全文获取类型
收费全文 | 2141篇 |
免费 | 412篇 |
国内免费 | 327篇 |
专业分类
化学 | 1687篇 |
晶体学 | 30篇 |
力学 | 142篇 |
综合类 | 23篇 |
数学 | 221篇 |
物理学 | 777篇 |
出版年
2024年 | 6篇 |
2023年 | 50篇 |
2022年 | 75篇 |
2021年 | 94篇 |
2020年 | 126篇 |
2019年 | 113篇 |
2018年 | 113篇 |
2017年 | 107篇 |
2016年 | 130篇 |
2015年 | 134篇 |
2014年 | 165篇 |
2013年 | 201篇 |
2012年 | 236篇 |
2011年 | 222篇 |
2010年 | 143篇 |
2009年 | 115篇 |
2008年 | 107篇 |
2007年 | 94篇 |
2006年 | 78篇 |
2005年 | 72篇 |
2004年 | 66篇 |
2003年 | 44篇 |
2002年 | 53篇 |
2001年 | 41篇 |
2000年 | 43篇 |
1999年 | 48篇 |
1998年 | 23篇 |
1997年 | 27篇 |
1996年 | 25篇 |
1995年 | 16篇 |
1994年 | 14篇 |
1993年 | 15篇 |
1992年 | 14篇 |
1991年 | 12篇 |
1990年 | 5篇 |
1989年 | 9篇 |
1988年 | 7篇 |
1987年 | 6篇 |
1986年 | 2篇 |
1985年 | 3篇 |
1984年 | 4篇 |
1983年 | 3篇 |
1982年 | 7篇 |
1981年 | 3篇 |
1980年 | 1篇 |
1979年 | 2篇 |
1977年 | 3篇 |
1975年 | 1篇 |
1957年 | 1篇 |
1936年 | 1篇 |
排序方式: 共有2880条查询结果,搜索用时 34 毫秒
1.
Theoretical and Mathematical Physics - We apply the Riemann–Hilbert method to the generalized mixed nonlinear Schrödinger equation and obtain a new formula for an explicit $$N$$ -soliton... 相似文献
2.
Journal of Algebraic Combinatorics - APR tilts for path algebra kQ can be realized as the mutation of the quiver Q in $${\mathbb Z}Q$$ with respect to the translation. In this paper, we show that... 相似文献
3.
Jiang Rui-Yang Xin Jia-Wei Cao Cong 《International Journal of Theoretical Physics》2021,60(8):2836-2855
International Journal of Theoretical Physics - Quantum logic gates are the foundation of circuit-based quantum computation and quantum simulation. Multi-qubit quantum controlled gates are of vital... 相似文献
4.
HUA Cong WANG Xuanzhong LIANG Shipeng LI Chen CHEN Xi PIAO Meihua WANG Zhenchuan GE Pengfei LUO Tianfei 《高等学校化学研究》2022,38(4):1089-1096
Ferroptosis triggered by hemin is regarded as a primary factor accounting for neuronal death secondary to intracerebral hemorrhage. Thus, compounds with inhibitory effect on hemin-induced ferroptosis might be potential medicines to prevent neuronal death caused by intracerebral hemorrhage. Herein, we investigate whether maltol could alleviate hemin-induced SH-SY5Y cell ferroptosis and its potential mechanisms. It is found that maltol effectively prevents hemin-induced SH-SY5Y cell ferroptosis via three pathways. The first one is inhibiting intracellular iron increase via preventing upregulation of transferrin receptor, the second one is alleviating lipid peroxidation via attenuating H2O2 generation by NOX4 and promoting H2O2 clearance by catalase, and the third one is to reduce peroxidized lipids via maintaining GPX4/GSH pathway. Therefore, maltol is a novel agent preventing hemin-induced SH-SY5Y cell ferroptosis. 相似文献
5.
A novel organoantimony complex of 6-cyclohexyl-6,7-dihydrodibenzo[c,f] [1,5]azastibocin-12(5H)-yl nitrate ( 2 ) was synthesized and systematically characterized by techniques such as NMR spectra, TG-DSC, and X-ray diffraction. It was found that the complex 2 exhibits relatively strong Lewis acidity (3.3 < Ho ≤ 4.8) and could be employed as a water tolerant Lewis acid catalyst for the synthesis of synthetically valuable benzimidazole derivatives starting from aldehydes and arylenediamines. This catalytic system shows excellent tolerance toward a wide variety of functional groups, such as methyl, methoxyl, fluoro, chloro, bromo, nitro, cyan, trifluoromethyl, 1-naphthaldehyde, furfural and n-butyl, together with facile reusability in 5 times scale enlarged synthesis. 相似文献
6.
