HIRFL-CSR外靶装置上的放射性束实验数据分析方法研究

开发了HIRFL-CSR外靶实验装置的大型数据分析程序(ANAETF)，并成功应用于核物理实验数据分析。详细阐述了该程序中的数据分析流程、漂移室寻迹算法、粒子鉴别方法和反应截面提取技术。利用本程序分析了240 MeV/u能量下12C次级束流打碳靶的实验数据，实现了清楚的碳和硼剩余核的粒子鉴别，总探测效率达到 ~90%，本工作提取的反应截面与已有的实验结果符合较好。     

Sodium‐Doped Mesoporous Ni2P2O7 Hexagonal Tablets for High‐Performance Flexible All‐Solid‐State Hybrid Supercapacitors

A simple hydrothermal method has been developed to prepare hexagonal tablet precursors, which are then transformed into porous sodium‐doped Ni₂P₂O₇ hexagonal tablets by a simple calcination method. The obtained samples were evaluated as electrode materials for supercapacitors. Electrochemical measurements show that the electrode based on the porous sodium‐doped Ni₂P₂O₇ hexagonal tablets exhibits a specific capacitance of 557.7 F g^?1 at a current density of 1.2 A g^?1. Furthermore, the porous sodium‐doped Ni₂P₂O₇ hexagonal tablets were successfully used to construct flexible solid‐state hybrid supercapacitors. The device is highly flexible and achieves a maximum energy density of 23.4 Wh kg^?1 and a good cycling stability after 5000 cycles, which confirms that the porous sodium‐doped Ni₂P₂O₇ hexagonal tablets are promising active materials for flexible supercapacitors.     

Evaluation of Physiological Characteristics,Soluble Sugars,Organic Acids and Volatile Compounds in ‘Orin’ Apples (Malus domestica) at Different Ripening Stages

‘Orin’ is a popular apple cultivar, which has a yellow-green appearance, pleasant taste, and unique aroma. However, few studies on the fruit quality characteristics of ‘Orin’ apples have been reported before. In this study, changes of the physiological characteristics were measured at different ripening stages, and the soluble sugars and organic acids were determined by high-performance liquid chromatography (HPLC). Volatile compounds were identified using the headspace solid-phase microextraction (HS-SPME) coupled with gas chromatography-mass spectrometry (GC-MS). During the fruit ripening, the ‘Orin’ apple fruit weight, size, and total soluble solid were gradually increased by contrast with the titratable acidity, and the firmness decreased. The content of four soluble sugars reached the maximum at the 180 days after full bloom (DAFB) stage. Malic acid was measured as the most abundant organic acid in ‘Orin’ apples. Ethyl butyrate, hexyl propanoate, hexyl acetate and butyl acetate belonging to esters with high odor activity values (OAVs) could be responsible for the typical aroma of ‘Orin’ apples. The aim of this work was to provide information on the flavor characteristics of ‘Orin’ apples and promote this apple cultivar for marketing and processing in the future.     

DROP FORMATION FROM A CAPILLARY TUBE IN THE PRESENCE OF SURFACTANT 1)

本文研究了竖直毛细圆管出口表面活化剂包覆液滴的形成过程。基于泰勒展开和润滑近似理论, 建立了液滴形成过程的一维动力学模型,并且通过坐标变换和有限差分的方法进行了数值求解。结果显示, 液滴自由面上表面活化剂包覆层可促进液滴颈部断裂,加快液滴头部与尾部锥形区的分离过程。与此同时, 还可增大颈部断裂前液滴下落的极限位移。与表面活化剂的活性相比, 液滴自由面上表面活化剂浓度的变化对液滴形成过程以及液滴形貌变化的影响更为显著。     

