点支式中空玻璃承载性能的有限元分析

中空玻璃承受均布横向荷载时,外、内片与密封气体之间产生复杂的交互作用,现行规范(程)基本按抗弯刚度比例在外、内片玻璃之间分配荷载。本文使用有限元法,分析点支式中空玻璃在承受均布横向荷载时的结构特性,利用迭代计算精确地求解外荷载在外、内片间的分配比例,计算与实验测值吻合得较好。本文指出,宽厚比、中空层厚度等因素对于荷载分配比例均有较大影响,在某些情况下,直接承受荷载的外片可能承受绝大部分的荷载,规范(程)的设计方法仍值得商榷。同时,本文建议在设计中考虑中空层温度变化对承载性能的影响。     

考虑中间主应力效应的损伤钢管混凝土构件承载力分析

混凝土三参数统一强度理论在Haigh-Westgaard空间的偏平面上的边界线为十二边形,通过调整中间主应力的影响系数消除角点的奇异性,根据相关流动准则推导基于标量损伤的弹塑性本构方程,考虑了混凝土材料的随动强化效应,结合塑性损伤理论给出了应力计算的数值方法,编制了相应的Fortran语言程序,并将其用于钢管混凝土构件承载能力的计算,计算结果验证了所用模型的预测能力。     

Poly(vinylphosphonate)s functionalized polymer microspheres via rare earth metal‐mediated group transfer polymerization

We demonstrate a facile, yet efficient method for the functionalization of crosslinked polystyrene (PS) microspheres with biocompatible poly(vinylphosphonate)s via the combination of a UV grafting polymerization and a surface‐initiated group transfer polymerization. Self‐initiated photografting and photopolymerization of ethylene glycol dimethacrylate results in direct photografting of poly(ethylene glycol dimethacrylate) on the PS microspheres with dangling methacrylate functionalities, which are used to immobilize ytterbocene complexes to form the surface‐bound rare‐earth metal catalyst system. The surface‐initiated GTP of dialkyl vinylphosphonates from the initiator system leads to the functionalization of PS microspheres with poly(vinylphosphonate) brushes. Polymerization kinetic investigation indicates that surface‐initiated GTP leads to a constant and remarkably rapid weight gain of the microsphere (a microsphere weight increase of 600% within 3 min), owing to the highly living and efficient character of GTP. The surface‐initiated GTP occurring inside the microsphere causes an accumulation of the tension between the polymer chains in the microsphere, which eventually induces fracture of the microsphere for longer polymerization time. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014 , 52, 2919–2925     

Geometrothermodynamics of Van der Waals black hole

We study the geometrothermodynamics of a special asymptotically AdS black hole, i.e. Van der Waals \(\left( VdW\right) \) black hole, in the extended phase space where the negative cosmological constant \(\Lambda \) can be regarded as thermodynamic pressure. Analysing some special conditions of this black hole with geometrothermodynamical method, we find a good correlation with ordinary cases according to the state equation.     

Absorption/Scattering of Scalar Waves by Dilatonic Black Hole

We investigate the scattering and absorption cross sections of scalar waves by Garfinkle-Horowitz-Strominger (GHS) black hole spacetime with partial wave method. We find that the total absorption cross section oscillates around the geometric optical value, and the scattering angle width becomes narrower and the damping oscillation pattern becomes more complex as l increases. With fixed frequency ω, the main glory peak value becomes higher and the glory width becomes wider as the magnetic parameter a increases.     

Metric of the gravitational field outside the neutron star

We have obtained the solution of the Einstein equation and the electric-magnetic field outside the neutron star, and at the same time, we investigated their asymptotic properties.     

Preparation of a new benzylureido-β-cyclodextrin-based column and its application for the determination of phenylmercapturic acid and benzylmercapturic acid enantiomers in human urine by LC/MS/MS

Analytical and Bioanalytical Chemistry - A benzylureido-β-cyclodextrin was synthesized by the reaction of 6-amino-β-cyclodextrin with an active benzyl isocyanate. Then, it was bonded to...     

基于五参数统一强度理论的刚构桥地震损伤分析

混凝土五参数统一强度理论在主应力空间偏平面上的边界线为十二边形,可通过调整中间主应力的影响系数消除角点的奇异性,以单位体积材料当前塑性耗能及其断裂能的比值定义损伤变量,根据相关流动准则推导混凝土的弹塑性损伤本构关系。该模型可同时考虑混凝土材料中间主应力的影响、高应力状态下的静水应力效应、拉压异性和随动强化效应等,不考虑循环荷载下的刚度折减。由图形回归法给出应力更新的数值方法,编写了相应的Fortran语言程序,并将其用于大跨度连续刚构桥地震损伤的模拟,计算结果验证了所用模型的预测能力。