Jihua Liu Huizhu Gan Ting Li Jia Wang Guangguang Du Yang An Xiaojing Yan Cong Geng 《Biomedical chromatography : BMC》2020,34(8):e4856
Ocotillol, pseudo-ginsenoside RT5 (RT5), and pseudo-ginsenoside F11 (PF11) are ocotillol-type saponins that have the same aglycone structure but with different numbers of glucose at the C-6 position. In this study, the metabolites of ocotillol, RT5, and PF11 in rat plasma, stomach, intestine, urine, and feces after oral administration were investigated by ultra-performance liquid chromatography coupled with time-of-flight mass spectrometry. The results showed that RT5 was easily biotransformed into metabolites in vivo, whereas PF11 and RT5 were difficult to be biotransformed. Hydrogenation, dehydrogenation, dehydration, deglycosylation, deoxygenation, hydration, phosphorylation, deoxidation, glucuronidation, and reactions combining amino acid were speculated to be involved in the biotransformation of ocotillol, RT5, and PF11. Based on the structural analysis of metabolites, it was deduced that hydrogenation, dehydration, deoxidation, and reactions combining amino acid occurred on the aglycone structure, whereas deglycosylation, hydration, and phosphorylation occurred on the glycosyl chain. Further, metabolites in plasma, urine, feces, and tissues were different: First, glucuronidation products were found in urine, stomach, intestine, and feces, but not in plasma. Second, the ocotillol prototype was not identified in urine samples. Third, the RT5 prototype was found in stomach, intestine, feces, and urine, but not in plasma. 相似文献
7.
8.
Cong Hu Bingyang Dong Li Liu 《Journal of polymer science. Part A, Polymer chemistry》2019,57(12):1333-1343
We report on the preparation of reduction‐responsive amphiphilic block copolymers containing pendent p‐nitrobenzyl carbamate (pNBC)‐caged primary amine moieties by reversible addition–fragmentation chain transfer (RAFT) radical polymerization using a poly(ethylene glycol)‐based macro‐RAFT agent. The block copolymers self‐assembled to form micelles or vesicles in water, depending on the length of hydrophobic block. Triggered by a chemical reductant, sodium dithionite, the pNBC moieties decomposed through a cascade 1,6‐elimination and decarboxylation reactions to liberate primary amine groups of the linkages, resulting in the disruption of the assemblies. The reduction sensitivity of assemblies was affected by the length of hydrophobic block and the structure of amino acid‐derived linkers. Using hydrophobic dye Nile red (NR) as a model drug, the polymeric assemblies were used as nanocarriers to evaluate the potential for drug delivery. The NR‐loaded nanoparticles demonstrated a reduction‐triggered release profile. Moreover, the liberation of amine groups converted the reduction‐responsive polymer into a pH‐sensitive polymer with which an accelerated release of NR was observed by simultaneous application of reduction and pH triggers. It is expected that these reduction‐responsive block copolymers can offer a new platform for intracellular drug delivery. © 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2019, 57, 1333–1343 相似文献
9.
Sing Lai Cong Roy Anitha Hui Lok Yong Mun Chan Sook Rajak Harish Karunakaran Rohini Ravichandran Veerasamy 《Structural chemistry》2022,33(3):649-669
Structural Chemistry - Quinoline- and acridine-based drugs are widely used as anti-breast cancer agents. These drugs act through various mechanisms of action; for example, neratinib acts on... 相似文献
10.
制备了3种不同质量浓度的充填体试件,进行了单轴压缩声发射试验,分析了不同浓度的充填体力学特性,重点研究了试件破坏过程中的声发射振铃计数、声发射累计撞击数与声发射累计能量的比值(r值)、主频及其相对高频信号激增响应系数特征。研究表明:随着浓度的增加,充填体的峰值强度与弹性模量呈增大趋势,充填体中出现的声发射累计振铃计数越多;r值先升高再持续减小到一个较低值,随着外载荷的增加,进入缓慢升高阶段,峰值前均保持在该阶段。充填体破裂前兆信息在声发射信号主频分布中呈现主频段增多现象,表现为由加载初期的1~2个主频段,在临界主破裂时增多到3~5个主频段;且随着浓度的增加,声发射信号主频频段分布越宽,声发射相对高频信号(160~180 kHz)的激增响应系数呈递减趋势。以上特征可为不同浓度的尾砂胶结充填体稳定性监测、预测提供依据。 相似文献