避雷器电阻片测试系统设计

采用工业PC机与可编程控制器、示波器、直流仪等设备设计了避雷器电阻片测试系统,阐述了本系统的控制流程及逻辑关系,用图形化编程语言编写了上位机软件,完成了避雷器电阻片在 U_1mA及0.75U_1mA下的漏电流等参数的测试,并对电阻片测试过程中的电压峰值、电流峰值进行采集存储,还存储了电阻片在整个测试过程中的能量,方便以后对测试过程中损坏的阀片进行能量、电流峰值、电压峰值方面的分析,对系统进行了初步的试验,结果表明该系统运行效果良好,实现了避雷器电阻片出厂前的测试,提高了测试效率。     

Quantification of Thiopurine/UVA-Induced Singlet Oxygen Production

Thiopurines were examined for their ability to produce singlet oxygen ((1)O(2)) with UVA light. The target compounds were three thiopurine prodrugs, azathioprine (Aza), 6-mercaptopurine (6-MP) and 6-thioguanine (6-TG), and their S-methylated derivatives of 6-methylmercaptopurine (me6-MP) and 6-methylthioguanine (me6-TG). Our results showed that these thiopurines were efficient (1)O(2) sensitizers under UVA irradiation but rapidly lost their photoactivities for (1)O(2) production over time by a self-sensitized photooxidation of sulfur atoms in the presence of oxygen and UVA light. The initial quantum yields of (1)O(2) production were determined to be in the range of 0.30-0.6 in aqueous solutions. Substitution of a hydrogen atom with a nitroimidazole or methyl group at S decreased the efficacy of photosensitized (1)O(2) production as found for Aza, me6-MP and me6-TG. (1)O(2)-induced formation of 8-oxo-7,8-dihydro-2'-dexyguanosine (8-oxodGuo) was assessed by incubation of 6-methylthiopurine/UVA-treated calf thymus DNA with human repair enzyme 8-oxodGuo DNA glycosylase (hOGG1), followed by apurinic (AP) site determination. Because more 8-oxodGuo was formed in Tris D(2)O than in Tris H(2)O, (1)O(2) is implicated as a key species in the reaction. These findings provided quantitative information on the photosensitization efficacy of thiopurines and to some extent revealed the correlations between photoactivity and phototoxicity.     

S-Index:一种面向大规模RDF数据的高效率语义索引方案

大规模RDF数据的高效查询和推理是语义Web研究中关键问题.通过研究RDFS推理规则,结合ORDPATH编码机制,提出了一种新的大规模RDF数据的索引构建方案——S-Index.S-Index的一个显著特点是,通过对RDF数据的查询即可得到RDFS蕴含知识,实现了离线推理.对RDF数据中的ABox和TBox进行区分,通过ORDPATH编码,分别构建TBox中的Class和Property子父关系,以及domain和range关系的语义信息.将构建的语义编码信息持久化到RDF三元组索引中,使得三元组索引承载有语义信息,也即构成语义索引并最终持久化到底层数据库.设计并进行了一系列实验,对比了语义索引与一般索引在存储和查询时的性能.实验结果表明,S-Index语义索引在没有给不支持语义的传统RDF索引增加显著额外负担和开销的情况下,获得了在查询时对推理的有效支持.     

一个反映土体复杂加卸荷路径的弹黏塑性模型

基于Perzyna 过应力理论,构造了一个土体各向异性弹黏塑性本构模型. 模型引入Wheeler 旋转硬化法则,能够较好的描述土体的初始各向异性和应力诱发各向异性. 借助ABAQUS 软件中UMAT 子程序接口,模型采用隐式积分算法——图形返回算法实现. 通过对一组复杂加卸荷路径的三轴不排水剪切试验(HKMD) 及一组分级加载三轴不排水蠕变试验(Sachville clay) 的模拟,表明本模型能够合理反映土体的率效应、应力松弛、蠕变及土体各向异性现象,验证了模型的有效性.     

有机化学课程中的绿色化学教育

介绍了在有机化学课程教学实践中对学生进行绿色化学教育的做法和建议,其中包括反应试剂的绿色化,反应条件的绿色化,目标产物绿色化。