关系数在0.99以上.静态吸附动力学实验结果表明后交联前后树脂对苯酚的吸附较VB12更容易达到吸附平衡.吸附动力学数据的拟合结果显示,McKay二级吸附动力学模型符合树脂对苯酚的吸附,而对VB12的吸附更符合Lagergren一级吸附动力学模型. 相似文献
4.
High cost of phosphors and significant efficiency roll-off at high brightness are the two main factors that limit the wide application of phosphorescent organic light-emitting diodes (PHOLEDs). Efforts have been paid to find ways to reduce the phosphors’ concentration and efficiency roll-off of PHOLEDs. In this work, we reported red emission PHOLEDs with low dopant concentration and low efficiency roll-off based on a novel host material 2,4-biscyanophenyl-6-(12-phenylindole[2,3-a]carbazole-11-yl)-1,3,5-triazine (BCPICT), with thermally activated delayed fluorescent(TADF) properties. The device with 1.0% dopant concentration displayed a maximum external quantum efficiency of 10.7%.When the dopant concentration was increased to 2.0%, the device displayed a maximum external quantum efficiency of 10.5% and a low efficiency roll-off of 5.7% at 1000 cd/m2. 相似文献
5.
设 $\Lambda$ 是域$k$上的有限维代数. 则 $\Lambda$的低阶 Hochschild上同调群在有限维代数的表示理论中扮演着重要的角色. 该文得到了 $l$ -遗传代数的一阶和二阶Hochschild 上同调群的维数方程. 相似文献
6.
7.
In this paper a post-crosslinked polymeric adsorbent PDHT-2 with high specific surface area was prepared by Friedel-Crafts reaction of the pendant vinyl groups without an externally added crosslinking agent. It was obvious that both the specific surface area and the pore volume of starting copolymer PDHT-1 increased significantly after post-crosslinking. Batch adsorption runs of phenol from aqueous solution onto adsorbent PDHT-1 and PDHT-2 were researched, and commercial macroporous resin XAD-4 was chosen for comparison purpose. Experimental results showed that the adsorption isotherms could be fitted by Langmuir model and Freundlich model and the adsorption capacity onto PDHT-2 was much larger than that onto PDHT-1 and XAD-4 with respect to phenol and phenolic compound, which possibly resulted from its larger specific surface area. The adsorption process for phenol onto the three adsorbents was proved to be exothermic and spontaneous in nature. The thermodynamic parameters such as Gibb's free energy (ΔG), change in enthalpy (ΔH) and change in entropy (ΔS) had been calculated. The adsorption kinetic curves obeyed the pseudo-second order model and the intraparticle diffusion process was the rate-controlling step. 相似文献
8.
酚醛型吸附树脂对咖啡因吸附性能的研究 总被引:6,自引:0,他引:6
利用 3种自制吸附树脂JDW 1、JDW 2、JDW 3和DuoliteS 761对咖啡因进行了静态和动态吸附研究 .结果发现 3种自制树脂对咖啡因的吸附性能明显优于DuoliteS 761 ;在吸附咖啡因的初始阶段 ,即达到 3 2 %~5 1 %平衡吸附百分率时 ,吸附速率数据和半经验速率方程很吻合 ,证实吸附咖啡因是粒扩散控制过程 ;酚醛型吸附树脂等温吸附咖啡因的平衡吸附数据符合Langmuir方程 ,相关系数在 0 99以上 ,因此 ,酚醛型吸附树脂吸附咖啡因属单分子层吸附 ;用 1mol LHCl和 40 %的甲醇溶液复合使用 ,效果很好 相似文献
9.
10.
研究了酚醛型吸附树脂在水体系中对吡啶和N,N-二甲基苯胺的静态和动态吸附行为.结果表明,在水中树脂对吡啶和N,N-二甲基苯胺的吸附主要以疏水吸附机理进行;吸附吡啶和N.N-二甲基苯胺的初始阶段,即达到38.3~48.9%平衡吸附时,吸附速率数据和半经验速率方程很吻合:酚醛型吸附树脂等温吸附吡啶和N,N-二甲基苯胺的平衡吸附数据符合Langmuir方程,相关系数在0.99以上,酚醛型吸附树脂吸附吡啶和N,N-二甲基苯胺属单分子层吸附:用80%的乙醇溶液作洗脱剂来洗脱吸附吡啶已达饱和的JDW-2树脂,效果是很理想的.在3.6个床体积内洗脱率达91.52%,4.8个床体积内洗脱率达到94.85%。表明酚醛型吸附树脂具有优良的洗脱性能. 相似文献